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1.发明申请WATER REDUCIBLE COATING COMPOSITIONS INCLUDING CARBOXY ESTER KETALS, METHODS OF MANUFACTURE, AND USES THEREOF 有权水可降低涂料组合物，包括碳酸钾，其制备方法及其用途公开(公告)号：US20120094135A1
公开(公告)日：2012-04-19
申请号：US13276091
申请日：2011-10-18
IPC分类号： B32B27/00 , C09D163/00 , B05D3/00 , C09D167/00 , C09D167/08 , B05D7/24 , C08K5/1565 , C09D175/04
CPC分类号： C09D167/00 , C08G18/0866 , C08K5/06 , C08K5/156 , C09D167/08 , C09D175/06 , Y10T428/31855 , C08K5/0041
摘要： A water-reducible coating composition includes a water-reducible polymer binder; water; and a ketal adduct of formula (1) as well as coated substrates and films formed from the compositions. The films are useful as paints, stains, and clear-coats.
摘要翻译： 水可稀释的涂料组合物包括水可稀释的聚合物粘合剂; 水; 和式（1）的缩酮加合物以及由组合物形成的涂覆的基材和薄膜。 这些电影可用作油漆，污渍和清漆。
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公开(公告)号：US09212176B2
公开(公告)日：2015-12-15
申请号：US13294690
申请日：2011-11-11
申请人： Brian D. Mullen , Marc D. Scholten , Tara J. Mullen , Cora M. Leibig , Vivek Badarinarayana , Matthew J. Tjosaas
发明人： Brian D. Mullen , Marc D. Scholten , Tara J. Mullen , Cora M. Leibig , Vivek Badarinarayana , Matthew J. Tjosaas
IPC分类号： C07D407/12 , C08K5/1565 , C08L79/08 , C08L77/00 , C08L59/02
CPC分类号： C07D407/12 , C08K5/1565 , C08L59/02 , C08L77/00 , C08L79/08 , Y02P20/582 , C08L27/06
摘要： Disclosed herein is a polyketal adduct obtained by forming an ester between a hydrocarbon polyol and a ketocarboxylic acid to produce an intermediate polyketocarboxylic ester. The intermediate polyketocarboxylic ester can be purified via crystallization to achieve purities of greater than 99.0% and then ketalized to produce the polyketal adduct, which can be used in polymer compositions. The polyketal adduct I is obtained at high purity and at high yield.
摘要翻译： 本文公开了通过在烃多元醇和酮羧酸之间形成酯以产生中间体多酮羧酸酯而获得的聚缩酮加成物。 可以通过结晶纯化中间体多酮羧酸酯以实现大于99.0％的纯度，然后缩醛化以产生可用于聚合物组合物中的聚缩酮加合物。 以高纯度和高收率获得聚缩酮加成物I.
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公开(公告)号：US08846817B2
公开(公告)日：2014-09-30
申请号：US13294926
申请日：2011-11-11
申请人： Dorie J. Yontz , Brian D. Mullen , Cora M. Leibig , Marc D. Rodwogin , Vivek Badarinarayana , Feng Jing , Friederike T. Stollmaier
发明人： Dorie J. Yontz , Brian D. Mullen , Cora M. Leibig , Marc D. Rodwogin , Vivek Badarinarayana , Feng Jing , Friederike T. Stollmaier
IPC分类号： C08F8/12 , C08F218/10 , B01J20/26 , C08F224/00 , B01J20/30 , C08F220/16 , B01J20/28 , C08F226/10 , C08F220/06
CPC分类号： B01J20/3042 , B01J20/264 , B01J20/267 , B01J20/2803 , B01J2220/46 , B01J2220/68 , C08F8/44 , C08F220/06 , C08F220/16 , C08F224/00 , C08F226/10 , C08F2800/10
摘要： An ionic polymer of formula VI wherein each b=0 or 1; X is hydrogen, 1/z of a metal ion of charge z, a protonated nitrogen base, or a tetrasubstituted organic ammonium compound; the molar ratio of q:r:s:t=(100-0.1):(0-99.9):(0-50):(0-30); R1, R2 and R3 are hydrogen or C1-4 alkyl; R4, R5, R6 and R7 are hydrogen, C1-4 alkyl or F, wherein F is a functional group that imparts a property to polymer VI, at least one and no more than two of R4, R5, R6 and R7 are F and F is the same or different; G is a single bond or a C1-30 hydrocarbyl group; and for each instance of t when t is not zero, c=0-5 and d=0-5, provided that c+d=1-5, and wherein q, r and s as present in c are independent of any other value of q, r and s.
摘要翻译： 式VI的离子聚合物，其中每个b = 0或1; X是氢，电荷z的金属离子的1 / z，质子化的氮碱或四取代的有机铵化合物; q：r：s：t =（100-0.1）：（0-99.9）：（0-50）：（0-30）的摩尔比; R1，R2和R3是氢或C1-4烷基; R4，R5，R6和R7是氢，C1-4烷基或F，其中F是赋予聚合物VI性质的官能团，R 4，R 5，R 6和R 7中的至少一个不超过两个是F， F相同或不同; G是单键或C1-30烃基; 并且对于t的每个实例，当t不为零时，c = 0-5和d = 0-5，条件是c + d = 1-5，并且其中存在于c中的q，r和s独立于任何其它 q，r和s的值。
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4.发明授权Water reducible coating compositions including carboxy ester ketals, methods of manufacture, and uses thereof 有权包含羧酯缩酮的可水稀释涂料组合物，其制备方法及其应用公开(公告)号：US08728625B2
公开(公告)日：2014-05-20
申请号：US13276091
申请日：2011-10-18
CPC分类号： C09D167/00 , C08G18/0866 , C08K5/06 , C08K5/156 , C09D167/08 , C09D175/06 , Y10T428/31855 , C08K5/0041
摘要： A water-reducible coating composition includes a water-reducible polymer binder; water; and a ketal adduct of formula (1) as well as coated substrates and films formed from the compositions. The films are useful as paints, stains, and clear-coats.
摘要翻译： 水可稀释的涂料组合物包括水可稀释的聚合物粘合剂; 水; 和式（1）的缩酮加合物以及由组合物形成的涂覆的基底和薄膜。 这些电影可用作油漆，污渍和清漆。
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公开(公告)号：US20120123147A1
公开(公告)日：2012-05-17
申请号：US13294751
申请日：2011-11-11
申请人： Brian D. MULLEN , Cora M. LEIBIG , Leo E. MANZER
发明人： Brian D. MULLEN , Cora M. LEIBIG , Leo E. MANZER
IPC分类号： C07C51/493 , C07C67/52 , C07C59/347 , C07C67/54 , C07C69/738 , C07C67/60 , C07C67/58
CPC分类号： C07C69/738 , C07C51/09 , C07C51/493 , C07C67/08 , C07C67/52 , C07C69/716 , Y02P20/582 , C07C59/185
摘要： Ketocarboxylic acids such as levulinic acid can be efficiently purified in high yield by esterification with a hydrocarbon polyol to the corresponding polyketocarboxylic ester, which can be readily purified, for example recrystallized. After purification, the ketocarboxylic ester can be hydrolyzed to provide pure ketocarboxylic acid, or a salt thereof, after removal of the esterifying hydrocarbon polyol, or used for other synthetic transformations. Advantageously, the polyketocarboxylic esters, ketocarboxylic acids, and salts thereof produced by this method are obtained in high purity.
摘要翻译： 酮羧酸如乙酰丙酸可以通过用烃多元醇与相应的聚酮羧酸酯酯化而以高收率有效地纯化，其可以容易地纯化，例如重结晶。 纯化后，在除去酯化烃多元醇之后，可以将酮羧酸酯水解以提供纯酮羧酸或其盐，或用于其它合成转化。 有利地，以高纯度获得通过该方法制备的多酮羧酸酯，酮羧酸及其盐。
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公开(公告)号：US20120118832A1
公开(公告)日：2012-05-17
申请号：US13294926
申请日：2011-11-11
申请人： Dorie J. Yontz , Brian D. Mullen , Cora M. Leibig , Marc D. Rodwogin , Vivek Badarinarayana , Feng Jing , Friederike T. Stollmaier
发明人： Dorie J. Yontz , Brian D. Mullen , Cora M. Leibig , Marc D. Rodwogin , Vivek Badarinarayana , Feng Jing , Friederike T. Stollmaier
IPC分类号： B01D21/01 , B01J20/26 , C09K3/00 , C08F218/10 , C08F8/44
CPC分类号： B01J20/3042 , B01J20/264 , B01J20/267 , B01J20/2803 , B01J2220/46 , B01J2220/68 , C08F8/44 , C08F220/06 , C08F220/16 , C08F224/00 , C08F226/10 , C08F2800/10
摘要： An ionic polymer of formula VI wherein each b=0 or 1; X is hydrogen, 1/z of a metal ion of charge z, a protonated nitrogen base, or a tetrasubstituted organic ammonium compound; the molar ratio of q:r:s:t=(100-0.1):(0-99.9):(0-50):(0-30); R1, R2 and R3 are hydrogen or C1-4 alkyl; R4, R5, R6 and R7 are hydrogen, C1-4 alkyl or F, wherein F is a functional group that imparts a property to polymer VI, at least one and no more than two of R4, R5, R6 and R7 are F and F is the same or different; G is a single bond or a C1-30 hydrocarbyl group; and for each instance of t when t is not zero, c=0-5 and d=0-5, provided that c+d=1-5, and wherein q, r and s as present in c are independent of any other value of q, r and s.
摘要翻译： 式VI的离子聚合物，其中每个b = 0或1; X是氢，电荷z的金属离子的1 / z，质子化的氮碱或四取代的有机铵化合物; q：r：s：t =（100-0.1）：（0-99.9）：（0-50）：（0-30）的摩尔比; R1，R2和R3是氢或C1-4烷基; R4，R5，R6和R7是氢，C1-4烷基或F，其中F是赋予聚合物VI性质的官能团，R 4，R 5，R 6和R 7中的至少一个不超过两个是F， F相同或不同; G是单键或C1-30烃基; 并且对于t的每个实例，当t不为零时，c = 0-5和d = 0-5，条件是c + d = 1-5，并且其中存在于c中的q，r和s独立于任何其它 q，r和s的值。
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公开(公告)号：US06426390B1
公开(公告)日：2002-07-30
申请号：US09726864
申请日：2000-11-30
申请人： Jerry L. Hahnfeld , Mary Ann Jones , Charles A. Berglund , Gary D. Parsons , Cora M. Leibig , Stephen F. Hahn
发明人： Jerry L. Hahnfeld , Mary Ann Jones , Charles A. Berglund , Gary D. Parsons , Cora M. Leibig , Stephen F. Hahn
IPC分类号： C08C1902
CPC分类号： C08F8/04 , C08L53/025 , C08F297/04 , C08L2666/02 , C08L2666/04
摘要： The present invention is directed to a composition comprising a hydrogenated block copolymer of a vinyl aromatic and conjugated diene polymer, having a lamellar morphology and high aromatic hydrogenation level.
摘要翻译： 本发明涉及包含乙烯基芳族化合物和共轭二烯聚合物的氢化嵌段共聚物的组合物，其具有层状形态和高芳族氢化水平。
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8.发明申请公开(公告)号：US20120121911A1
公开(公告)日：2012-05-17
申请号：US13294854
申请日：2011-11-11
IPC分类号： B32B27/36 , C07D317/30 , C08J9/35 , C08K5/156 , C08G63/16 , C08G14/02 , C08G18/32 , C09K3/00 , C09D163/00 , C09D175/06 , C08G64/00 , B05D7/24 , B05D3/00 , B32B27/28 , C07D407/12
CPC分类号： C08K5/1565 , C07D317/02 , C07D317/14 , C07D317/30 , C08G2/32 , C08G18/3218 , C08G63/668 , C08G63/672 , C08G63/91 , C08G64/0208 , C08G64/42 , C08G2101/0025 , C08L59/00 , C08L67/00 , C09D159/00 , C09D167/00 , Y02P20/582 , Y10T428/31507 , Y10T428/31786
摘要： Disclosed herein is a polyhydroxy ketal adduct obtained by the esterification of a hydrocarbon polyol by at least 1.5 equivalents of a ketocarboxy to produce an intermediate ketocarboxylic ester. The intermediate polyketocarboxylic ester is then ketalized to produce the polyhydroxyketal adduct, which can be used to provide a polymeric composition.
摘要翻译： 本文公开了通过烃多元醇通过至少1.5当量的酮羧基酯化以产生中间体酮羧酸酯而获得的多羟基缩酮加合物。 然后中间体多酮羧酸酯被缩醛化以产生可用于提供聚合物组合物的多羟基缩酮加合物。
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公开(公告)号：US20120118201A1
公开(公告)日：2012-05-17
申请号：US13294690
申请日：2011-11-11
IPC分类号： C08K5/1565 , C08L67/04 , C08L27/06 , C08L23/00 , C08L69/00 , C08L79/08 , C08L25/06 , C08L77/00 , C08L1/02 , C08L81/04 , C08L81/06 , C07D407/12 , C08L83/04
CPC分类号： C07D407/12 , C08K5/1565 , C08L59/02 , C08L77/00 , C08L79/08 , Y02P20/582 , C08L27/06
摘要： Disclosed herein is a polyketal adduct obtained by forming an ester between a hydrocarbon polyol and a ketocarboxylic acid to produce an intermediate polyketocarboxylic ester. The intermediate polyketocarboxylic ester can be purified via crystallization to achieve purities of greater than 99.0% and then ketalized to produce the polyketal adduct, which can be used in polymer compositions. The polyketal adduct I is obtained at high purity and at high yield.
摘要翻译： 本文公开了通过在烃多元醇和酮羧酸之间形成酯以产生中间体多酮羧酸酯而获得的聚缩酮加成物。 可以通过结晶纯化中间体多酮羧酸酯以实现大于99.0％的纯度，然后缩醛化以产生可用于聚合物组合物中的聚缩酮加合物。 以高纯度和高收率获得聚缩酮加成物I.
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10.发明授权公开(公告)号：US06583230B2
公开(公告)日：2003-06-24
申请号：US10040780
申请日：2001-10-31
IPC分类号： C08F804
CPC分类号： C08F8/04 , Y10T428/21 , C08F297/04
摘要： The present invention is a composition comprising an alternating hydrogenated block copolymer having at least two hydrogenated vinyl aromatic polymer blocks and at least one conjugated diene polymer block, wherein the number average molecular weights (Mn) of each block can be different.
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