公开(公告)号：US07156944B2

公开(公告)日：2007-01-02

申请号：US11042600

申请日：2005-01-24

Applicant: Thomas Moeller ,  Marcus Heemann ,  Andreas Ferencz

Inventor： Thomas Moeller ,  Marcus Heemann ,  Andreas Ferencz

IPC: B29C65/14 ,  B29C65/40 ,  C08L53/02 ,  C09J153/00 ,  C08J32/28 ,  C08F2/46

CPC classification number: C09J121/00 ,  C08F291/02 ,  C09J4/06 ,  C08F279/02

Abstract: To obtain an adhesive having both a high initial adhesive capacity and high heat resistance, a fusible adhesive which can be cross-linked by radiation and a low tendency to creep is provided. The adhesive contains 0 to 40 weight percent of at least one elastomer which cannot be cross-linked by radiation, 15 to 40 weight percent of at least one compound containing at least two olefinic double bonds, and 20 to 85 weight percent of at least one tackifier. The adhesive is especially suitable for use on high speed labeling machines.

Abstract translation: 为了获得具有高初始粘合能力和高耐热性的粘合剂，提供了可以通过辐射交联并且具有低的蠕变倾向的可熔粘合剂。 粘合剂含有0至40重量％的至少一种弹性体，其不能通过辐射交联，15至40重量％的至少一种含有至少两个烯属双键的化合物和20至85重量％的至少一种 增粘剂 该粘合剂特别适用于高速贴标机。

公开(公告)号：US5985074A

公开(公告)日：1999-11-16

申请号：US983158

申请日：1997-12-22

Applicant: Marcus Heemann ,  Eckhard Puerkner ,  Wolfgang Klingberg ,  Bernhard Herlfterkamp ,  Hermann Onusseit ,  Ralf Gossen

Inventor： Marcus Heemann ,  Eckhard Puerkner ,  Wolfgang Klingberg ,  Bernhard Herlfterkamp ,  Hermann Onusseit ,  Ralf Gossen

IPC: C09J5/00 ,  B65C9/20 ,  C09J7/02 ,  C09J7/04 ,  C09J11/06 ,  C09J123/00 ,  C09J123/02 ,  C09J129/02 ,  C09J133/02 ,  C09J133/04 ,  C09J167/00 ,  C09J167/02 ,  C09J191/06 ,  C09J201/00 ,  B65C1/00

CPC classification number: C09J123/02 ,  B65C9/20 ,  C09J167/00 ,  C09J7/0207 ,  C09J7/045 ,  Y10T156/1033 ,  Y10T156/1195 ,  Y10T428/15

Abstract: The invention is an adhesive system for applying wrap around labels to containers. The system comprises a hotmelt pick-up adhesive which is active at the temperature which the label is applied and loses its bonding ability after the adhesive sets and an overlap adhesive for bonding the label overlap. At its application temperature, the pick-up adhesive has significantly higher adhesiveness, measured at its application temperature than at its conventional storage temperature. In addition, the adhesive preferably has a greater affinity for the label than for the container bearing the label. Consequently, the label can be easily removed from the hollow body without leaving residues of adhesive. If, nevertheless, a residual adhesive should remain on the hollow body, it can be dissolved by an alkaline solution.

Abstract translation: PCT No.PCT / EP96 / 02753 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT Filed 1996年6月24日PCT公布。 公开号WO97 / 01483 日期1997年1月16日本发明是一种用于将标签包裹在容器上的粘合剂系统。 该系统包括热敏拾取粘合剂，其在施加标签的温度下有活性，并且在粘合剂组之后失去其粘合能力，并且用于粘合标签的重叠粘合剂重叠。 在其使用温度下，拾取粘合剂在其使用温度下比在其常规储存温度下测量的粘合性显着更高。 此外，粘合剂优选对标签的亲和力比承载标签的容器更大。 因此，可以容易地从中空体中去除标签，而不会留下粘合剂残留物。 然而，如果残留的粘合剂应该保留在中空体上，则它可以通过碱性溶液溶解。

公开(公告)号：US08163833B2

公开(公告)日：2012-04-24

申请号：US13040405

申请日：2011-03-04

Applicant: Thomas Moeller ,  Volker Erb ,  Marcus Heemann ,  Dirk Kasper ,  Eckhard Puerkner ,  Bernhard Herlfterkamp

Inventor： Thomas Moeller ,  Volker Erb ,  Marcus Heemann ,  Dirk Kasper ,  Eckhard Puerkner ,  Bernhard Herlfterkamp

IPC: C08L53/00 ,  B05D5/10

CPC classification number: C09J123/0815 ,  C08L2314/06 ,  C08L2666/02 ,  C09J153/00

Abstract: Melt adhesive containing 5 to 40 wt.-% of at least one ethylene-based copolymer and at least one C3 to C20-α-olefin obtained through metallocene-catalyzed polymerization, 10 to 65 wt.-% of at least one tackifying resin, 0 to 35 wt.-% of a plasticizer, 0.01 to 30 wt.-% additives and additional ingredients selected from stabilizers, adhesion promoters, fillers or pigments, waxes and/or other polymers, wherein the total should amount to 100%, characterized in that copolymer A is a block copolymer that exhibits a substantially even elastic behavior in the range of 0° C. to 25° C., measured as the ratio of the storage modulus E′ according to (E′0C−E′25C)/E′25C

Abstract translation: 含有5〜40重量％的至少一种乙烯类共聚物和至少一种通过金属茂催化聚合得到的C3〜C20-α-烯烃的熔融粘合剂，10〜65重量％的至少一种增粘树脂， 0至35重量％的增塑剂，0.01至30重量％的添加剂和选自稳定剂，粘合促进剂，填料或颜料，蜡和/或其它聚合物的其它成分，其中总量应为100％ 在该共聚物A中，嵌段共聚物在0℃〜25℃的范围内显示出基本上均匀的弹性，根据（E'C-E'25℃）的储能模量E' /E'25C<1.5。

公开(公告)号：US07166341B2

公开(公告)日：2007-01-23

申请号：US10762175

申请日：2004-01-21

Applicant: Marcus Heemann ,  Thomas Moeller ,  Ingo Gensch ,  Wolfgang Klingberg

Inventor： Marcus Heemann ,  Thomas Moeller ,  Ingo Gensch ,  Wolfgang Klingberg

IPC: C08L51/08 ,  B32B7/12

CPC classification number: C08F283/06 ,  C09J151/08 ,  Y10T156/1028 ,  Y10T428/13 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/28 ,  Y10T428/31504 ,  Y10T428/31855

Abstract: Water-soluble or water-dispersible hotmelt adhesives are prepared using graft copolymers produced by graft copolymerizing olefinically unsaturated monomers onto polyalkylene oxides. The adhesives additionally contain at least one resin which improves tackiness and the compatibility of the adhesive components. Other components such as polymers, plasticizers, and additives may also be present. The adhesives are especially suited for use in the labelling of recyclable or reuseable hollow containers. The adhesive may be completely separated from the hollow containers and dissolved in an alkaline washing liquor even at low temperatures.

Abstract translation: 使用通过将烯属不饱和单体接枝共聚在聚环氧烷上制备的接枝共聚物来制备水溶性或水分散性热熔粘合剂。 粘合剂另外含有至少一种改善粘合剂组分的粘合性和相容性的树脂。 也可以存在其它组分如聚合物，增塑剂和添加剂。 粘合剂特别适合用于可回收或可重复使用的中空容器的标签。 即使在低温下，粘合剂也可以与中空容器完全分离并溶解在碱性洗涤液中。

公开(公告)号：US06641911B1

公开(公告)日：2003-11-04

申请号：US09600035

申请日：2000-09-13

Applicant: Eckhard Puerkner ,  Andreas Ferencz ,  Marcus Heemann ,  Thomas Huver ,  Hermann Onusseit

Inventor： Eckhard Puerkner ,  Andreas Ferencz ,  Marcus Heemann ,  Thomas Huver ,  Hermann Onusseit

IPC: B65C306

CPC classification number: C09J175/16 ,  B65C9/22 ,  C08G18/12 ,  C08G18/672 ,  Y10T156/1033 ,  Y10T428/2809 ,  C08G18/307 ,  C08G18/40

Abstract: Adhesive systems are useful for bonding wrap-around labels using an overlap adhesive in their application to blown plastic containers, more particularly plastic bottles. The adhesive system includes reactive contact adhesives based on multifunctional macromonomer compounds curable in steps by different reaction mechanisms, which may also be present mixed with one-stage reactive mixture components.

Abstract translation: 粘合剂系统可用于使用重叠粘合剂将包裹标签粘合在吹塑塑料容器中，特别是塑料瓶中。 粘合剂系统包括基于可通过不同反应机理步骤固化的多功能大分子单体化合物的反应性接触粘合剂，其也可以与一步反应混合物组分混合。

公开(公告)号：US08076422B2

公开(公告)日：2011-12-13

申请号：US12813694

申请日：2010-06-11

Applicant: Marcus Heemann ,  Eckhard Pürkner ,  Volker Erb ,  Maja Schroeder ,  Dirk Vianden

Inventor： Marcus Heemann ,  Eckhard Pürkner ,  Volker Erb ,  Maja Schroeder ,  Dirk Vianden

IPC: C08L23/16 ,  C08K5/01

CPC classification number: B32B27/32 ,  B32B7/06 ,  B32B7/12 ,  B32B27/08 ,  B32B27/304 ,  B32B27/34 ,  B32B27/36 ,  B32B2250/24 ,  B32B2307/308 ,  B32B2307/5825 ,  B32B2307/702 ,  B32B2307/748 ,  B32B2405/00 ,  B32B2439/40 ,  B32B2439/46 ,  B32B2439/70 ,  C08L91/06 ,  C08L2314/06 ,  C09J123/083 ,  C09J123/0869

Abstract: A hot-melt adhesive for resealable packaging, containing 30 to 90 wt. % of at least one copolymer based on ethylene and/or propylene together with C4 to C12-α-olefins, which is obtainable by metallocene-catalyzed polymerization, with a melt index of 5 to 100 g/10 min (DIN ISO 1133), 5 to 50 wt. % of tackifier resins with a softening point of 80 to 140° C., 0 to 15 wt. % of waxes with a melting point of 120 to 170° C., 0.1 to 20 wt. % of additives and auxiliaries, the adhesive having a viscosity of 25,000 mPa·s to 250,000 mPa·s, measured at a temperature of 170 to 190° C.

Abstract translation: 一种用于可再密封包装的热熔粘合剂，含有30至90wt。 至少一种基于乙烯和/或丙烯的共聚物以及可通过金属茂催化聚合获得的C4至C12-α-烯烃，熔体指数为5至100g / 10min（DIN ISO 1133）， 5至50wt。 软化点为80〜140℃的增粘树脂的％，0〜15重量％ 熔点为120〜170℃的蜡的％，0.1〜20重量％ ％的添加剂和助剂，粘合剂的粘度为25,000mPa·s至250,000mPa·s，在170至190℃的温度下测量。

公开(公告)号：US20110213067A1

公开(公告)日：2011-09-01

申请号：US13040405

申请日：2011-03-04

Applicant: Thomas Moeller ,  Volker Erb ,  Marcus Heemann ,  Dirk Kasper ,  Eckhard Puerkner ,  Bernhard Herlfterkamp

Inventor： Thomas Moeller ,  Volker Erb ,  Marcus Heemann ,  Dirk Kasper ,  Eckhard Puerkner ,  Bernhard Herlfterkamp

IPC: C08L53/00 ,  B05D5/10

CPC classification number: C09J123/0815 ,  C08L2314/06 ,  C08L2666/02 ,  C09J153/00

Abstract: Melt adhesive containing 5 to 40 wt.-% of at least one ethylene-based copolymer and at least one C3 to C20 -α-olefin obtained through metallocene-catalyzed polymerization, 10 to 65 wt.-% of at least one tackifying resin, 0 to 35 wt.-% of a plasticizer, 0.01 to 30 wt.-% additives and additional ingredients selected from stabilizers, adhesion promoters, fillers or pigments, waxes and/or other polymers, wherein the total should amount to 100%, characterized in that copolymer A is a block copolymer that exhibits a substantially even elastic behavior in the range of 0° C. to 25° C., measured as the ratio of the storage modulus E′ according to (E′0C−E′25C)/E′25C

Abstract translation: 含有5〜40重量％的至少一种乙烯类共聚物和至少一种通过金属茂催化聚合得到的C3〜C20-α-烯烃的熔融粘合剂，10〜65重量％的至少一种增粘树脂， 0至35重量％的增塑剂，0.01至30重量％的添加剂和选自稳定剂，粘合促进剂，填料或颜料，蜡和/或其它聚合物的其它成分，其中总量应为100％ 在该共聚物A中，嵌段共聚物在0℃〜25℃的范围内显示出基本上均匀的弹性，根据（E'C-E'25℃）的储能模量E' /E'25C<1.5。

公开(公告)号：US20100256274A1

公开(公告)日：2010-10-07

申请号：US12813694

申请日：2010-06-11

Applicant: Marcus Heemann ,  Eckhard Pürkner ,  Volker Erb ,  Maja Schroeder ,  Dirk Vianden

Inventor： Marcus Heemann ,  Eckhard Pürkner ,  Volker Erb ,  Maja Schroeder ,  Dirk Vianden

IPC: C09J123/08 ,  C09J131/02 ,  C09J193/04 ,  B29C49/04

CPC classification number: B32B27/32 ,  B32B7/06 ,  B32B7/12 ,  B32B27/08 ,  B32B27/304 ,  B32B27/34 ,  B32B27/36 ,  B32B2250/24 ,  B32B2307/308 ,  B32B2307/5825 ,  B32B2307/702 ,  B32B2307/748 ,  B32B2405/00 ,  B32B2439/40 ,  B32B2439/46 ,  B32B2439/70 ,  C08L91/06 ,  C08L2314/06 ,  C09J123/083 ,  C09J123/0869

Abstract: A hot-melt adhesive for resealable packaging, containing 30 to 90 wt. % of at least one copolymer based on ethylene and/or propylene together with C4 to C12-α-olefins, which is obtainable by metallocene-catalyzed polymerization, with a melt index of 5 to 100 g/10 min (DIN ISO 1133), 5 to 50 wt. % of tackifier resins with a softening point of 80 to 140° C., 0 to 15 wt. % of waxes with a melting point of 120 to 170° C., 0.1 to 20 wt. % of additives and auxiliaries, the adhesive having a viscosity of 25,000 mPa·s to 250,000 mPa·s, measured at a temperature of 170 to 190° C.

Abstract translation: 一种用于可再密封包装的热熔粘合剂，含有30至90wt。 至少一种基于乙烯和/或丙烯的共聚物以及可通过金属茂催化聚合获得的C4至C12-α-烯烃，熔体指数为5至100g / 10min（DIN ISO 1133）， 5至50wt。 软化点为80〜140℃的增粘树脂的％，0〜15重量％ 熔点为120〜170℃的蜡的％，0.1〜20重量％ ％的添加剂和助剂，粘合剂的粘度为25,000mPa·s至250,000mPa·s，在170至190℃的温度下测量。

公开(公告)号：US06677394B1

公开(公告)日：2004-01-13

申请号：US08991365

申请日：1997-12-16

Applicant: Ruediger Butterbach ,  Ulrike Maassen ,  Siegfried Kopannia ,  Marcus Heemann

Inventor： Ruediger Butterbach ,  Ulrike Maassen ,  Siegfried Kopannia ,  Marcus Heemann

IPC: C08K505

CPC classification number: G02B6/4494 ,  H01B7/288

Abstract: Thermoplastic compositions based on a water-insoluble component of one or more thermoplastic copolymers and one or more resins with a saponification number and a water-soluble or water-dispersible component and a water-swellable component from the class of superabsorbers are suitable as water-swellable hotmelt adhesives. Such water-swellable hotmelt adhesives are preferably used for the production of watertight constructions, more particularly for the production of longitudinally watertight cable constructions.

Abstract translation: 基于一种或多种热塑性共聚物的水不溶性组分和一种或多种皂化物和水溶性或水分散性组分的树脂和来自超吸收剂类的水溶胀性组分的热塑性组合物适合作为水 - 可膨胀热熔胶。 这种水溶胀性热熔粘合剂优选用于生产水密结构，更具体地用于生产纵向水密电缆结构。

公开(公告)号：US20050165164A1

公开(公告)日：2005-07-28

申请号：US11042600

申请日：2005-01-24

Applicant: Thomas Moeller ,  Marcus Heemann ,  Andreas Ferencz

Inventor： Thomas Moeller ,  Marcus Heemann ,  Andreas Ferencz

IPC: C09J4/06 ,  C09J121/00 ,  C08L51/00

CPC classification number: C09J121/00 ,  C08F291/02 ,  C09J4/06 ,  C08F279/02

Abstract: To obtain an adhesive having both a high initial adhesive capacity and high heat resistance, a fusible adhesive which can be cross-linked by radiation and a low tendency to creep is provided. The adhesive contains 0 to 40 weight percent of at least one elastomer which cannot be cross-linked by radiation, 15 to 40 weight percent of at least one compound containing at least two olefinic double bonds, and 20 to 85 weight percent of at least one tackifier. The adhesive is especially suitable for use on high speed labeling machines.

Abstract translation: 为了获得具有高初始粘合能力和高耐热性的粘合剂，提供了可以通过辐射交联并且具有低的蠕变倾向的可熔粘合剂。 粘合剂含有0至40重量％的至少一种不能通过辐射交联的弹性体，15至40重量％的至少一种含有至少两个烯属双键的化合物和20至85重量％的至少一种 增粘剂 该粘合剂特别适用于高速贴标机。