摘要:
A process to induce polymerization of an organic electronically conductive polymer in the presence of a partially delithiated alkali metal phosphate which acts as the polymerization initiator.
摘要:
Self-protecting current collector, with lateral collection an insulating plastic support film having a thickness between about 1 and 30 microns, and a conductive metallic coating, of a thickness lower than about 10 microns, adhering to at least one face of the insulating support film, compatible with the corresponding material of the electrode of the generator, and wherein its conductive surface is divided into a plurality of adjacent distinct areas, each area being electrically insulated by means of non-conductive borders except for at least one conductive bridge of small cross-section connected to a lateral common conductive margin enabling a lateral collection of the entire distinct areas; the nature and electrical resistance of the conductive bridges enabling on the one hand, passage of currents corresponding to maximum currents provided for each of the individual collection areas of the generator to be produced, and limiting on the other hand, in case of an accidental short-circuit inside an area, the maximum current received by this area originating from the entire areas of the generator.
摘要:
Between the high electronic conduction structures of the multilayer assembly an electric voltage signal is applied of which at least one portion includes an alternating component which has an amplitude between 0.05 and 100 volts and a frequency lower than 5 kHz and preferably between 2 and 2000 Hz so as to generate within the multilayer assembly an alternating ion current susceptible of producing a heating of the ion conducting macromolecular material by Joule effect. Application to the heating of electrochemical current generators in thin layers with solid polymer electrolyte or to the surface heating of elements of various regular or irregular shapes of which the surface is coated with the multilayer assembly.
摘要:
Electrochemical cells containing lithium and a solid polymer electrolyte in the form of thin films are produced by making multilayer assemblies from double-layer solid polymer electrolyte/composite positive electrode sub-assemblies which are subsequently associated with the other constituent layers of the cell so that the multilayer assembly so obtained comprises a layer of a metal of low ductility. Cells may be made from multilayer assemblies by stacking, rolling or bending techniques.
摘要:
Process of manufacturing thin electrodes, supported on a sheet substrate, the electrodes being made from an element selected form lithium, lithium alloy, or doped lithium, whose melting point does not differ from the melting point of lithium by +50.degree. C. and whose thickness is constant, from a roller of the sheet and a source of the element. According to the invention, there is provided a bath of the element in molten state, the sheet is continuously unrolled, a constant quantity of the molten element is continuously applied on one of the two faces of the sheet, so as to produce a film on the sheet, whose thickness is constant and between abouth 0.1 and about 40.mu. and whose surface is homogeneous and uniform. The process is carried out in such a manner that the molten element is prevented from solidifying while in contact with the sheet, and the solidification of the element on the sheet takes place after formation of the film on the sheet. Electrode made of a sheet coated with a layer of lithium whose thickness is 0.1 to 40.mu..
摘要:
Process of manufacturing thin electrodes, supported on an electronically conductive sheet, the electrodes being made from an element selected from lithium, lithium alloy, or doped lithium, whose melting point does not differ from the melting point of lithium by .+-.50.degree. C. and whose thickness is constant, from a roller of the sheet and a source of the element. According to the invention, there is provided a bath of the element in molten state, the sheet is continuously unrolled, a constant quantity of the molten element is continuously applied on one of the two faces of the sheet, so as to produce a film on the sheet, whose thickness is constant and between about 0.1 and about 40.mu. and whose surface is homogeneous and uniform. The process is carried out in such a manner that the molten element is prevented from solidifying while in contact with the sheet, and the solidification of the element on the sheet takes place after formation of the film on the sheet. Electrode made of a sheet coated with a layer of lithium whose thickness is 0.1 to 40.mu..
摘要:
A method and a device for detecting a gaseous anhydride and measuring its concentration in an oxygen-bearing gas. The method comprises the following steps: (a) forming an electrolytic junction by contact between a first solid-electrolyte element containing oxyanions of the anhydride to be detected and a second, 0.sup.-- ion-conducting solid-electrolyte element such as stabilized zirconia; (b) bringing this electrolytic junction into contact with the gas containing the gaseous anhydride to be detected so as to form a triple junction; (c) creating at this triple junction a difference of potential measurable by means of two reference electrodes in contact with the first and second electrolyte elements respectively, by fixation of a constant potential in the vicinity of each of these reference electrodes, which themselves are spatially removed from the triple junction; (d) heating the triple junction to such a temperature that a logarithmic variation in the concentration of the anhydride to be detected produces a proportional, substantially linear variation in the difference of potential at the triple junction, this temperature being lower than the melting temperatures of the first and second electrolyte elements; and (e) measuring this difference of potential by means of a potentiometer connected to the reference electrodes so as to obtain a measurement of the concentration of the anhydride to be detected. This method and device may advantageously be used for detecting sulfur carbon anhydrides.
摘要:
A guide is provided for the buckets of an endless dredging line comprising an emptying station incorporated into the guide. A system comprising a pair of trolleys and a pulley system is provided to hold each bucket stationary at the emptying station for dumping. The endless line travels over the pulleys, some of which are mounted on the trolleys. When a bucket approaches the emptying station, the trolleys are actuated to travel in opposite directions so as to allow the endless line to move at its normal speed while holding the bucket at the dumping station stationary.
摘要:
A process to induce polymerization of an organic electronically conductive polymer in the presence of a partially delithiated alkali metal phosphate which acts as the polymerization initiator.
摘要:
Process for the purification of an ionic electrolyte comprising at least one alkali metal salt, the process having at least one stage in which particles of at least one calcium salt are brought into contact. The process makes it possible to obtain electrolytes characterized in particular by a particularly low water content. The corresponding electrochemical generators which incorporate the electrolyte as constituent component are characterized by a noteworthy stability and are particularly safe.