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公开(公告)号:US11631829B2
公开(公告)日:2023-04-18
申请号:US16465666
申请日:2017-11-30
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Karissa L. Eckert , David Scott Thompson , Ryan M. Braun , Catherine A. Leatherdale , Michael A. Johnson , Steven D. Solomonson , Richard J. Pokorny , John J. Stradinger , Kevin R. Schaffer , Joseph D. Rule , Peter D. Condo , Derek W. Patzman
IPC: B32B27/40 , H01L51/52 , B32B7/12 , B32B27/08 , B32B27/30 , C08G18/24 , C08G18/34 , C08G18/42 , C08G18/66 , C08G18/78 , C08J5/18 , H01L51/00
Abstract: A display film includes a transparent polymeric substrate layer and a transparent energy dissipation layer disposed on the transparent polymeric substrate layer. The transparent energy dissipation layer includes cross-linked polyurethane and a polyacrylate polymer. The transparent energy dissipation layer has a glass transition temperature of 27 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater.
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公开(公告)号:US11584817B2
公开(公告)日:2023-02-21
申请号:US17048627
申请日:2019-06-26
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tianyu Wu , Saswata Chakraborty , Benjamin C. MacMurray , Richard J. Pokorny , Thomas P. Klun , Wayne S. Mahoney , Chad M. Amb , Ahmed S. Abuelyaman , Robert S. Clough , John M. Riedesel , James D. Hansen , Ian Dailey , Daniel J. Skamser , Eric W. Nelson , George W. Griesgraber , Dana R. Reed
IPC: C08F220/12 , B33Y10/00 , B33Y30/00 , B33Y70/00 , B33Y80/00 , B29C64/135 , A61K6/887 , A61K6/893 , A61C7/08 , B29K75/00 , B29K105/00 , B29L31/00
Abstract: Orthodontic articles and polymerizable resin compositions are described. The orthodontic article comprises a cured composition comprising the reaction product of free-radically polymerizable resin comprising 30 to 70 wt. %, inclusive, of at least one urethane component, and 25 to 70 wt. %, inclusive, of reactive diluent(s) comprising at least one monofunctional (meth)acrylate monomer. The polymerizable resin comprises no greater than 35 wt. % of reactive diluent(s) having a high affinity for water. Reactive diluent(s) such as monofunctional (meth)acrylate monomers having a high affinity for water have low log P values. In one embodiment, the polymerizable resin comprises at least one acidic monomer.
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公开(公告)号:US11503720B2
公开(公告)日:2022-11-15
申请号:US17270912
申请日:2019-09-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Saagar Shah , Mikhail L. Pekurovsky , Ankit Mahajan , Lyudmila A. Pekurovsky , Jessica Chiu , Jeremy K. Larsen , Kara A. Meyers , Teresa M. Goeddel , Thomas J. Metzler , Jonathan W. Kemling , Richard J. Pokorny , Benjamin R. Coonce , Chad M. Amb , Thomas P. Klun
Abstract: Flexible devices including conductive traces with enhanced stretchability, and methods of making and using the same are provided. The circuit die is disposed on a flexible substrate. Electrically conductive traces are formed in channels on the flexible substrate to electrically contact with contact pads of the circuit die. A first polymer liquid flows in the channels to cover a free surface of the traces. The circuit die can also be surrounded by a curing product of a second polymer liquid.
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公开(公告)号:US20220220333A1
公开(公告)日:2022-07-14
申请号:US17604945
申请日:2020-05-04
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , David Scott Thompson , John J. Stradinger , Catherine A. Leatherdale , Richard J. Pokorny , Steven D. Solomonson
IPC: C09D133/06 , C09D7/40
Abstract: A hardcoat composition includes one or more multifunctional (meth)acrylate monomers, and a nanoparticle mixture dispersed within the one or more multifunctional (meth)acrylate monomers. The nanoparticle mixture includes a first population of semi-reactive nanoparticles having an average particle diameter in a range from 5 nm to 60 nm, and a second population of non-reactive nanoparticles having an average particle diameter in a range from 5 nm to 60 nm.
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公开(公告)号:US20220169884A1
公开(公告)日:2022-06-02
申请号:US17436952
申请日:2020-04-08
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Chunjie Zhang , Jung-Sheng Wu , Thomas P. Klun , Richard J. Pokorny , Benjamin R. Coonce
IPC: C09D133/14 , C08F220/28 , C08K3/22 , C09D7/61 , C09D7/40 , C09D4/00
Abstract: A curable composition comprising components: a) alpha-alumina particles; b) 4-(2-(acryloyloxy)ethoxy)-4-oxobutanoic acid; c) at least one free-radically polymerizable compound different from component b); and d) optionally an effective amount of free-radical initiator. An at least partially cured reaction product of components comprising components a) to d), and an abrasion-resistant article including the same are also disclosed.
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公开(公告)号:US20210301042A1
公开(公告)日:2021-09-30
申请号:US17344096
申请日:2021-06-10
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Thomas P. Klun , Zeba Parkar , John M. Riedesel , Richard J. Pokorny , Chad M. Amb , Benjamin R. Coonce , Robert S. Clough , Tianyu Wu , Saswata Chakraborty , Yongshang Lu , Benjamin C. Mac Murray
IPC: C08F2/50 , B33Y10/00 , B33Y30/00 , B33Y70/00 , B29C64/129 , C08F2/44 , C08F220/18 , C08F290/06 , C08G18/44 , C08G18/67 , C08K5/00 , C08K5/3437
Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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公开(公告)号:US20210238328A1
公开(公告)日:2021-08-05
申请号:US17048627
申请日:2019-06-26
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tianyu Wu , Saswata Chakraborty , Benjamin C. Mac Murray , Richard J. Pokorny , Thomas P. Klun , Wayne S. Mahoney , Chad M. Amb , Ahmed S. Abuelyaman , Robert S. Clough , John M. Riedesel , James D. Hansen , Ian Dailey , Daniel J. Skamser , Eric W. Nelson , George W. Griesgraber , Dana R. Reed
IPC: C08F220/12 , A61K6/893 , A61K6/887 , B33Y80/00 , B33Y70/00 , B33Y30/00 , B33Y10/00 , B29C64/135
Abstract: Orthodontic articles and polymerizable resin compositions are described. The orthodontic article comprises a cured composition comprising the reaction product of free-radically polymerizable resin comprising 30 to 70 wt. %, inclusive, of at least one urethane component, and 25 to 70 wt. %, inclusive, of reactive diluent(s) comprising at least one monofunctional (meth)acrylate monomer. The polymerizable resin comprises no greater than 35 wt. % of reactive diluent(s) having a high affinity for water. Reactive diluent(s) such as monofunctional (meth)acrylate monomers having a high affinity for water have low log P values. In one embodiment, the polymerizable resin comprises at least one acidic monomer.
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公开(公告)号:US20210212216A1
公开(公告)日:2021-07-08
申请号:US17270912
申请日:2019-09-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Saagar Shah , Mikhail L. Pekurovsky , Ankit Mahajan , Lyudmila A. Pekurovsky , Jessica Chiu , Jeremy K. Larsen , Kara A. Meyers , Teresa M. Goeddel , Thomas J. Metzler , Jonathan W. Kemling , Richard J. Pokorny , Benjamin R. Coonce , Chad M. Amb , Thomas P. Klun
Abstract: Flexible devices including conductive traces with enhanced stretchability, and methods of making and using the same are provided. The circuit die is disposed on a flexible substrate. Electrically conductive traces are formed in channels on the flexible substrate to electrically contact with contact pads of the circuit die. A first polymer liquid flows in the channels to cover a free surface of the traces. The circuit die can also be surrounded by a curing product of a second polymer liquid.
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89.
公开(公告)号:US20210147648A1
公开(公告)日:2021-05-20
申请号:US17254483
申请日:2019-08-14
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Richard J. Pokorny , Joan M. Noyola , Zachary J. Malmberg , Thomas P. Klun , Moses M. David , Jun Ma , Cordell M. Hardy , Chad M. Amb
Abstract: Articles and intermediates are described comprising an organic polymeric base member and a hardcoat layer disposed on the organic polymeric base member, wherein the hardcoat layer can be stretched 25-75% without cracking. A siliceous layer is disposed on the hardcoat layer. The siliceous layer has a porosity of no greater than 10% and a thickness no greater than 1 micron. In some embodiments, the article further comprises a surface layer comprising a zwitterionic compound bonded to the siliceous layer.
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公开(公告)号:US20210095056A1
公开(公告)日:2021-04-01
申请号:US17042243
申请日:2019-05-21
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Thomas P. Klun , Zeba Parkar , John M. Riedesel , Richard J. Pokorny , Chad M. Amb , Benjamin R. Coonce , Robert S. Clough , Tianyu Wu , Saswata Chakraborty , Yongshang Lu , Benjamin C. Mac Murray , Ian Dailey , David B. Olson
IPC: C08F2/50 , C08F220/18 , C08F2/44 , C08F290/06 , C08G18/44 , C08G18/67 , C08K5/00 , C08K5/3437 , B29C64/129 , B33Y10/00 , B33Y30/00 , B33Y70/00
Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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