摘要:
A polyarylene sulfide resin composition contains a polyarylene sulfide containing at least one group selected from a group consisting of an amino group and an amide group, a polyamide resin, an epoxy resin and, as needed, a filler. A further composition contains 100 parts by weight of the polyarylene sulfide, 0.05 to 5 parts of the epoxy resin, and 5 to 400 parts of the filler. Another type of the resin composition contains the polyarylene sulfide, the polyamide, a compound selected from an acid, an acid anhydride and an acid halide, each having in its molecule not less than two functional groups reactive with the amino group or the amide group, and, as needed, the filler. A further type of the resin composition contains the polyarylene sulfide, the compound and, as needed, an inorganic filler subjected to surface treatment with a silane type coupling agent. A still further type of the resin composition contains the polyarylene sulfide and the compound. A still further type of the resin composition contains the polyarylene sulfide and the inorganic filler subjected to surface treatment with an epoxysilane type coupling agent.
摘要:
A laminated resin sheet consisting of (a) at least one layer of an ethylene-vinyl alcohol copolymeric resin (EVOH resin), (b) at least one layer of a hot-melt adhesive resin and (c) at least one layer of a polystrene-based resin, the layer (b) being interposed between the layers (a) and (c) to serve to adhesively bond them together. The laminated sheet has excellent moldability only when the EVOH resin has a thermal characteristic specified in terms of the integrated value of the peak areas in a diagram obtained by the DSC (differential scanning calorimetry) measurement in the course of temperature elevation. The sheet may be formed into a vessel having a multilayered wall structure by hot molding.
摘要:
In forming a diamond film on a surface of substrate by means of plasma method, there is employed in a plasma reacting chamber a supporting member having a top surface for placing the substrate so disposed as to be smaller than a bottom surface of the substrate and having engagement means for engaging with the substrate. When the substrate (particularly substrate for a cutting tool) placed on the top surface of the supporting member is brought into contact with plasma obtainable by exciting raw material gases, a diamond film is coated on the face, land and flank of the substrate for the cutting tool with a uniform film thickness.
摘要:
A curable phosphazene composition contains a curable phosphazene compound and a silicone-modified curable compound. The curable phosphazene composition is coated on a substrate and cured to form a coated article. The cured coating is excellent in surface hardness, slip properties and water repellency.
摘要:
Disclosed is a process for preparing a polyarylene sulfide, which involves polycondensing a dihalogenated aromatic compound with a source of sulfur in an organic polar solvent while dehydrating at pressure under which polycondensation is performed. This process avoids dehydration operation of the raw materials, particularly the source of sulfur, prior to polycondensation, thereby resulting in the production of the polyarylene sulfide having a high molecular weight.
摘要:
A curable resin composition is a blend of a curable phosphazene compound with a pentaerythritol acrylate compound and/or a bis(4-acryloxydialkoxyphenyl)alkane compound in a ratio of the former to the latter ranging from 90 to 10 to 5 to 95. The curable resin composition is provided with excellent properties such as a surface hardness, transparency and so on, and it can be cured at an improved curing rate.
摘要:
The present invention relates to a diamond-coated member characterized by superposing an acicular diamond layer, an intermediate layer formed by a metal belonging to either of the group IIIb, IVa, Va or VIa of the periodic table or by a compound containing the said metal, Si or B, and a non-acicular diamond layer on the surface of a base material and to a process for the preparation of a diamond-coated member characterized in that a diamond layer is formed on the surface of a base material by vapor phase synthesis method; the resulting diamond layer is converted into acicular diamond by exposing the resulting diamond layer to a gas obtainable by exciting an oxygen-containing etching gas; an intermediate layer comprising a metal belonging to either of the group IIIb, IVa, Va or VIa of the periodic table or by a compound containing the said metal, Si or B is formed on the resulting acicular diamond; and the resulting intermediate layer is exposed to a gas obtainable by exciting a raw material gas containing a carbon source gas. The diamond-coated member according to the present invention is useful as cutting tools and abrasion resistant members.
摘要:
Polyarylene sulfides are prepared by reacting a dihalogen aromatic compound with a sodium hydrosulfide in the presence of an alkali metal aminoalkanoate and a lithium halide in an organic polar solvent. This process can prevent a decomposition of the sodium hydrosulfide during dehydration and produce the polyarylene sulfides in a granular form in high yields and with high efficiency.The polyarylene sulfides obtainable by this process are high in molecular weight and degree of whiteness and low in a content of salts remaining therein. Furthermore, the polyarylene sulfides are in the granular form so that they can be handled with ease because of their readily separability and washability.
摘要:
Disclosed is a process for producing 2,2-bis(4'-hydroxyphenyl)propanes represented by the following general formula (2): ##STR1## (wherein R.sup.2 represents hydrogen atom or a hologen atom and the four R.sup.2 may be identical or different, R.sup.3 and R.sup.4 which may be identical or different represent hydrogen atom, an alkyl group, an aryl group, an aralkyl group, a cycloalkyl group, an alkoxy group or a halogen atom, p and q which may be identical or different represent integers of 1-4, a is 2 or 3 and b is 2 when a is 2 and is 1 when a is 3), characterized by reacting at least one phenol represented by the following formula (1): ##STR2## (wherein R.sup.1 has the same meaning as R.sup.3 and R.sup.4 and n is an integer of 1-4) with an unsaturated carbon compound represented by the general formula: C.sub.3 R.sub.4.sup.2 (wherein R.sup.2 has the same meaning as in the formula (2) and the four R.sup.2 may be identical or different) in the presence of hydrochloric acid.
摘要:
A process for preparing a linear .alpha.-olefin having from 4 to 20 carbon atoms is disclosed which comprises polymerizing ethylene or gas containing ethylene in the presence of a catalyst consisting of a zirconium halide, an organoaluminium compound and a Lewis base, and adding a catalyst deactivating agent to the resulting reaction mixture, wherein said Lewis base is at least one member selected from the group consisting of thioethers, alkyl disulfides, thiophenes, thiourea, sulfides, phosphines and primary amines.Use of the catalyst enables preparation of linear .alpha.-olefins of a high purity and reduction in the amount of by-produced wax.