摘要:
A novel oxide material (MIN-I) comprising YO2; and X2O3, wherein Y is a tetravalent element and X is a trivalent element, wherein X/Y=O or Y/X=30 to 100 is provided. Surprisingly, MIN-I can be reversibly deswollen. MIN-I can further be combined with a polymer to produce a nanocomposite, depolymerized to produce predominantly fully exfoliated layers (MIN-2), and pillared to produce a pillared oxide material (MIN-3), analogous to MCM-36. The materials are useful in a wide range of applications, such as catalysts, thin films, membranes, and coatings.
摘要翻译:包含YO2的新型氧化物材料(MIN-I) 和X 2 O 3,其中Y是四价元素,X是三价元素,其中X / Y = O或Y / X = 30至100。 令人惊讶的是,MIN-I可以可逆地消除。 MIN-I可以进一步与聚合物结合以产生纳米复合材料,解聚以产生主要完全剥离的层(MIN-2),并且被柱形以产生类似于MCM-36的柱状氧化物材料(MIN-3)。 该材料可用于广泛的应用,如催化剂,薄膜,膜和涂料。
摘要:
A hybrid multichannel porous structure for processing between two fluid streams of different compositions includes a housing and one or more structures disposed within the cavity of the housing in a shell and tube configuration. Each structure includes a body made of a porous, inorganic material and a plurality of channels for processing an optional sweep stream. Each channel is coated with a membrane layer. A feed stream introduced into the housing is in direct contact with the structures such that a gas selectively permeates through the body and into the channels. The gas combines with the sweep stream to form a permeate that exits from each channel. The remaining feed stream forms a retentate that exits from the housing. The feed stream may consist of syngas containing hydrogen gas and the sweep stream may contain nitrogen gas. A power plant that incorporates the hybrid structure is disclosed.
摘要:
Example embodiments herein relate to a semi-permeable film including a nanoporous material and a polymer matrix. The nanoporous material includes a nanoporous core and a coating layer that is disposed on a surface of the nanoporous core. The coating layer may include a particle selected from a metal hydroxide particle, a metal oxide particle, and a combination thereof. A separation membrane may include the semi-permeable film. Example embodiments also relate to a method of manufacturing the semi-permeable film and the separation membrane.
摘要:
Process for fabricating a catalyzed ion transport membrane (ITM). In one embodiment, an uncatalyzed ITM is (a) contacted with a non-reducing gaseous stream while heating to a temperature and for a time period sufficient to provide an ITM possessing anion mobility; (b) contacted with a reducing gaseous stream for a time period sufficient to provide an ITM having anion mobility and essentially constant oxygen stoichiometry; (c) cooled while contacting the ITM with the reducing gaseous stream to provide an ITM having essentially constant oxygen stoichiometry and no anion mobility; and (d) treated by applying catalyst to at least one of (1) a porous mixed conducting multicomponent metallic oxide (MCMO) layer contiguous with a first side of a dense layer of MCMO and (2) a second side of the dense MCMO layer. In another embodiment, these steps are carried out in the alternative order of (a), (d), (b), and (c).
摘要:
A membrane structure is provided. The membrane structure includes an air permeable hydrophobic membrane having a first side and an opposite second side. An oleophobic conformal coating is applied across the membrane. Moreover, a porous polymeric coating is applied onto the first side and/or the second side of the membrane. A patterned layer of particles are applied onto the porous polymeric coating.
摘要:
The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature may be combined with a process of ceramic ultra-filtration (UF filtration) employed to treat water, and optionally followed by any of membrane distillation or forward osmosis (FO). Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.
摘要:
A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
摘要:
A modular element having a high-temperature stable main body, including at least one metallic or ceramic plate, which has at least one through-going aperture for the insertion of a ceramic capillary membrane and at least one potting in the form of a sufficiently gas-tight and high-temperature stable joint between the metallic or ceramic plate and the ceramic capillary membrane. The through-going aperture of the metallic or ceramic plate having an extension for accommodating the sufficiently gas-tight and high-temperature stable joint on at least one side of the metallic or ceramic plate.
摘要:
A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding core and sheath suspensions from a spinnerette. The core suspension includes particles of the first ceramic material, a polymeric binder, a solvent, and a pore former material insoluble in the solvent. The sheath suspension includes particles of the second ceramic material, a polymeric binder and a solvent. The nascent hollow fiber is coagulated in a coagulant bath to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders and pore former material are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the core.