Shrink wrap labels for shaped articles

    公开(公告)号:US10858545B2

    公开(公告)日:2020-12-08

    申请号:US16569699

    申请日:2019-09-13

    摘要: Methods for applying high shrink wrap labels to a shaped article are disclosed. The leading edge of the label is bonded to the article. A seaming agent is applied, and the label is wrapped around the article. The seaming agent is then exposed to radiation to cure the seaming agent, and the label is then exposed to heat to cause heat-shrinking. The label is made of a film with at least one external layer that has a Hildebrand solubility parameter. The seaming agent includes a component having a Hildebrand solubility parameter that is within 2.2 MPa1/2 or within 4.4 calories1/2·cm−3/2 of the Hildebrand solubility parameter of the external layer of the film. The seaming agent also has a viscosity of at least 1 centipoise and less than 1000 centipoise when measured at any temperature between ambient temperature and 60° C. Articles including such affixed high shrink wrap labels are also disclosed.

    Light curable composition
    75.
    发明授权

    公开(公告)号:US10828240B2

    公开(公告)日:2020-11-10

    申请号:US16328984

    申请日:2017-08-30

    摘要: A photocurable composition is provided, which is characterized by comprising a polymerizable monomer component (A), an inorganic filler component (B) having an average particle diameter of 0.07 μm or more, an organic-inorganic composite filler component (C) comprising an inorganic filler component (C1) and an organic polymer component (C2) and having an average particle diameter of 0.5 μm or more, and a photopolymerization initiator (D), wherein the inorganic filler component (B) and the organic-inorganic composite filler component (C) are contained in a total amount of 100 to 1500 parts by mass relative to 100 parts by mass of the polymerizable monomer component (A), and the polymerizable monomer component (A), 90 parts by mass or more of the inorganic filler component (B) and 90 parts by mass or more of the organic-inorganic composite filler component (C) are selected in such a manner that specific requirements can be satisfied.

    Photoinitiators functioned as both initiators and nanofillers

    公开(公告)号:US10711019B2

    公开(公告)日:2020-07-14

    申请号:US15752866

    申请日:2016-08-17

    摘要: This invention relates to a photoinitiator compound comprising: a polyhedral oligomeric silsesquioxane (POSS) moiety and a photoinitiator moiety, wherein the photoinitiator compound having the structure according to formula (I): [R—SiO1.5]n (I), wherein n is 6, 8, 10 or 12 and R is independently selected from the group consisting of H, linear or branched (hetero)alkyl, linear or branched (hetero)alkenyl, (hetero)aryl, (hetero)alkyl aryl, (hetero)aryl alkyl and a photoinitiator moiety, wherein at least one R is a photoinitiator moiety and the photoinitiator compound is a nanoparticle. The present invention also relates to a method for the production of the photoinitiator compound of the invention, a photopolymerizable composition comprising the photoinitiator compound of the invention, the use of the photoinitiator compound of the invention for photopolymerization. The present invention is further related to a coated substrate comprising the photopolymerizable composition of the invention.