公开(公告)号：US10017643B2

公开(公告)日：2018-07-10

申请号：US15029697

申请日：2014-10-24

Applicant: POLYPLASTICS CO., LTD.

Inventor： Hiroki Arai

IPC: C08L81/04 ,  C08J3/20 ,  C08L67/02 ,  C08L101/00 ,  C09D181/04 ,  C08G77/442

CPC classification number: C08L81/04 ,  C08G77/442 ,  C08J3/20 ,  C08K7/14 ,  C08L51/085 ,  C08L67/02 ,  C08L83/04 ,  C08L101/00 ,  C08L2201/08 ,  C09D181/04

Abstract: A corona-resistant resin composition and a corona-resistant member, having sufficient durability relative to corona discharge, are provided. A corona-resistant resin composition obtained, at least, by melt kneading 7 to 80 parts by mass of a silicone-based polymer per 100 parts by mass of a resin component, and a corona-resistant member formed by molding the corona-resistant resin composition, are disclosed. A polyarylene sulfide resin or a polybutylene terephthalate resin may be used as the resin component.

公开(公告)号：US20170306141A1

公开(公告)日：2017-10-26

申请号：US15510381

申请日：2015-06-11

Applicant: Polyplastics Co., Ltd.

Inventor： Akihide SHIMODA

IPC: C08L59/00 ,  F16C33/20

Abstract: A polyoxymethylene (POM) resin composition which is used for a resin molded article having an excellent sliding characteristic and wear resistance property and also having an excellent surface property and peeling resistance property. This POM resin composition contains: (A) 100 parts by mass of a POM resin; (B) 0.01-1 parts by mass of a hindered phenolic antioxidant; (C) 0.05-1 parts by mass inclusive of a nitrogen-containing compound; (D) 0.5-10 parts by mass of a modified olefin polymer which is an olefin polymer that has been modified by an unsaturated carboxylic acid or the like; (E) 0.01-5 parts by mass of an alkylene glycol polymer that has a primary or secondary amino group and a number average molecular weight of 400-500,000; (F) 0.1-20 parts by mass of calcium carbonate which has a BET specific surface area of 15 m2/g or less, has a mean particle size of 50-200 nm or less, is surface-untreated, and is substantially cubic; (G) 0.1-10 parts by mass of a partial ester of a divalent to tetravalent alcohol; and (H) 0.1-10 parts by mass of an α-olefin oligomer.

公开(公告)号：US20170096557A1

公开(公告)日：2017-04-06

申请号：US15128015

申请日：2015-03-17

Applicant: Polyplastics Co., Ltd.

Inventor： Katsuhei OHNISHI ,  Tatsuya KANEZUKA ,  Sei WAKATSUKA

IPC: C08L81/02 ,  B32B27/28 ,  B29C47/02 ,  B29C45/14 ,  B29C45/00 ,  B29C47/00 ,  B32B15/08 ,  B32B27/20

CPC classification number: C08L81/02 ,  B29B9/06 ,  B29C45/0001 ,  B29C45/14 ,  B29C48/022 ,  B29C48/04 ,  B29C48/15 ,  B29C48/402 ,  B29K2081/04 ,  B29K2705/00 ,  B32B15/08 ,  B32B27/20 ,  B32B27/286 ,  B32B2250/02 ,  B32B2262/101 ,  B32B2264/104 ,  B32B2457/00 ,  B32B2605/00 ,  C08J5/043 ,  C08J2381/04 ,  C08J2423/08 ,  C08K2003/265 ,  C08L2201/08 ,  C08L2203/20 ,  C08L2205/06

Abstract: A polyarylene sulfide-derived resin composition which has flowability optimal for insert molding and which can impart superior high- and low-temperature impact properties to a molded body, and an insert-molded body using the resin composition. The resin composition includes a polyarylene sulfide resin having carboxylic terminal groups, an olefin-derived copolymer, glass fibers and calcium carbonate. The weight-average molecular weight of the polyarylene sulfide resin is 15,000-40,000; as copolymerization components, the olefin-derived copolymer includes α-olefins, glycidyl esters of α,β-unsaturated acids, and acrylic esters, and the content of the copolymerization component derived from the glycidyl esters in the resin composition is 0.2-0.6 mass %. Further, the fiber diameter of the glass fibers is 9-13 μm, the average particle diameter of the calcium carbonate is 10-50 μm, and the total content of glass fibers and the calcium carbonate is 45-55 mass % of the resin composition.

公开(公告)号：US20170073451A1

公开(公告)日：2017-03-16

申请号：US15119561

申请日：2014-12-10

Applicant: Polyplastics Co., Ltd.

Inventor： Tadahiro HORIGUCHI ,  Eiji MASUDA

IPC: C08G2/06 ,  C08G2/28 ,  C08G2/10

CPC classification number: C08G2/06 ,  C08G2/04 ,  C08G2/10 ,  C08G2/28

Abstract: A process for producing a polyacetal copolymer, the process making catalyst deactivation easy and efficient. Trioxane as a major monomer is copolymerized with one or more comonomers that are a cyclic ether and/or cyclic formal having at least one carbon-carbon bond, using a nonvolatile protonic acid as a polymerization catalyst at 100° C. or lower until the conversion reaches 50% and thereafter at a polymerization environment temperature of 115° C. to 140° C. This process includes: a crushing step in which a dry-process crusher is used to obtain a crude polyacetal copolymer crushed to such a degree that when the crude copolymer is screened with a sieve having an opening size of 11.2 mm, 90 parts by weight or more thereof passes therethrough; and a deactivation step in which a basic compound (e) is added to the crude copolymer and the mixture is melt-kneaded to thereby deactivate the polymerization catalyst.

Abstract translation: 一种生产聚缩醛共聚物的方法，使催化剂失活的方法简单高效。 作为主要单体的三恶烷与一种或多种作为具有至少一个碳 - 碳键的环醚和/或环状缩甲醛的共聚单体共聚，使用非挥发性质子酸作为聚合催化剂，在100℃以下直至转化 达到50％，之后在115℃至140℃的聚合环境温度下进行。该方法包括：破碎步骤，其中使用干法破碎机获得粗聚缩醛共聚物，该聚缩醛共聚物被粉碎至如 粗共聚物用开口尺寸为11.2mm的筛子筛选，其中90重量份以上通过; 以及将碱性化合物（e）加入到粗共聚物中并使混合物熔融捏合以使聚合催化剂失活的失活步骤。

公开(公告)号：US09546241B2

公开(公告)日：2017-01-17

申请号：US14786249

申请日：2014-04-04

Applicant: Polyplastics Co., Ltd.

Inventor： Tomohiro Monma ,  Eiji Masuda ,  Shoji Sanada

IPC: C08G2/24 ,  C08G2/10 ,  C08G2/06 ,  C08G2/22 ,  C08G4/00 ,  C08L59/04 ,  C08G2/12

CPC classification number: C08G2/24 ,  C08G2/06 ,  C08G2/10 ,  C08G2/22 ,  C08G4/00 ,  C08L59/04

Abstract: A high-quality polyacetal copolymer produced by a simple process in an economical manner. The process includes supplying a raw material including trioxane and the like to a reaction device; setting the polymerization environmental temperature to no more than 100° C. until the reaction device conversion rate becomes 0.5, and then carrying out further polymerization; vaporizing and separating unreacted monomers from the reaction mixture at an environmental temperature of at least 115° C. and less than 140° C.; supplying the separated monomers to the raw material supply; and recovering the polyacetal copolymer from the reaction mixture.

Abstract translation: 以经济的方式通过简单的方法生产的高品质聚缩醛共聚物。 该方法包括向反应装置供应包括三恶烷等的原料; 将聚合环境温度设定在不超过100℃，直到反应装置转化率达到0.5，然后进行进一步的聚合; 在至少115℃且小于140℃的环境温度下从反应混合物中蒸发和分离未反应的单体; 将分离的单体供应给原料供应; 并从反应混合物中回收聚缩醛共聚物。

公开(公告)号：US20160280917A1

公开(公告)日：2016-09-29

申请号：US15029697

申请日：2014-10-24

Applicant: POLYPLASTICS CO., LTD.

Inventor： Hiroki ARAI

IPC: C08L81/04 ,  C09D181/04

CPC classification number: C08L81/04 ,  C08G77/442 ,  C08J3/20 ,  C08K7/14 ,  C08L51/085 ,  C08L67/02 ,  C08L83/04 ,  C08L101/00 ,  C08L2201/08 ,  C09D181/04

Abstract: A corona-resistant resin composition and a corona-resistant member, having sufficient durability relative to corona discharge, are provided. A corona-resistant resin composition obtained, at least, by melt kneading 7 to 80 parts by mass of a silicone-based polymer per 100 parts by mass of a resin component, and a corona-resistant member formed by molding the corona-resistant resin composition, are disclosed. A polyarylene sulfide resin or a polybutylene terephthalate resin may be used as the resin component.

Abstract translation: 提供具有相对于电晕放电具有足够的耐久性的耐电晕树脂组合物和耐电晕构件。 至少通过每100质量份树脂成分将7〜80质量份的硅酮系聚合物熔融混炼得到的耐电晕树脂组合物，以及通过将抗电晕树脂 组合物。 可以使用聚芳硫醚树脂或聚对苯二甲酸丁二醇酯树脂作为树脂组分。

公开(公告)号：US20160251509A1

公开(公告)日：2016-09-01

申请号：US15149952

申请日：2016-05-09

Applicant: Polyplastics Co., Ltd.

Inventor： Akihide SHIMODA ,  Satomi NAKADA ,  Yasumitsu MIYAMOTO ,  Hidemi KONDO

IPC: C08L59/04 ,  C08J7/14

CPC classification number: C08L59/04 ,  C08J7/14 ,  C08J2359/02 ,  C08K3/22 ,  C08K5/103 ,  C08K5/134 ,  C08K5/1345 ,  C08K2003/222 ,  C08L71/02 ,  C08L2201/08 ,  F02M2200/9015

Abstract: A polyacetal resin composition makes it possible, when formed into a molded article, to minimize deterioration during contact with sulfur-containing fuel or an acidic detergent. The polyacetal resin composition contains (A) 100 parts by weight of polyacetal resin, (B) 0.1-1.0 parts by weight of hindered phenolic antioxidant, (C) 0.1-2.0 parts by weight of alkaline earth metal oxide, (D) 0.5-3.0 parts by weight of polyalkylene glycol, and (E) 0.01-1.0 parts by weight of polyvalent fatty acid full ester. This polyacetal resin composition minimizes reductions in the weight of a molded article even after the molded article has been immersed in sulfur-containing fuel.

Abstract translation: 聚缩醛树脂组合物可以在形成模塑制品时使与硫含量燃料或酸性洗涤剂接触时的劣化最小化。 聚缩醛树脂组合物含有（A）100重量份的聚缩醛树脂，（B）0.1-1.0重量份的受阻酚类抗氧化剂，（C）0.1-2.0重量份的碱土金属氧化物，（D） 3.0重量份聚亚烷基二醇，和（E）0.01-1.0重量份多价脂肪酸全酯。 即使在模制品浸入含硫燃料中之后，该聚缩醛树脂组合物也使模制品的重量减少最小化。

公开(公告)号：US20150247034A1

公开(公告)日：2015-09-03

申请号：US14427857

申请日：2013-09-25

Applicant: DAICEL CORPORATION ,  POLYPLASTICS CO., LTD

Inventor： Kohji Nakatani ,  Yoko Hashizume ,  Katsutoshi Sakamoto ,  Yoshiaki Taguchi

IPC: C08L67/03 ,  C08L35/00 ,  C09K19/38

CPC classification number: C08L67/03 ,  C08G63/916 ,  C08J3/243 ,  C08J5/24 ,  C08J2367/03 ,  C08J2367/07 ,  C08L35/00 ,  C09K19/3809

Abstract: Provided is a thermosetting composition that can be cured at a relatively low temperature and gives a cured product having excellent heat resistance.The thermosetting composition according to the present invention is a thermosetting liquid-crystal polyester composition prepared by melt-blending a liquid-crystal polyester (A) and a compound (B) with each other. The liquid-crystal polyester (A) includes at least one of hydroxy and acyloxy at molecular chain end. The compound (B) includes a first functional group and a second functional group in molecule. The first functional group is reactive with the at least one of hydroxy and acyloxy. The second functional group is thermally polymerizable. In the thermosetting liquid-crystal polyester composition, the liquid-crystal polyester (A) is preferably a liquid-crystal polyester that contains a monomer unit derived from an aromatic compound and has an average degree of polymerization of from 3 to 30 and a melting point of 250° C. or lower.

Abstract translation: 本发明提供一种可在较低温度下固化的热硬化性组合物，得到耐热性优异的固化物。 根据本发明的热固性组合物是通过将液晶聚酯（A）和化合物（B）彼此熔融共混制备的热固性液晶聚酯组合物。 液晶聚酯（A）在分子链末端包含羟基和酰氧基中的至少一个。 化合物（B）分子中含有第一官能团和第二官能团。 第一官能团与羟基和酰氧基中的至少一种反应。 第二官能团是可热聚合的。 在热固性液晶聚酯组合物中，液晶聚酯（A）优选为含有来自芳香族化合物的单体单元，平均聚合度为3〜30，熔点 为250℃以下。

公开(公告)号：US08967207B2

公开(公告)日：2015-03-03

申请号：US13910555

申请日：2013-06-05

Applicant: Polyplastics Co., Ltd.

Inventor： Shigeru Nezu ,  Masumi Tanikita

IPC: F16L11/00 ,  F16L9/133

CPC classification number: F16L9/133 ,  Y10T428/1393 ,  Y10T428/31533

Abstract: The present invention provides a highly heat-resistant multi-layer molded article having excellent adhesion between layers and which can be inexpensively produced and easily recycled. The multi-layer molded article comprises an innermost layer including a first polyarylene sulfide-derived resin composition having 95% to 91% by mass of a polyarylene sulfide-derived resin and 5% to 9% by mass of an olefinic (olefine-derived) elastomer, and an outer layer disposed on an outer-side of the innermost layer, including a second polyarylene sulfide-derived resin composition having 5 to 35 parts by mass of reinforced fibers and 100 parts by mass of a third polyarylene sulfide-derived resin composition having 95% to 80% by mass of a polyarylene sulfide-derived resin and 5% to 20% by mass of an olefinic elastomer.

Abstract translation: 本发明提供了一种具有优异的层间粘附性的高耐热性多层成型体，能够廉价地制造并且易于再循环。 所述多层成型体包括由聚亚芳基硫醚衍生的树脂构成的具有95〜91质量％的第一聚芳硫醚系树脂组合物和5质量％〜9质量％的烯烃（烯烃衍生物）树脂组合物的最内层， 弹性体和设置在最内层的外侧的外层，包括第二聚芳撑硫醚衍生的树脂组合物，其具有5至35质量份增强纤维和100质量份第三聚芳撑硫醚衍生的树脂组合物 具有95〜80质量％的聚芳硫醚衍生的树脂和5〜20质量％的烯烃系弹性体。

公开(公告)号：US20020028905A1

公开(公告)日：2002-03-07

申请号：US09908495

申请日：2001-07-19

Applicant: POLYPLASTICS CO., LTD.

Inventor： Toshiaki Yokota

IPC: C08G063/00

CPC classification number: C08F246/00

Abstract: The invention provides a method for producing a thermotropic liquid crystalline polymer of high quality at high yield and in short polymerization time, which method includes polymerizing staring monomers I, II, III, and IV, i.e., (I) an aromatic hydroxycarboxylic acid, etc.; (II) an aromatic dicarboxylic acid and an alicyclic dicarboxylic acid; (III) an aromatic diol, an alicyclic diol, an aliphatic diol, etc.; and (IV) an aromatic hydroxylamine, an aromatic diamine, etc. in the presence of an acylating agent, wherein the starting materials are charged so as to satisfy the following equations (1) to (4):0.0015null((A)null(B))/((A)null(B))null0.006nullnull(1);1.01null(D)/(C)null1.08nullnull(2);0null(E)null40nullnull(3);and(D)/(C)nullnull0.002null(E)null1.04nullnull(4),wherein (A) denotes the total amount by equivalent (with respect to a carboxyl group) of starting monomers I and/or II; (B) denotes the total amount by equivalent (with respect to a hydroxyl group, an amino group, an ester derivative group thereof, and an amide derivative group thereof) of starting monomers I, III, and/or IV; (C) denotes the total amount by equivalent (with respect to a hydroxyl group and an amino group) of starting monomers I, III, and/or IV; (D) denotes the amount by equivalent of an acylating agent; and (E) denotes the amount of a catalyst (as reduced to amount by weight of metal, unit: ppm).

Abstract translation: 本发明提供一种以高产率和短聚合时间生产高质量热致液晶聚合物的方法，该方法包括将凝胶单体I，II，III和IV聚合，即（I）芳族羟基羧酸等 。 （II）芳族二羧酸和脂环族二羧酸; （III）芳族二醇，脂环族二醇，脂肪族二醇等; 和（IV）芳族羟胺，芳族二胺等，其中原料被充电以满足下列等式（1）至（4）：<段落lvl =“0” > 0.0015 <=（（A） - （B））/（（A）+（B））<= 0.006（1）; <段落lvl = 0“> 1.01 <=（D）/（C）<= 1.08（2）; 0 <=（E）<= 40（3）; 和<段落lvl =“0”> （D）/（C）> = - 0.002x E）+1.04（4），其中（A）表示起始单体I和/或II的当量总量（相对于羧基）; （B）表示起始单体I，III和/或IV的当量总量（相对于其羟基，氨基，酯衍生物基团和酰胺衍生物基团）; （C）表示起始单体I，III和/或IV的当量总量（相对于羟基和氨基）; （D）表示相当于酰化剂的量; 和（E）表示催化剂的量（按金属重量计，单位：ppm）。