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1.发明授权Process for producing alkylbenzenes using a catalyst based on a dealuminized Y zeolite and a catalyst based on a dealuminized mordenite 失效使用基于脱铝Y沸石的催化剂和基于脱盐的MORDENITE的催化剂生产烷基苯甲酸的方法
公开(公告)号：US5177280A
公开(公告)日：1993-01-05
申请号：US534229
申请日：1990-06-07
IPC分类号： B01J29/08 , B01J29/18 , C07B61/00 , C07C2/66 , C07C2/70 , C07C6/12 , C07C15/02 , C07C15/073 , C07C15/085
CPC分类号： C07C15/085 , C07C15/02 , C07C15/073 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , Y02P20/52
摘要： The invention relates to a process for producing an alkylbenzene from benzene and an aliphatic mono-olefin in the presence of a catalyst based on a dealuminized Y zeolite with a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 ranging from 8 to 70, the product of this reaction being afterwards fractionated into a first fraction containing non converted benzene and a mono-alkylbenzene and a second fraction containing a poly-alkylbenzene, said second fraction reacting then with benzene in the presence of a catalyst based on a dealuminized mordenite with a total atomic ratio Si/Al ranging from 30 to 80. The invention especially applies to the production of ethylbenzene and cumene respectively from ethylene and propene.
摘要翻译： 本发明涉及一种在基于SiO 2 / Al 2 O 3的摩尔比为8至70的脱铝Y沸石的催化剂存在下由苯和脂族单烯烃生产烷基苯的方法，该反应产物之后 分馏成含有未转化的苯和单烷基苯的第一馏分和含有聚烷基苯的第二馏分，所述第二馏分在基于脱铝丝光沸石的催化剂存在下与苯反应，总原子比Si / Al 范围从30到80.本发明特别适用于从乙烯和丙烯生产乙苯和枯烯。
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2.发明授权Method for producing olefin oligomers using a modified mordenite based catalyst 失效使用改性丝光沸石催化剂生产烯烃低聚物的方法
公开(公告)号：US4902847A
公开(公告)日：1990-02-20
申请号：US245241
申请日：1988-09-16
CPC分类号： B01J29/18 , C10G50/00 , B01J2229/16 , F02B3/06
摘要： Preparation of oligomers of C.sub.2 to C.sub.8 olefins useful in gasoline, yet fuel and diesel fuel is disclosed. The oligomerization is catalyzed by a modified mordenite in the H or NH.sub.4 + to form which has been sequentially treated with steam and an acid.
摘要翻译： 公开了可用于汽油的C2至C8烯烃的低聚物，但燃料和柴油燃料的制备。 低聚由H或NH4 +中的改性丝光沸石催化形成，其已经用蒸汽和酸依次处理。
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公开(公告)号：US4435274A
公开(公告)日：1984-03-06
申请号：US425348
申请日：1982-09-28
CPC分类号： C10L1/06 , C10G1/002 , C10G2400/02
摘要： Residual oils from steam-cracking or catalytic cracking, oils from coal liquefaction and oils from bituminous sands and shales are converted to gasoline by a process comprising the fractionation of the feed charge to a naphtha and a middle distillate: the naphtha, admixed with a gasoline cut "E", is hydrotreated and then dehydrogenated to gasoline; the middle distillate is hydrotreated and fractionated to gasoline and a heavier fraction, the heavier fraction is hydrocracked and fractionated, thus producing a gasoline cut which constitutes the above cut "E".
摘要翻译： 来自蒸汽裂解或催化裂化的残余油，来自煤液化的油和来自沥青砂和页岩的油通过包括将进料装料分馏成石脑油和中间馏分的方法转化为汽油：石脑油与汽油混合 切“E”，加氢处理后脱氢至汽油; 将中间馏分加氢处理并分馏成汽油和较重的馏分，将较重的馏分进行加氢裂化和分馏，从而产生构成上述馏分“E”的汽油馏分。
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公开(公告)号：US4498907A
公开(公告)日：1985-02-12
申请号：US393913
申请日：1982-06-30
申请人： Bernard Juguin , Germain Martino , Jean Miquel
发明人： Bernard Juguin , Germain Martino , Jean Miquel
CPC分类号： C10L1/023 , B01J35/10 , C10G1/002 , C10G35/06 , B01J35/1014 , B01J35/1042 , B01J35/1061 , C10G2400/02
摘要： Process for the production of a liquid effluent comprising at least 75% of aromatic hydrocarbons from a naphtha feed charge of high sulfur, nitrogen or oxygen content; said process comprises two steps: (a) hydrotreatment of the charge to decrease its sulfur, nitrogen or oxygen content to selected values, and (b) dehydrogenation of the product of step (a) in the presence of a supported catalyst whose neutralization heat by ammonia adsorption is lower than about 40 joules per gram at 300 mm Hg.
摘要翻译： 用于生产包含至少75％的来自高硫，氮或氧含量的石脑油进料的芳烃的液体流出物的方法; 所述方法包括两个步骤：（a）加氢处理电荷以将其硫，氮或氧含量降低至所选值，和（b）步骤（a）的产物在负载型催化剂的存在下脱氢，所述催化剂的中和热由 氨吸附在300 mm Hg下低于约40焦耳/克。
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公开(公告)号：US4401557A
公开(公告)日：1983-08-30
申请号：US616123
申请日：1975-09-24
申请人： Bernard Juguin , Germain Martino , Jean Miquel
发明人： Bernard Juguin , Germain Martino , Jean Miquel
IPC分类号： B01J21/04 , B01J23/40 , B01J23/46 , B01J23/56 , B01J23/60 , B01J23/62 , B01J23/63 , B01J23/652 , B01J23/656 , B01J27/13 , B01J27/132 , B01J27/135 , B01J27/138 , C10G35/09 , B01J27/06
CPC分类号： B01J23/40 , B01J23/46 , B01J23/56 , C10G35/09 , B01J21/04 , B01J23/60 , B01J23/62 , B01J23/622 , B01J23/63 , B01J23/652 , B01J23/656
摘要： Reforming process operated in the presence of a catalyst comprising a carrier, platinum, rhodium or osmium, an additional metal consisting of chromium, tungsten, molybdenum, manganese, rhenium, germanium, tin, gallium, indium, thallium, thorium, cerium, samarium, lanthanum, zinc, cadmium, titanium or zirconium, and halogen.
摘要翻译： 在包含载体，铂，铑或锇的催化剂存在下操作的重整工艺，由铬，钨，钼，锰，铼，锗，锡，镓，铟，铊，钍，铈，钐， 镧，锌，镉，钛或锆，和卤素。
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公开(公告)号：US4392002A
公开(公告)日：1983-07-05
申请号：US311828
申请日：1981-10-16
CPC分类号： C10L1/06 , C07C2/10 , C07C5/2556 , C07C9/16 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2523/44 , C07C2523/75 , C07C2523/755
摘要： A C.sub.4 cut is upgraded according to the following steps:(a) the dried C.sub.4 cut is polymerized in the presence of fluorinated alumina, boron-alumina or silica-alumina, to convert at least 95% of isobutene to dimers and trimers, the conversion of the normal butenes being at most 3%,(b) the whole polymerization effluent is hydro-isomerized in the presence of a group VIII metal catalyst, to isomerize at least 90% of the 1-butene of said effluent,(c) the hydro-isomerization effluent is fractionated and a resultant fraction is alkylated.Resultant alkylate and mixture of dimers and trimers can be mixed and used as gasoline.
摘要翻译： C4馏分根据以下步骤升级：（a）干燥的C4馏分在氟化氧化铝，硼 - 氧化铝或二氧化硅 - 氧化铝的存在下聚合，以将至少95％的异丁烯转化为二聚体和三聚体，转化率 （b）在第VIII族金属催化剂存在下将整个聚合流出物加氢异构化，使至少90％的所述流出物的1-丁烯异构化，（c） 分批加氢异构化流出物，并将所得馏分烷基化。 得到的烷基化物和二聚体和三聚体的混合物可以混合并用作汽油。
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7.发明授权Process for the conversion of olefinic C.sub.4 cuts from steam cracking to high octane gasoline and butane 失效烯烃C4馏分从蒸汽裂解转化为高辛烷值汽油和丁烷的方法
公开(公告)号：US4197185A
公开(公告)日：1980-04-08
申请号：US936965
申请日：1978-08-25
IPC分类号： B01J21/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C2/06 , C07C2/10 , C07C2/74 , C07C5/03 , C07C9/10 , C07C9/21 , C07C67/00 , C10G50/00 , C10G69/12 , C10L1/06 , C07C9/20
CPC分类号： C10L1/06 , C07C2/10 , C07C5/03 , C10G69/126 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2523/75 , C07C2523/755 , C10G2400/02
摘要： Process for producing butane and gasoline of high isooctane content, from a C.sub.4 olefin cut issued from a steam cracking unit, comprising the steps of:polymerizing at least 90% of the isobutene of the cut mainly to dimers and trimers thereof,hydrogenating the resulting polymerization mixture to normal butane, isooctane and isododecane,supplying the effluent from the hydrogenation unit to a separation zone to recover a gaseous fraction and a liquid mixture, andfractionating the liquid mixture to separate gasoline of high isooctane content, a C.sub.3.sup.- fraction and a butane fraction which is recycled to the steam cracking unit.
摘要翻译： 从蒸汽裂解装置发出的C4烯烃切割制备高异辛烷含量的丁烷和汽油的方法，包括以下步骤：将切割的至少90％的异丁烯聚合成二聚体和三聚体，将所得聚合物氢化 与正丁烷，异辛烷和异十二烷的混合物，将来自氢化单元的流出物供应到分离区以回收气态馏分和液体混合物，并将液体混合物分馏分离出高异辛烷含量的汽油，C3馏分和丁烷 再循环到蒸汽裂解装置的馏分。
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8.发明授权Process for the joint production of highly pure 1-butene and premium gasoline from a C.sub.4 olefinic cut 失效从C4烯烃切割联合生产高纯度1-丁烯和优质汽油的方法
公开(公告)号：US4423264A
公开(公告)日：1983-12-27
申请号：US392056
申请日：1982-06-25
申请人： Bernard Juguin , Jean Cosyns , Jean Miquel
发明人： Bernard Juguin , Jean Cosyns , Jean Miquel
摘要： Highly pure 1-butene and premium gasoline are obtained by(a) subjecting a C.sub.4 olefinic cut to a polymerization-disproportionation to partly convert the isobutene thereof to a gasoline which, in turn, by partial disproportionation, yields a jet fuel base and butenes,(b) fractionating the effluent from step (a) to a mixture (.alpha.) of gasoline and jet fuel base and to a fraction (.beta.) containing isobutane, n-butane, butenes, a small amount of isobutene and a minor amount of butadiene,(c) selectively polymerizing fraction (.beta.) to convert more than 90% of the isobutene thereof to gasoline,(d) fractionating the polymerized fraction (.beta.) to a gasoline cut (.gamma.) containing isobutene dimers and trimers and to a fraction (.delta.) containing isobutane, n-butane and butenes,(e) selectively hydrogenating the fraction (.delta.),(f) removing isobutane from the hydrogenated fraction (.delta.) and(g) fractionating the deisobutanized hydrogenated fraction (.delta.) to obtain a fraction containing at least 99% of 1-butene, the mixture (.alpha.) being admixed with the cut (.gamma.).
摘要翻译： 通过以下方法获得高纯度的1-丁烯和优质汽油：（a）使C4烯烃切割物进行聚合歧化，将其异丁烯部分转化成汽油，然后汽油通过部分歧化产生喷气燃料基体和丁烯， （b）将来自步骤（a）的流出物分馏成汽油和喷气燃料基料的混合物（α）和含有异丁烷，正丁烷，丁烯，少量异丁烯和少量丁二烯的馏分（β） ，（c）选择性地聚合馏分（β）以将其超过90％的异丁烯转化成汽油，（d）将聚合馏分（β）分馏成含有异丁烯二聚体和三聚体的汽油馏分（γ） （e）选择性氢化馏分（δ），（f）从氢化馏分（delta）中除去异丁烷，和（g）分离除异丁氢化氢化馏分（delta）以获得af 反应物含有至少99％的1-丁烯，混合物（α）与切割（γ）混合。
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9.发明授权Process for converting C.sub.4 olefinic cracking cuts to alkylate and gasoline 失效将C4烯烃裂解馏分转化为烷基化物和汽油的方法
公开(公告)号：US4324646A
公开(公告)日：1982-04-13
申请号：US180205
申请日：1980-08-21
摘要： A process is provided for selectively polymerizing isobutene in an olefinic C.sub.4 cut comprising isobutene and normal butenes by contacting the cut with a catalyst consisting essentially of silica-alumina; whereby at least 90% of the isobutene and less than 10% of the normal butenes in the cut are converted.
摘要翻译： 提供了一种通过使切割与基本上由二氧化硅 - 氧化铝组成的催化剂接触来选择性地聚合包含异丁烯和正丁烯的烯烃C4馏分中的异丁烯的方法; 由此转化了至少90％的异丁烯和小于正丁烯的10％。
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公开(公告)号：US3966833A
公开(公告)日：1976-06-29
申请号：US532618
申请日：1974-12-13
CPC分类号： B01J35/10 , B01J23/56 , C07C4/18 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1061 , C07C2521/04 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , Y02P20/52
摘要： Process for hydrodealkylating an alkylaromatic hydrocarbon charge at a temperature from 400.degree. to 650.degree.C under a pressure from 1 to 30 kg/cm.sup.2 at a space velocity from 1 to 10 by reacting said charge with hydrogen in a molar proportion with respect to the effluent of the reactor in the range from 1 to 10, in the presence of a catalyst containing alumina and at least one metal selected from ruthenium, osmium, palladium, rhodium, iridium, platinum and manganese in an amount from 0.05 to 5 % of the catalyst, said catalyst having a specific surface from 1 to 100 m.sup.2 /g., a total pore volume of 0.2-0.8 g/cc and a heat of neutralization lower than 10 calories per gram are measured by ammonia adsorption at 320.degree. C. under 300 mm Hg.
摘要翻译： 通过使所述电荷与氢气相对于流出物的摩尔比例反应，在400至650℃的温度下，在1至30kg / cm 2的压力下以1至10的空间速度对烷基芳烃进行加氢脱烷基化的方法 在含有氧化铝和选自钌，锇，钯，铑，铱，铂和锰中的至少一种金属的催化剂存在下，反应器的量为1至10，催化剂的量为催化剂的0.05至5％ 所述催化剂具有1至100m 2 / g的比表面积，0.2-0.8g / cc的总孔容积和低于10卡路里/克的中和热通过在320℃下在300℃下的氨吸附来测量 mm Hg。
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