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公开(公告)号:US08202638B2
公开(公告)日:2012-06-19
申请号:US11235097
申请日:2005-09-27
申请人: John Bøgild Hansen , Søren Dahl
发明人: John Bøgild Hansen , Søren Dahl
CPC分类号: H01M8/0618 , H01M8/04097 , H01M2008/1293
摘要: A fuel processing method for a solid oxide fuel cell stack comprising the steps of: (a) supplying a feed stream comprising ethanol to a methanation reactor containing catalytic material for the methanation of ethanol; (b) processing the feed stream in the methanation reactor under adiabatic conditions to produce an effluent fuel comprising methane; (c) transferring the effluent fuel comprising methane to the anode of a solid oxide fuel cell stack comprising at least one solid oxide fuel cell; (d) providing the cathode of the solid oxide fuel cell stack with an oxygen-containing gas; and (e) converting the fuel comprising methane and the oxygen-containing gas to electricity in the solid oxide fuel cell stack.
摘要翻译: 一种固体氧化物燃料电池堆的燃料处理方法,包括以下步骤:(a)将含有乙醇的进料流供应到含甲醇化乙醇的催化剂的甲烷化反应器; (b)在绝热条件下处理甲烷化反应器中的进料流以产生包含甲烷的废气; (c)将包含甲烷的废气燃料转移到包含至少一个固体氧化物燃料电池的固体氧化物燃料电池堆的阳极; (d)用含氧气体提供固体氧化物燃料电池堆的阴极; 和(e)将包含甲烷和含氧气体的燃料转化为固体氧化物燃料电池堆中的电。
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2.
公开(公告)号:US07481859B2
公开(公告)日:2009-01-27
申请号:US11067563
申请日:2005-02-28
CPC分类号: C01B3/382 , B01J8/0285 , B01J8/067 , B01J2208/00132 , B01J2208/0053 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/0816 , C01B2203/0844 , C01B2203/0888 , C01B2203/1241 , C01B2203/1288 , C01B2203/142 , C01B2203/82 , Y02P20/129
摘要: Process for cooling an exothermic reaction zone by introducing a stream of water and a hydrocarbon-containing stream into a plurality of humidifying tubes extending through a catalytic exothermic reaction zone of a catalytic fixed bed with solid catalyst, introducing a process stream into the reaction zone for one or more catalytic exothermic reactions, passing the stream of water in a falling film along the inner circumference of the humidifying tubes, humidifying the hydrocarbon-containing stream with water in the humidifying tubes in indirect heat exchange with the exothermic reaction zone, withdrawing cooled reaction product of the exothermic reaction from the reaction zone, withdrawing the heated humidified, hydrocarbon-containing stream from the humidifying tubes, and transferring the heated humidified, hydrocarbon-containing process stream for further processing.
摘要翻译: 通过将水流和含烃物流引入到通过催化固定床的催化放热反应区的固体催化剂的多个加湿管中来冷却放热反应区的方法,将工艺流引入反应区 一个或多个催化放热反应,沿着加湿管的内周将水流送入落下的薄膜中,在加湿管内与含水物流加湿,与放热反应区间接热交换,抽出冷却反应 来自反应区的放热反应的产物,从加湿管中取出加热的加湿的含烃物流,并转移加热的加湿的含烃流程以进一步处理。
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公开(公告)号:US08067474B2
公开(公告)日:2011-11-29
申请号:US12725555
申请日:2010-03-17
申请人: Poul Erik Højlund Nielsen , Finn Joensen , John Bøgild Hansen , Esben Lauge Sørensen , Jørgen Madsen , Rachid Mabrouk
发明人: Poul Erik Højlund Nielsen , Finn Joensen , John Bøgild Hansen , Esben Lauge Sørensen , Jørgen Madsen , Rachid Mabrouk
IPC分类号: C07C27/00
CPC分类号: C10G3/49 , C10G2300/1044 , C10G2300/4012 , C10G2300/4081 , C10G2300/44 , Y02P30/20
摘要: A process for the preparation of hydrocarbon products comprising the steps of a) providing a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; (b) reacting at least part of the synthesis gas to an oxygenate mixture comprising methanol and dimethyl ether in presence of one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates at a pressure of at least 3 MPa; (c) withdrawing from step (b) a reaction mixture comprising amounts of methanol, dimethyl ether, carbon dioxide and water together with unreacted synthesis gas and cooling the reaction mixture to obtain a liquid phase with the amounts of methanol, dimethyl ether and water and simultaneously dissolving carbon dioxide in the liquid phase; (d) separating the carbon dioxide containing liquid phase from a remaining gaseous phase comprising hydrogen and carbon monoxide; (e) evaporating and reacting the liquid phase being withdrawn from step (d) in presence of a catalyst being active in the conversion of oxygenates to higher hydrocarbons and a tail gas comprising carbon dioxide; (f) separating tail gas from a liquid phase with the higher hydrocarbons; and wherein pressure employed in step (c) to step (f) is substantially the same as employed in step (b).
摘要翻译: 一种用于制备烃产物的方法,包括以下步骤:a)提供包含氢气,一氧化碳和二氧化碳的合成气体; (b)在一种或多种催化剂的存在下使至少部分合成气与包含甲醇和二甲醚的含氧化合物反应,所述催化剂在至少3MPa的压力下共同催化氢和一氧化碳与含氧化合物的反应; (c)从步骤(b)中取出含有甲醇,二甲醚,二氧化碳和水以及未反应的合成气的反应混合物并冷却反应混合物以获得具有甲醇,二甲醚和水的量的液相,以及 同时将二氧化碳溶解在液相中; (d)从包含氢气和一氧化碳的剩余气相中分离含二氧化碳的液相; (e)在将氧化物转化为高级烃和包含二氧化碳的尾气的催化剂存在下,使从步骤(d)中取出的液相蒸发和反应; (f)用高级烃分离尾气与液相; 并且其中在步骤(c)至步骤(f)中使用的压力与步骤(b)中采用的基本相同。
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公开(公告)号:US07670394B2
公开(公告)日:2010-03-02
申请号:US11471574
申请日:2006-06-21
申请人: Michael Boe , John Bøgild Hansen
发明人: Michael Boe , John Bøgild Hansen
CPC分类号: C01B3/323 , B01J8/0242 , B01J8/0285 , B01J8/0446 , B01J8/0453 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J8/06 , B01J8/065 , B01J8/067 , B01J2208/00106 , B01J2208/00309 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/1223 , Y02P20/128 , Y02P20/129
摘要: Reforming reactor for the conversion of a process fluid into hydrogen comprising: a reforming section and a boiler section which are both contained within a common volume and a combustion section, in which said reforming section contains one or more catalyst tubes filled with reforming catalyst, said boiler section is provided with one or more tubes carrying flue gas from the combustion section and said combustion section is provided with at least one burner, wherein the heat exchanging medium required for the reforming of said process fluid in the one or more catalyst tubes is a gas-liquid mixture that self-circulates and is encapsulated inside said common volume containing said reforming and boiler sections.
摘要翻译: 用于将工艺流体转化为氢的重整反应器,包括:重整部分和锅炉部分,其均包含在共同体积和燃烧部分内,其中所述重整部分包含一个或多个填充有重整催化剂的催化剂管,所述重整部分和锅炉部分 锅炉部分设置有一个或多个管道,其承载来自燃烧部分的烟道气,并且所述燃烧部分设置有至少一个燃烧器,其中所述一个或多个催化剂管中的所述工艺流体重整所需的热交换介质是 气体 - 液体混合物,其自循环并且包封在包含所述重整和锅炉部分的所述公共容积内。
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公开(公告)号:US09005827B2
公开(公告)日:2015-04-14
申请号:US13695944
申请日:2010-05-05
申请人: Thomas Nedergaard Clausen , Thomas Rostrup-Nielsen , Rasmus Gottrup Barfod , Peter Vang Hendriksen , Johan Hjelm , Joachim Jacobsen , John Bøgild Hansen
发明人: Thomas Nedergaard Clausen , Thomas Rostrup-Nielsen , Rasmus Gottrup Barfod , Peter Vang Hendriksen , Johan Hjelm , Joachim Jacobsen , John Bøgild Hansen
CPC分类号: H01M8/04955 , H01M8/04007 , H01M8/04097 , H01M8/04238 , H01M8/04731 , H01M8/04873 , H01M8/0488 , H01M8/04888 , H01M8/0612 , H01M2008/1293 , H01M2008/147 , Y02E60/50 , Y02E60/525 , Y02E60/526
摘要: Process for operating a high temperature fuel cell stack by the steps of: connecting the fuel cell stack in parallel to a power supply unit at a predefined temperature and/or voltage of the fuel cell stack, applying a voltage from the power supply unit of between 700 to 1500 mV per fuel cell across the fuel cell stack irrespective of the electro-motive force of the fuel cell stack, heating up the fuel cell stack from the predefined temperature to operation temperature while maintaining the voltage per fuel cell the power supply unit, maintaining the fuel cell stack at or above a predetermined operation temperature and/or above a predetermined voltage until the fuel cell stack is to be put into operation, supplying fuel to the fuel cell stack, and disconnecting the power supply unit followed by connecting a power-requiring load to the fuel cell stack.
摘要翻译: 用于通过以下步骤操作高温燃料电池堆的方法:在燃料电池堆的预定温度和/或电压下将燃料电池堆并联到电源单元,施加来自电源单元之间的电压 不管燃料电池堆的电动力如何,每个燃料电池700至1500mV,不管燃料电池堆的电动力,将燃料电池堆从预定温度加热到工作温度,同时保持每个燃料电池的电压,电源单元, 将燃料电池堆保持在预定操作温度以上或高于预定电压,直到燃料电池组投入运行,向燃料电池堆供电,并断开电源单元连接电源 - 需要负载到燃料电池堆。
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公开(公告)号:US20130052548A1
公开(公告)日:2013-02-28
申请号:US13695944
申请日:2010-05-05
申请人: Thomas Nedergaard Clausen , Thomas Rostrup-Nielsen , Rasmus Gottrup Barfod , Peter Vang Hendriksen , Johan Hjelm , Joachim Jacobsen , John Bøgild Hansen
发明人: Thomas Nedergaard Clausen , Thomas Rostrup-Nielsen , Rasmus Gottrup Barfod , Peter Vang Hendriksen , Johan Hjelm , Joachim Jacobsen , John Bøgild Hansen
CPC分类号: H01M8/04955 , H01M8/04007 , H01M8/04097 , H01M8/04238 , H01M8/04731 , H01M8/04873 , H01M8/0488 , H01M8/04888 , H01M8/0612 , H01M2008/1293 , H01M2008/147 , Y02E60/50 , Y02E60/525 , Y02E60/526
摘要: Process for operating a high temperature fuel cell stack, the process comprising the following steps: b) connecting the fuel cell stack in parallel to a power supply unit at a predefined temperature and/or voltage of the fuel cell stack, h) applying a voltage from the power supply unit of between 700 to 1500 mV per fuel cell across the fuel cell stack irrespective of the electro-motive force of the fuel cell stack, i) heating up the fuel cell stack from the predefined temperature to operation temperature while maintaining the voltage per fuel cell the power supply unit, j) maintaining the fuel cell stack at or above a predetermined operation temperature and/or above a predetermined voltage until the fuel cell stack is to be put into operation, k) supplying fuel to the fuel cell stack, l) disconnecting the power supply unit followed by m) connecting a power-requiring load to the fuel cell stack.
摘要翻译: 用于操作高温燃料电池堆的方法,该方法包括以下步骤:b)在燃料电池堆的预定温度和/或电压下将燃料电池堆并联连接到电源单元,h)施加电压 不管燃料电池堆的电动势如何,从燃料电池堆的每个燃料电池700至1500mV的电源单元,i)将燃料电池堆从预定的温度加热到工作温度,同时保持 燃料电池单元的电压,电源单元,j)将燃料电池堆保持在预定操作温度以上或高于预定电压,直到燃料电池组投入运行,k)向燃料电池供应燃料 堆叠,l)断开电源单元,然后m)将需要功率的负载连接到燃料电池堆。
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公开(公告)号:US07670395B2
公开(公告)日:2010-03-02
申请号:US11471601
申请日:2006-06-21
申请人: Michael Boe , John Bøgild Hansen
发明人: Michael Boe , John Bøgild Hansen
CPC分类号: C01B3/384 , B01J8/0242 , B01J8/0285 , B01J8/0446 , B01J8/0453 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J8/06 , B01J8/065 , B01J8/067 , B01J19/2495 , B01J19/26 , B01J2208/00106 , B01J2208/00132 , B01J2208/00185 , B01J2208/00203 , B01J2208/00212 , B01J2208/00221 , B01J2208/00274 , B01J2208/00283 , B01J2208/00309 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , C01B3/505 , C01B3/56 , C01B2203/0233 , C01B2203/0405 , C01B2203/041 , C01B2203/043 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0833 , C01B2203/0866 , C01B2203/1217 , F28D15/0266 , Y02P20/128
摘要: Reforming reactor for the conversion of a process fluid into hydrogen comprising: a reforming section which is contained within a closed volume, a boiler section and a combustion section, in which said reforming section contains one or more catalyst tubes filled with reforming catalyst, said boiler section is provided with one or more flow channels for the passage of flue gas from the combustion section and said combustion section is provided with at least one burner, wherein the heat exchanging medium required for the reforming of said process fluid in the one or more catalyst tubes is a gas-liquid mixture that self-circulates and is encapsulated inside said closed volume and wherein at least a portion of said closed volume protrudes inside said boiler section.
摘要翻译: 用于将工艺流体转化为氢的重整反应器,包括:包含在封闭体积内的重整部分,锅炉部分和燃烧部分,其中所述重整部分包含一个或多个填充有重整催化剂的催化剂管,所述锅炉 具有一个或多个用于烟道气从燃烧部分通过的流动通道,并且所述燃烧部分设置有至少一个燃烧器,其中所述一个或多个催化剂中所述工艺流体重整所需的热交换介质 管是气体 - 液体混合物,其自行循环并被封装在所述封闭体积内,并且其中所述封闭体积的至少一部分在所述锅炉部分内部突出。
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公开(公告)号:US07641994B2
公开(公告)日:2010-01-05
申请号:US11143708
申请日:2005-06-03
申请人: John Bøgild Hansen
发明人: John Bøgild Hansen
IPC分类号: H01M5/00
CPC分类号: C01B3/22 , H01M8/04097 , H01M8/0612 , H01M8/0637 , H01M2008/1293 , Y02E60/566
摘要: A fuel processing method for a solid oxide fuel cell stack comprising the steps of: (a) supplying a feed stream comprising methanol and/or dimethyl ether to a methanation reactor containing catalytic material for the methanation of methanol and/or dimethyl ether; (b) processing the feed stream in the methanation reactor under adiabatic conditions to produce an effluent fuel comprising methane; (c) transferring the effluent fuel comprising methane to the anode of a solid oxide fuel cell stack comprising at least one solid oxide fuel cell; (d) providing the cathode of the solid oxide fuel cell stack with an oxygen-containing gas; and (e) converting the fuel comprising methane and the oxygen-containing gas into electricity in the solid oxide fuel cell stack.
摘要翻译: 一种固体氧化物燃料电池堆的燃料处理方法,包括以下步骤:(a)将含有甲醇和/或二甲醚的进料流供应到含有用于甲醇化和/或二甲醚甲烷化的催化材料的甲烷化反应器; (b)在绝热条件下处理甲烷化反应器中的进料流以产生包含甲烷的废气; (c)将包含甲烷的废气燃料转移到包含至少一个固体氧化物燃料电池的固体氧化物燃料电池堆的阳极; (d)用含氧气体提供固体氧化物燃料电池堆的阴极; 和(e)将包含甲烷和含氧气体的燃料转化为固体氧化物燃料电池堆中的电。
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公开(公告)号:US20100240779A1
公开(公告)日:2010-09-23
申请号:US12725555
申请日:2010-03-17
申请人: Poul Erik Højlund Nielsen , Finn Joensen , John Bøgild Hansen , Esben Lauge Sørensen , Jørgen Madsen , Rachid Mabrouk
发明人: Poul Erik Højlund Nielsen , Finn Joensen , John Bøgild Hansen , Esben Lauge Sørensen , Jørgen Madsen , Rachid Mabrouk
IPC分类号: C07C1/04
CPC分类号: C10G3/49 , C10G2300/1044 , C10G2300/4012 , C10G2300/4081 , C10G2300/44 , Y02P30/20
摘要: A process for the preparation of hydrocarbon products comprising the steps of a) providing a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; (b) reacting at least part of the synthesis gas to an oxygenate mixture comprising methanol and dimethyl ether in presence of one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates at a pressure of at least 3 MPa; (c) withdrawing from step (b) a reaction mixture comprising amounts of methanol, dimethyl ether, carbon dioxide and water together with unreacted synthesis gas and cooling the reaction mixture to obtain a liquid phase with the amounts of methanol, dimethyl ether and water and simultaneously dissolving carbon dioxide in the liquid phase; (d) separating the carbon dioxide containing liquid phase from a remaining gaseous phase comprising hydrogen and carbon monoxide; (e) evaporating and reacting the liquid phase being withdrawn from step (d) in presence of a catalyst being active in the conversion of oxygenates to higher hydrocarbons and a tail gas comprising carbon dioxide; (f) separating tail gas from a liquid phase with the higher hydrocarbons; and wherein pressure employed in step (c) to step (f) is substantially the same as employed in step (b).
摘要翻译: 一种用于制备烃产物的方法,包括以下步骤:a)提供包含氢气,一氧化碳和二氧化碳的合成气体; (b)在一种或多种催化剂的存在下使至少部分合成气与包含甲醇和二甲醚的含氧化合物反应,所述催化剂在至少3MPa的压力下共同催化氢和一氧化碳与含氧化合物的反应; (c)从步骤(b)中取出含有甲醇,二甲醚,二氧化碳和水以及未反应的合成气的反应混合物并冷却反应混合物以获得具有甲醇,二甲醚和水的量的液相,以及 同时将二氧化碳溶解在液相中; (d)从包含氢气和一氧化碳的剩余气相中分离含二氧化碳的液相; (e)在将氧化物转化为高级烃和包含二氧化碳的尾气的催化剂存在下,使从步骤(d)中取出的液相蒸发和反应; (f)用高级烃分离尾气与液相; 并且其中在步骤(c)至步骤(f)中使用的压力与步骤(b)中采用的基本相同。
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公开(公告)号:US07527781B2
公开(公告)日:2009-05-05
申请号:US10548802
申请日:2004-03-25
CPC分类号: C01B3/48 , C01B3/16 , C01B3/323 , C01B2203/0205 , C01B2203/0283 , C01B2203/0288 , C01B2203/1041 , C01B2203/1076 , C01B2203/143 , C01B2203/148
摘要: A process for the preparation of a hydrogen-rich stream comprising contacting a carbon monoxide-containing gas, methanol and water in at least one shift step in the presence of a catalyst comprising copper, zinc and aluminium and/or chromium at a shift inlet temperature of at least 280° C. and a pressure of at least 2.0 MPa.
摘要翻译: 一种用于制备富氢流的方法,包括在迁移入口温度下在包含铜,锌和铝和/或铬的催化剂存在下,在至少一个位移步骤中使含一氧化碳的气体,甲醇和水接触 至少280℃,压力至少为2.0MPa。
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