摘要:
In a NOx removal catalyst used for removing nitrogen oxides in flue gas, when a silica (Si) component as an inhibitor that causes an increase in a SO2 oxidation rate accumulates on a surface of the catalyst, the silica component accumulating on the surface of the catalyst is dissolved, thereby regenerating the catalyst. Accordingly, the inhibitor such as the silica component covering the surface of the NOx removal catalyst can be removed, thereby enabling to provide a catalyst without having an increase in the SO2 oxidation rate of the regenerated NOx removal catalyst.
摘要:
Provided is an exhaust gas treatment catalyst including: a de-NOx catalyst; and a coating layer being provided on a surface of the de-NOx catalyst and containing at least one selected from the group consisting of alkali metal carbonates and alkaline earth metal carbonates.In a method for regenerating an exhaust gas treatment catalyst of the present invention, the coating layer of the de-NOx catalyst on which VOSO4 is deposited is removed with an acid, and after the removal of the coating layer, a coating layer containing at least one selected from the group consisting of alkali metal carbonates and alkaline earth metal carbonates is again provided.
摘要:
To provide a catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds whose oxidation power has been enhanced without increasing the amount of precious metal supported thereon; a method for producing the same; and a method for treating exhaust gases. A catalyst for treating exhaust gases, including coat layers made up of a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein, can be obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying.
摘要:
A catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds includes a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein. The catalyst is obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying. The oxidation power of the resulting catalyst is enhanced without increasing the amount of precious metal supported thereon.
摘要:
Provided is a catalyst for treating exhaust gas capable of reducing the amount of a highly corrosive mercury-chlorinating agent to be added while keeping the mercury oxidation efficiency high in an exhaust gas treatment. By the catalyst for treating exhaust gas, nitrogen oxide in the exhaust gas is removed upon contact with ammonia serving as a reducing agent, and mercury is oxidized using a halogen serving as an oxidant. The catalyst includes: TiO2 as a support; an oxide of at least one selected from the group consisting of V, W and Mo, which is supported as an active component on the support; and at least one selected from the group consisting of Bi, P, and compounds containing Bi and/or P, which is supported as a co-catalyst component on the support.
摘要:
An exhaust gas treating apparatus removes nitrogen oxides and mercury in an exhaust gas from a boiler by use of an ammonia denitration catalyst, the exhaust gas treating apparatus including: an ammonium chloride powder feed unit 101 for feeding ammonium chloride, in powder form, into any one of or both of a vicinity of an entrance of an economizer 15 provided to a combustion gas flue of the boiler and an economizer bypass unit 15a, the fed ammonium chloride in powder form being sublimed by a combustion gas, to thereby feed hydrogen chloride and ammonia into the flue 102; and an ammonium chloride liquid feed unit 110 for feeding ammonium chloride, in liquid form, into any one of or both of a vicinity of the entrance of the economizer 15 and the economizer bypass unit 15a, the ammonium chloride liquid feed unit 110 also being capable of feeding ammonium chloride, vaporization of the fed ammonium chloride in liquid form by the combustion gas also allowing hydrogen chloride and ammonia to be fed into the flue 102.
摘要:
An air pollution control apparatus according to the present invention reduces nitrogen oxides and oxidizes mercury in flue gas 16 discharged from a boiler by an ammonia denitrating catalyst. The air pollution control apparatus includes an economizer bypassing unit 15a that diverts high-temperature combustion gas 11 to a downstream side while bypassing an economizer 15 provided in a gas flue 10a for combustion gas 11 from the boiler, provided with an ammonium-chloride supply unit 101 that supplies powdery ammonium chloride (NH4Cl) to the economizer bypassing unit 15a. The air pollution control apparatus sublimates the ammonium chloride in an atmosphere at a high temperature of the combustion gas 11, and supplies hydrogen chloride and ammonium into the flue gas flue 102.
摘要:
To provide a catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds whose oxidation power has been enhanced without increasing the amount of precious metal supported thereon; a method for producing the same; and a method for treating exhaust gases. A catalyst for treating exhaust gases, including coat layers made up of a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein, can be obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying.
摘要:
Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
摘要翻译:本发明提供一种脱硝活性高,能够抑制副反应即SO2氧化的烟道气脱硝催化剂。 和催化剂的制备方法。 烟气脱硝催化剂包括TiO 2,WO 3和V 2 O 5。 在催化剂的表面200μm以内的表面层中,将V 2 O 5负载在含有TiO 2和WO 3的载体上。 V2O5的负载量为0.4〜5wt。 %,基于表层的重量,为0.1-0.9wt。 %,基于催化剂的总重量。 如此支持的V 2 O 5通过X射线衍射测得的微晶尺寸小于10nm。 催化剂可以通过制备含有TiO 2和WO 3的混合物并且通过气相法将V 2 O 5负载在所制备的混合物的挤出产品的表面上来获得。 催化剂也可以通过使V 2 O 5通过气相法在制备的混合物的粉末上负载并将所得粉末负载在成形产品的表面上来获得。
摘要:
An object of the present invention is to provide a catalyst for treating exhaust gas adapted not only to remove CO and VOCs based on unsaturated hydrocarbons such as C2H4 but also to accelerate a decomposition reaction of saturated hydrocarbons such as propane and to provide a method for producing such a catalyst for treating exhaust gas. The present invention provides a catalyst for treating an exhaust gas containing carbon monoxide and volatile organic compounds, the catalyst comprising a substrate containing a NOx removal catalyst component and a porous inorganic compound layer containing a noble metal, the layer being applied to the substrate.
摘要翻译:本发明的目的是提供一种用于处理废气的催化剂,其不仅适用于除去基于不饱和烃如C 2 H 4的CO和VOC,而且还用于加速饱和烃如丙烷的分解反应,并提供一种生产方法 这种用于处理废气的催化剂。 本发明提供一种用于处理含有一氧化碳和挥发性有机化合物的废气的催化剂,该催化剂包括含有除去NOx的催化剂组分的基质和含有贵金属的多孔无机化合物层,该层被施加到基材上。