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    Solid phosphoric acid catalyst and methods of olefin dimerization reaction with the same
    85.
    发明授权
    Solid phosphoric acid catalyst and methods of olefin dimerization reaction with the same 有权
    固体磷酸催化剂和烯烃二聚反应方法与此相同

    公开(公告)号：US08203025B2

    公开(公告)日：2012-06-19

    申请号：US11920816

    申请日：2006-05-25

    申请人： Tatsuo Hamamatsu ,  Nobuhiro Kimura ,  Tsutomu Takashima ,  Takashi Morikita

    发明人： Tatsuo Hamamatsu ,  Nobuhiro Kimura ,  Tsutomu Takashima ,  Takashi Morikita

    IPC分类号： C07C2/18

    CPC分类号： C07C2/18 ,  B01J27/16 ,  B01J27/182

    摘要： The invention provides a solid phosphoric acid catalyst which has high activity and attains high dimer selectivity in olefin dimerization reactions and efficient methods of olefin dimerization. The solid phosphoric acid catalyst comprises a carrier and phosphoric acid supported thereon. When the solid phosphoric acid catalyst is heated at 250° C. for 20 minutes, heating loss of water is 50 mass % or more based on diphosphorus pentoxide (P2O5) derived from the phosphoric acid. A method of olefin dimerization comprises bringing an olefin-containing feed material containing water in an amount of 10-1000 mass ppm into contact with the catalyst to initiate the reaction.

    摘要翻译： 本发明提供一种固体磷酸催化剂，其在烯烃二聚反应中具有高活性和高二聚体选择性，并且烯烃二聚的有效方法。 固体磷酸催化剂包括载体和负载在其上的磷酸。 当固体磷酸催化剂在250℃加热20分钟时，基于磷酸衍生的五氧化二磷（P 2 O 5），水的加热损失为50质量％以上。 烯烃二聚的方法包括将含有10-1000质量ppm的含有烯烃的进料与催化剂接触以引发反应。

    Process for production of acrolein
    86.
    发明授权
    Process for production of acrolein 有权
    丙烯醛生产工艺

    公开(公告)号：US07683220B2

    公开(公告)日：2010-03-23

    申请号：US12225823

    申请日：2007-03-27

    申请人： Etsushige Matsunami ,  Tsukasa Takahashi ,  Hiroto Kasuga ,  Yoshitaka Arita

    发明人： Etsushige Matsunami ,  Tsukasa Takahashi ,  Hiroto Kasuga ,  Yoshitaka Arita

    IPC分类号： C07C45/32

    CPC分类号： B01J27/182 ,  B01J21/08 ,  B01J27/16 ,  B01J27/1806 ,  B01J27/187 ,  B01J35/002 ,  B01J37/0201 ,  B01J37/03 ,  C07C45/52 ,  C07C47/22

    摘要： There is provided a process for producing acrolein from glycerin, exhibiting a suppressed decrease in the yield of acrolein with time. In the process for producing acrolein by dehydrating glycerin in the presence of a catalyst containing a metal phosphate, one, or two or more, metal phosphates are used, which are selected from aluminum salts, zirconium salts, manganese salts, alkali metal salts (provided that the alkali metal is sodium, potassium, or cesium, and the ratio between the mole number (M) of the alkali metal and the mole number (P) of phosphoric acid (i.e., M/P ratio) in the metal phosphate is 2.0 or lower), alkali earth metal salts (provided that the ratio between the mole number (M) of the alkali earth metal and the mole number (P) of phosphoric acid (i.e., M/P ratio) in the metal phosphate is 1.0 or lower), and the like.

    摘要翻译： 提供了一种从甘油制备丙烯醛的方法，随着时间的推移，丙烯醛的收率下降。 在含有金属磷酸盐，一种或两种以上的催化剂存在下，通过脱水甘油来制备丙烯醛的方法中，使用选自铝盐，锆盐，锰盐，碱金属盐的金属磷酸盐（提供 碱金属是钠，钾或铯，碱金属的摩尔数（M）与磷酸的摩尔数（P）之比（M / P比）在金属磷酸盐中的比例为2.0 或更低）碱土金属盐（条件是金属磷酸盐中碱土金属的摩尔数（M）与磷酸的摩尔数（P）之比（即M / P比）之比为1.0或 较低）等。