公开(公告)号：US20050054694A1

公开(公告)日：2005-03-10

申请号：US10491453

申请日：2002-10-02

Applicant: Kenneth Seddon ,  Christopher Hardacre ,  Barry McAuley

Inventor： Kenneth Seddon ,  Christopher Hardacre ,  Barry McAuley

IPC: B01J31/26 ,  B01J27/125 ,  B01J31/02 ,  B01J31/40 ,  B01J37/04 ,  B01J38/00 ,  C07B41/06 ,  C07B61/00 ,  C07C45/46 ,  C07C49/784 ,  C07C49/84 ,  B01J31/00 ,  C07D285/14

CPC classification number: B01J31/0284 ,  B01J27/125 ,  B01J31/0239 ,  B01J31/0244 ,  B01J31/0288 ,  B01J31/26 ,  B01J31/4015 ,  B01J2231/4205 ,  C07B41/06 ,  C07C45/46 ,  Y02P20/584 ,  C07C49/84 ,  C07C49/67

Abstract: Disclosed is a catalyst composition based on an indium salt and an organic ionic liquid, a process for making the catalyst composition, and uses thereof. The catalyst composition is particularly suitable for Lewis acid catalysed electrophilic aromatic substitution reactions, such as Friedel-Crafts alkylation reactions an Friedel-Crafts acylation reactions.

Abstract translation: 公开了一种基于铟盐和有机离子液体的催化剂组合物，制备催化剂组合物的方法及其用途。 催化剂组合物特别适用于路易斯酸催化的亲电芳族取代反应，如Friedel-Crafts烷基化反应，Friedel-Crafts酰化反应。

公开(公告)号：US06831141B2

公开(公告)日：2004-12-14

申请号：US09909152

申请日：2001-07-19

Applicant: Max P. McDaniel ,  Elizabeth A. Benham ,  Shirley J. Martin ,  Kathy S. Collins ,  James L. Smith ,  Gil R. Hawley ,  Christopher E. Wittner ,  Michael D. Jensen

Inventor： Max P. McDaniel ,  Elizabeth A. Benham ,  Shirley J. Martin ,  Kathy S. Collins ,  James L. Smith ,  Gil R. Hawley ,  Christopher E. Wittner ,  Michael D. Jensen

IPC: C08F4642

CPC classification number: B01J31/143 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J27/053 ,  B01J27/125 ,  B01J31/1608 ,  B01J31/2295 ,  B01J31/38 ,  B01J35/10 ,  B01J37/0207 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F110/02 ,  C08F4/65916 ,  C08F2500/12 ,  C08F2500/03

Abstract: A process of using a catalyst composition to polymerize at least one monomer to produce a polymer. The process comprises contacting the catalyst composition and at least one monomer in a polymerization zone under polymerization conditions to produce the polymer. The catalyst composition is produced by a process comprising contacting at least one organometal compound, at least one treated solid oxide compound, and at least one organoaluminum compound.

Abstract translation: 使用催化剂组合物聚合至少一种单体以制备聚合物的方法。 该方法包括在聚合条件下使催化剂组合物和聚合区中的至少一种单体接触以产生聚合物。 催化剂组合物通过包括使至少一种有机金属化合物，至少一种经处理的固体氧化物化合物和至少一种有机铝化合物接触的方法制备。

公开(公告)号：US06791001B2

公开(公告)日：2004-09-14

申请号：US10072873

申请日：2002-02-12

Applicant: Paolo Cuzzato ,  Letanzio Bragante

Inventor： Paolo Cuzzato ,  Letanzio Bragante

IPC: C07C2100

CPC classification number: B01J27/125 ,  C07C17/358 ,  C07C19/12

Abstract: A process in gaseous phase to obtain CFC 113a starting from CFC 113, wherein CFC 113, optionally diluted with a gas inert under the reaction conditions, is let flow on a catalyst formed by aluminum fluoride.

Abstract translation: 气相中从CFC 113开始获得CFC 113a的方法，其中CFC 113（其任选地在反应条件下用惰性气体稀释）在由氟化铝形成的催化剂上流动。

公开(公告)号：US06525227B1

公开(公告)日：2003-02-25

申请号：US09762102

申请日：2001-04-04

Applicant: Shu Kobayashi

Inventor： Shu Kobayashi

IPC: C07C4500

CPC classification number: C07C45/72 ,  B01J27/10 ,  B01J27/125 ,  B01J35/002 ,  B01J2531/96 ,  C07C45/511 ,  C07C49/83

Abstract: A reaction method by a novel Lewis acid catalyst stable in water for organic synthesis by using a metal compound stable in water and functioning as a Lewis acid catalyst and using water as apart or all of a solvent, the metal ion of the metal compound having a hydrolysis constant (pKh) of: 4.3≦pKh≦10.1 and a water exchange rate constant (WERC) of 3.2×106M−1sec−1 or more.

Abstract translation: 一种通过使用在水中稳定并用作路易斯酸催化剂并用作分离或全部溶剂的水的金属化合物在水中稳定用于有机合成的新型路易斯酸催化剂的反应方法，金​​属化合物的金属离子具有 水解常数（pKh）为：4.3 <= pKh <= 10.1，水交换率常数（WERC）为3.2×106M-1sec-1以上。

公开(公告)号：US06365544B2

公开(公告)日：2002-04-02

申请号：US09314920

申请日：1999-05-19

Applicant: Norman Herron ,  Leo E. Manzer ,  Munirpallam A. Subramanian

Inventor： Norman Herron ,  Leo E. Manzer ,  Munirpallam A. Subramanian

IPC: B01J2340

CPC classification number: C10G2/331 ,  B01J23/8896 ,  B01J27/12 ,  B01J27/125 ,  B01J27/128 ,  B01J37/0201 ,  C07C1/0435 ,  C07C1/044 ,  C07C1/0445 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/34 ,  C07C2523/36 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/889 ,  C07C2527/12 ,  C07C2527/125 ,  C07C2527/14 ,  C10G2/332

Abstract: A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium); and a support selected from the group consisting of an aluminum fluoride and fluorided aluminas.

Abstract translation: 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂包括至少一种用于费 - 托反应的催化金属（例如铁，钴，镍和/或钌）; 和选自氟化铝和氟化氧化铝的载体。

公开(公告)号：US06333294B1

公开(公告)日：2001-12-25

申请号：US09314811

申请日：1999-05-19

Applicant: Wenchun Chao ,  Kamel M. Makar ,  Leo E. Manzer ,  Munirpallam A. Subramanian

Inventor： Wenchun Chao ,  Kamel M. Makar ,  Leo E. Manzer ,  Munirpallam A. Subramanian

IPC: B01J2300

CPC classification number: C10G2/331 ,  B01J23/8896 ,  B01J27/12 ,  B01J27/125 ,  B01J27/128 ,  B01J37/0201 ,  C07C1/0435 ,  C07C1/044 ,  C07C1/0445 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/34 ,  C07C2523/36 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/889 ,  C07C2527/12 ,  C07C2527/125 ,  C07C2527/14 ,  C10G2/332

Abstract: A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least cobalt, rhenium, and a promoter selected from the group including boron, phosphorus, potassium, manganese, and vanadium. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.

Abstract translation: 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂至少包括钴，铼和选自硼，磷，钾，锰和钒的助催化剂。 催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。

公开(公告)号：US20010053835A1

公开(公告)日：2001-12-20

申请号：US09747509

申请日：2000-12-19

Applicant: Exxon Chemical Patents Inc.

Inventor： Frank Joung-yei Chen ,  Christophe Le Deore ,  Roger Spitz ,  Alain Louis Pierre Lenack

IPC: C08F004/14

CPC classification number: B01J27/08 ,  B01J27/10 ,  B01J27/125 ,  B01J27/138

Abstract: A supported Lewis acid catalyst system effective for hydrocarbon conversion reactions including cationic polymerization, alkylation, isomerization and cracking reactions and comprising at least one Lewis acid immobilized on an anhydrous dihalide of Cd, Fe, Co, Ni, Mn or Mg is disclosed.

Abstract translation: 公开了一种对包括阳离子聚合，烷基化，异构化和裂解反应在内的烃转化反应有效的载体的路易斯酸催化剂体系，并且包含固定在Cd，Fe，Co，Ni，Mn或Mg的无水二卤化物上的至少一种路易斯酸。

公开(公告)号：US20010051588A1

公开(公告)日：2001-12-13

申请号：US09314920

申请日：1999-05-19

Inventor： NORMAN HERRON ,  LEO E. MANZER ,  MUNIRPALLAM A. SUBRAMANIAN

IPC: B01J023/00 ,  B01J023/40 ,  B01J023/42 ,  B01J027/128 ,  C07C027/00 ,  C07C027/06

CPC classification number: C10G2/331 ,  B01J23/8896 ,  B01J27/12 ,  B01J27/125 ,  B01J27/128 ,  B01J37/0201 ,  C07C1/0435 ,  C07C1/044 ,  C07C1/0445 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/34 ,  C07C2523/36 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/889 ,  C07C2527/12 ,  C07C2527/125 ,  C07C2527/14 ,  C10G2/332

Abstract: A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium); and a support selected from the group consisting of an aluminum fluoride and fluorided aluminas.

Abstract translation: 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂包括至少一种用于费 - 托反应的催化金属（例如铁，钴，镍和/或钌）; 和选自氟化铝和氟化氧化铝的载体。

公开(公告)号：US06316681B1

公开(公告)日：2001-11-13

申请号：US08982803

申请日：1996-12-04

Applicant: Satoshi Yoshikawa ,  Ryouichi Tamai ,  Fuyuhiko Sakyu ,  Yasuo Hibino ,  Yoshihiko Gotoh

Inventor： Satoshi Yoshikawa ,  Ryouichi Tamai ,  Fuyuhiko Sakyu ,  Yasuo Hibino ,  Yoshihiko Gotoh

IPC: C07C1708

CPC classification number: C07C19/08 ,  B01J27/125 ,  C07C17/00 ,  C07C17/21 ,  C07C21/18

Abstract: The present invention relates to a method for producing 1,1,1,3,3-pentafluoropropane. This method includes a first step of fluorinating 1-chloro-3,3,3-trifluoropropene in a liquid phase by hydrogen fluoride in the presence of an antimony compound as a catalyst, or a second step of fluorinating 1-chloro-3,3,3-trifluoropropene in a gas phase by hydrogen fluoride in the presence of a fluorination catalyst. If the first step is taken, 1,1,1,3,3-pentafluoropropane can be produced with a high yield. If the second step is taken, 1,1,1,3,3-pentafluoropropane can continuously be easily produced. Therefore, the second step is useful for an industrial scale production thereof. According to the invention, 1-chloro-3,3,3-trifluoropropene may be produced by a method including a step of reacting 1,1,1,3,3-pentachloropropane with hydrogen fluoride in a gas phase in the presence of a fluorination catalyst. This method is useful, because yield of 1-chloro-3,3,3-trifluoropropene is high.

公开(公告)号：US06300530B1

公开(公告)日：2001-10-09

申请号：US09305676

申请日：1999-05-05

Applicant: Paolo Cuzzato

Inventor： Paolo Cuzzato

IPC: C07C1708

CPC classification number: C07C17/206 ,  B01J23/26 ,  B01J27/125 ,  B01J27/132 ,  C07C19/08 ,  C07C19/12

Abstract: Catalyst comprising a supported Cr(III) amorphous compound, characterized in that the support is formed by an aluminum trifluoride (AlF3) having an high surface area obtainable by alumina fluorination with gaseous HF at an initial temperature lower than 300° C., the temperature is rised with a temperature gradient≦100° C./hour up to the final temperature>320° C. and

Abstract translation: 催化剂，其包含负载的Cr（III）无定形化合物，其特征在于，所述载体由具有高表面积的三氟化铝（AlF 3）形成，所述三氟化铝通过在低于300℃的初始温度下用气态HF进行氧化铝氟化获得， 在温度梯度<= 100℃/小时之前升温至最终温度> 320℃和<450℃，氟化在最终温度下继续进行，直到进料​​至少等于 化学计量相对于氧化铝，进行氟化，直到获得氟含量不低于化学计量的95％的氟化氧化铝。