Fuel processing method and system
    1.
    发明授权
    Fuel processing method and system 失效
    燃料加工方法和系统

    公开(公告)号:US08202638B2

    公开(公告)日:2012-06-19

    申请号:US11235097

    申请日:2005-09-27

    IPC分类号: H01M8/10 H01M8/12

    摘要: A fuel processing method for a solid oxide fuel cell stack comprising the steps of: (a) supplying a feed stream comprising ethanol to a methanation reactor containing catalytic material for the methanation of ethanol; (b) processing the feed stream in the methanation reactor under adiabatic conditions to produce an effluent fuel comprising methane; (c) transferring the effluent fuel comprising methane to the anode of a solid oxide fuel cell stack comprising at least one solid oxide fuel cell; (d) providing the cathode of the solid oxide fuel cell stack with an oxygen-containing gas; and (e) converting the fuel comprising methane and the oxygen-containing gas to electricity in the solid oxide fuel cell stack.

    摘要翻译: 一种固体氧化物燃料电池堆的燃料处理方法,包括以下步骤:(a)将含有乙醇的进料流供应到含甲醇化乙醇的催化剂的甲烷化反应器; (b)在绝热条件下处理甲烷化反应器中的进料流以产生包含甲烷的废气; (c)将包含甲烷的废气燃料转移到包含至少一个固体氧化物燃料电池的固体氧化物燃料电池堆的阳极; (d)用含氧气体提供固体氧化物燃料电池堆的阴极; 和(e)将包含甲烷和含氧气体的燃料转化为固体氧化物燃料电池堆中的电。

    Process for the preparationn of hydrocarbons from oxygenates
    3.
    发明授权
    Process for the preparationn of hydrocarbons from oxygenates 有权
    从含氧化合物制备烃的方法

    公开(公告)号:US08067474B2

    公开(公告)日:2011-11-29

    申请号:US12725555

    申请日:2010-03-17

    IPC分类号: C07C27/00

    摘要: A process for the preparation of hydrocarbon products comprising the steps of a) providing a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; (b) reacting at least part of the synthesis gas to an oxygenate mixture comprising methanol and dimethyl ether in presence of one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates at a pressure of at least 3 MPa; (c) withdrawing from step (b) a reaction mixture comprising amounts of methanol, dimethyl ether, carbon dioxide and water together with unreacted synthesis gas and cooling the reaction mixture to obtain a liquid phase with the amounts of methanol, dimethyl ether and water and simultaneously dissolving carbon dioxide in the liquid phase; (d) separating the carbon dioxide containing liquid phase from a remaining gaseous phase comprising hydrogen and carbon monoxide; (e) evaporating and reacting the liquid phase being withdrawn from step (d) in presence of a catalyst being active in the conversion of oxygenates to higher hydrocarbons and a tail gas comprising carbon dioxide; (f) separating tail gas from a liquid phase with the higher hydrocarbons; and wherein pressure employed in step (c) to step (f) is substantially the same as employed in step (b).

    摘要翻译: 一种用于制备烃产物的方法,包括以下步骤:a)提供包含氢气,一氧化碳和二氧化碳的合成气体; (b)在一种或多种催化剂的存在下使至少部分合成气与包含甲醇和二甲醚的含氧化合物反应,所述催化剂在至少3MPa的压力下共同催化氢和一氧化碳与含氧化合物的反应; (c)从步骤(b)中取出含有甲醇,二甲醚,二氧化碳和水以及未反应的合成气的反应混合物并冷却反应混合物以获得具有甲醇,二甲醚和水的量的液相,以及 同时将二氧化碳溶解在液相中; (d)从包含氢气和一氧化碳的剩余气相中分离含二氧化碳的液相; (e)在将氧化物转化为高级烃和包含二氧化碳的尾气的催化剂存在下,使从步骤(d)中取出的液相蒸发和反应; (f)用高级烃分离尾气与液相; 并且其中在步骤(c)至步骤(f)中使用的压力与步骤(b)中采用的基本相同。

    Fuel processing method and system
    8.
    发明授权
    Fuel processing method and system 失效
    燃料加工方法和系统

    公开(公告)号:US07641994B2

    公开(公告)日:2010-01-05

    申请号:US11143708

    申请日:2005-06-03

    IPC分类号: H01M5/00

    摘要: A fuel processing method for a solid oxide fuel cell stack comprising the steps of: (a) supplying a feed stream comprising methanol and/or dimethyl ether to a methanation reactor containing catalytic material for the methanation of methanol and/or dimethyl ether; (b) processing the feed stream in the methanation reactor under adiabatic conditions to produce an effluent fuel comprising methane; (c) transferring the effluent fuel comprising methane to the anode of a solid oxide fuel cell stack comprising at least one solid oxide fuel cell; (d) providing the cathode of the solid oxide fuel cell stack with an oxygen-containing gas; and (e) converting the fuel comprising methane and the oxygen-containing gas into electricity in the solid oxide fuel cell stack.

    摘要翻译: 一种固体氧化物燃料电池堆的燃料处理方法,包括以下步骤:(a)将含有甲醇和/或二甲醚的进料流供应到含有用于甲醇化和/或二甲醚甲烷化的催化材料的甲烷化反应器; (b)在绝热条件下处理甲烷化反应器中的进料流以产生包含甲烷的废气; (c)将包含甲烷的废气燃料转移到包含至少一个固体氧化物燃料电池的固体氧化物燃料电池堆的阳极; (d)用含氧气体提供固体氧化物燃料电池堆的阴极; 和(e)将包含甲烷和含氧气体的燃料转化为固体氧化物燃料电池堆中的电。

    PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM OXYGENATES
    9.
    发明申请
    PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM OXYGENATES 有权
    从氧化物中制备碳氢化合物的方法

    公开(公告)号:US20100240779A1

    公开(公告)日:2010-09-23

    申请号:US12725555

    申请日:2010-03-17

    IPC分类号: C07C1/04

    摘要: A process for the preparation of hydrocarbon products comprising the steps of a) providing a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; (b) reacting at least part of the synthesis gas to an oxygenate mixture comprising methanol and dimethyl ether in presence of one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates at a pressure of at least 3 MPa; (c) withdrawing from step (b) a reaction mixture comprising amounts of methanol, dimethyl ether, carbon dioxide and water together with unreacted synthesis gas and cooling the reaction mixture to obtain a liquid phase with the amounts of methanol, dimethyl ether and water and simultaneously dissolving carbon dioxide in the liquid phase; (d) separating the carbon dioxide containing liquid phase from a remaining gaseous phase comprising hydrogen and carbon monoxide; (e) evaporating and reacting the liquid phase being withdrawn from step (d) in presence of a catalyst being active in the conversion of oxygenates to higher hydrocarbons and a tail gas comprising carbon dioxide; (f) separating tail gas from a liquid phase with the higher hydrocarbons; and wherein pressure employed in step (c) to step (f) is substantially the same as employed in step (b).

    摘要翻译: 一种用于制备烃产物的方法,包括以下步骤:a)提供包含氢气,一氧化碳和二氧化碳的合成气体; (b)在一种或多种催化剂的存在下使至少部分合成气与包含甲醇和二甲醚的含氧化合物反应,所述催化剂在至少3MPa的压力下共同催化氢和一氧化碳与含氧化合物的反应; (c)从步骤(b)中取出含有甲醇,二甲醚,二氧化碳和水以及未反应的合成气的反应混合物并冷却反应混合物以获得具有甲醇,二甲醚和水的量的液相,以及 同时将二氧化碳溶解在液相中; (d)从包含氢气和一氧化碳的剩余气相中分离含二氧化碳的液相; (e)在将氧化物转化为高级烃和包含二氧化碳的尾气的催化剂存在下,使从步骤(d)中取出的液相蒸发和反应; (f)用高级烃分离尾气与液相; 并且其中在步骤(c)至步骤(f)中使用的压力与步骤(b)中采用的基本相同。