公开(公告)号：US09011674B2

公开(公告)日：2015-04-21

申请号：US13314683

申请日：2011-12-08

Applicant: Stanley Nemec Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington ,  Frederik Arnold Buhrman

Inventor： Stanley Nemec Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington ,  Frederik Arnold Buhrman

IPC: C10G65/12 ,  C10G45/04 ,  C10G47/06 ,  B01J23/652 ,  B01J23/85 ,  B01J27/051 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC classification number: C10G65/12 ,  B01J23/652 ,  B01J23/85 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0201 ,  C10G45/04 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

Abstract: A process is provided in which a first hydrocarbon-containing composition is provided where the first hydrocarbon-containing composition comprises hydrocarbons having a boiling range from 25° C. to 538° C. and from 0.1 wt. % to 5 wt. % sulfur, where at least 40 wt. % of the sulfur is contained in hydrocarbons having a boiling point of less than 343° C. where at least 40 wt. % of the sulfur contained in hydrocarbons having a boiling point less than 343° C. is contained in benzothiophenic compounds, and the first hydrocarbon-containing compound is hydrotreated to produce a second hydrocarbon-containing compound.

Abstract translation: 提供了一种方法，其中提供第一含烃组合物，其中第一含烃组合物包含沸点范围为25℃至538℃的烃和0.1重量％ ％至5wt。 ％硫，其中至少40wt。 硫含量在沸点低于343℃的烃中，其中至少40wt。 在苯并噻吩类化合物中含有沸点低于343℃的烃中所含的硫的％，第一含烃化合物被加氢处理以产生第二含烃化合物。

公开(公告)号：US08679319B2

公开(公告)日：2014-03-25

申请号：US13010901

申请日：2011-01-21

Applicant: Stanley Nemee Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington

Inventor： Stanley Nemee Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington

IPC: C10L1/04 ,  C10M101/02

CPC classification number: C10L1/00 ,  C10G47/00 ,  C10G47/02 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/30

Abstract: A hydrocarbon composition is provided containing: at least 0.05 grams of hydrocarbons having boiling point in the range from an initial boiling point of the composition up to 204° C. (400° F.) per gram of the composition; at least 0.1 gram of hydrocarbons having a boiling point in the range from 204° C. up to 260° C. (500° F.) per gram of the composition; at least 0.25 gram of hydrocarbons having a boiling point in the range from 260° C. up to 343° C. per gram of the composition; at least 0.3 gram of hydrocarbons having a boiling point in the range from 343° C. to 538° C. per gram of the composition; and at most 0.03 gram of hydrocarbons having a boiling point of greater than 538° C. per gram of the composition; at least 0.0005 gram of sulfur per gram of the composition, wherein at least 40 wt. % of the sulfur is contained in hydrocarbon compounds having a carbon number of 17 or less as determined by GC-GC sulfur chemiluminescence, where at least 60 wt. % of the sulfur in the sulfur-containing hydrocarbon compounds having a carbon number of 17 or less is contained in benzothiophenic compounds as determined by GC-GC sulfur chemiluminescence.

Abstract translation: 提供一种烃组合物，其含有：至少0.05克沸点在组合物的初沸点至204℃（400°F）范围内的烃/克组合物; 至少0.1克沸点为每克组合物的204℃至260℃（500℉）的烃; 至少0.25克沸点为每克组合物的260℃至343℃的烃; 至少0.3克沸点为每克组合物的343℃至538℃的烃; 和至多0.03克每克组合物沸点大于538℃的烃; 每克组合物至少0.0005克硫，其中至少40重量％ 通过GC-GC硫化学发光测定，碳含量为17或更低的烃化合物中含有的硫％，其中至少60wt。 通过GC-GC硫化学发光测定的苯并噻吩类化合物中含有碳数为17以下的含硫烃化合物中的硫的％。

公开(公告)号：US08597498B2

公开(公告)日：2013-12-03

申请号：US13010938

申请日：2011-01-21

Applicant: Stanley Nemec Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington

Inventor： Stanley Nemec Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington

IPC: C10G47/06 ,  C10G47/02 ,  C10G47/24 ,  C10G47/26

CPC classification number: C10G47/26 ,  B01J27/0515 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/088 ,  C01G19/006 ,  C01G39/006 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/16 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

Abstract: A process for treating a hydrocarbon-containing feedstock is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a metal-containing catalyst to produce a hydrocarbon-containing product. The hydrocarbon-containing feedstock, the catalyst(s), the hydrogen sulfide, and the hydrogen are provided to a mixing zone and blended in the mixing zone at a temperature of from 375° C. to 500° C. and a total pressure of from 6.9 MPa to 27.5 MPa, where hydrogen sulfide is provided at a mole ratio of hydrogen sulfide to hydrogen of at least 0.5:9.5 and the combined hydrogen sulfide and hydrogen partial pressures provide at least 60% of the total pressure. A vapor comprised of hydrocarbons that are vaporizable at the temperature and pressure within the mixing zone is separated from the mixing zone, and, apart from the mixing zone, the vapor may be condensed to produce a liquid hydrocarbon-containing product.

Abstract translation: 提供了一种处理含烃原料的方法，其中含烃进料包含至少20wt。 将重质烃的重量与氢气，硫化氢和含金属的催化剂混合以产生含烃产物。 将含烃原料，催化剂，硫化氢和氢气提供到混合区，并在混合区中在375℃至500℃的温度下共混， 从6.9MPa至27.5MPa，其中以硫化氢与氢的摩尔比提供至少0.5:9.5的硫化氢，并且组合的硫化氢和氢分压提供至少总压的60％。 由在混合区内的温度和压力下可蒸发的烃组成的蒸气与混合区分离，并且除混合区之外，蒸气可以冷凝以产生含液体烃的产物。

公开(公告)号：US20120145596A1

公开(公告)日：2012-06-14

申请号：US13314683

申请日：2011-12-08

Applicant: Stanley Nemec MILAM ,  Michael Anthony REYNOLDS ,  Scott Lee WELLINGTON ,  Frederik Arnold BUHRMAN

Inventor： Stanley Nemec MILAM ,  Michael Anthony REYNOLDS ,  Scott Lee WELLINGTON ,  Frederik Arnold BUHRMAN

IPC: C10G1/04

CPC classification number: C10G65/12 ,  B01J23/652 ,  B01J23/85 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0201 ,  C10G45/04 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

Abstract: A process is provided in which a first hydrocarbon-containing composition is provided where the first hydrocarbon-containing composition comprises hydrocarbons having a boiling range from 25° C. to 538° C. and from 0.1 wt. % to 5 wt. % sulfur, where at least 40 wt. % of the sulfur is contained in hydrocarbons having a boiling point of less than 343° C. where at least 40 wt. % of the sulfur contained in hydrocarbons having a boiling point less than 343° C. is contained in benzothiophenic compounds, and the first hydrocarbon-containing compound is hydrotreated to produce a second hydrocarbon-containing compound.

Abstract translation: 提供了一种方法，其中提供第一含烃组合物，其中第一含烃组合物包含沸点范围为25℃至538℃的烃和0.1重量％ ％至5wt。 ％硫，其中至少40wt。 硫含量在沸点低于343℃的烃中，其中至少40wt。 在苯并噻吩类化合物中含有沸点低于343℃的烃中所含的硫的％，第一含烃化合物被加氢处理以产生第二含烃化合物。

公开(公告)号：US20110192764A1

公开(公告)日：2011-08-11

申请号：US13010895

申请日：2011-01-21

Applicant: Michael Anthony Reynolds ,  Stanley Nemee Milam ,  Scott Lee Wellington

Inventor： Michael Anthony Reynolds ,  Stanley Nemee Milam ,  Scott Lee Wellington

IPC: C10G57/00 ,  C10G47/02

CPC classification number: C10G47/06 ,  B01J27/049 ,  B01J27/0515 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/088 ,  C10G47/26 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

Abstract: A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen and a catalyst to produce a hydrocarbon-containing product. The catalyst is comprised of a material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Bi, Ag, Mn, Zn, Sn, Ru, La, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb. The material of the catalyst may have a structure according to formula (I), formula (II), formula (III), or formula (IV):

Abstract translation: 提供了一种处理含烃进料的方法，其中含烃进料包含至少20wt。 将重质烃的重量与氢气和催化剂混合以产生含烃产物。 催化剂由包含第一金属和第二金属的材料组成，其中第一金属选自Cu，Fe，Bi，Ag，Mn，Zn，Sn，Ru，La，Pr，Sm， Eu，Yb，Lu，Dy，Pb和Sb，第二金属是Mo，W，V，Sn和Sb。 催化剂的材料可以具有式（I），式（II），式（III）或式（IV）的结构：

公开(公告)号：US20110186477A1

公开(公告)日：2011-08-04

申请号：US13010912

申请日：2011-01-21

Applicant: Stanley Nemec MILAM ,  Michael Anthony Reynolds ,  Scott Lee Wellington

Inventor： Stanley Nemec MILAM ,  Michael Anthony Reynolds ,  Scott Lee Wellington

IPC: C10L1/222

CPC classification number: C10L1/00 ,  C10G47/00 ,  C10G47/02 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/30

Abstract: A hydrocarbon composition is provided containing:at least 0.05 grams of hydrocarbons having boiling point in the range from an initial boiling point of the composition up to 204° C. (400° F.) per gram of the composition;at least 0.1 gram of hydrocarbons having a boiling point in the range from 204° C. up to 260° C. (500° F.) per gram of the composition;at least 0.25 gram of hydrocarbons having a boiling point in the range from 260° C. up to 343° C. per gram of the composition;at least 0.3 gram of hydrocarbons having a boiling point in the range from 343° C. up to 510° C. per gram of the composition; andat most 0.03 gram of hydrocarbons having a boiling point of greater than 538° C. per gram of the composition;at least 0.0005 gram of nitrogen per gram of the composition, wherein at least 30 wt. % of the nitrogen in the hydrocarbon composition is contained in nitrogen-containing hydrocarbon compounds having a carbon number of 17 or less as determined by GC-GC nitrogen chemiluminscence.

Abstract translation: 提供一种烃组合物，其含有：至少0.05克沸点在组合物的初沸点至204℃（400°F）范围内的烃/克组合物; 至少0.1克沸点为每克组合物的204℃至260℃（500℉）的烃; 至少0.25克沸点为每克组合物的260℃至343℃的烃; 至少0.3克沸点为每克组合物的343℃至510℃的烃; 和至多0.03克每克组合物沸点大于538℃的烃; 至少0.0005克氮/克组合物，其中至少30重量％ 通过GC-GC氮化学发光测定，烃组合物中的氮的％含有碳数为17以下的含氮烃化合物。

公开(公告)号：US20110178346A1

公开(公告)日：2011-07-21

申请号：US13010901

申请日：2011-01-21

Applicant: Stanley Nemee Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington

Inventor： Stanley Nemee Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington

IPC: C07C7/20

CPC classification number: C10L1/00 ,  C10G47/00 ,  C10G47/02 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/30

Abstract: A hydrocarbon composition is provided containing: at least 0.05 grams of hydrocarbons having boiling point in the range from an initial boiling point of the composition up to 204° C. (400° F.) per gram of the composition; at least 0.1 gram of hydrocarbons having a boiling point in the range from 204° C. up to 260° C. (500° F.) per gram of the composition; at least 0.25 gram of hydrocarbons having a boiling point in the range from 260° C. up to 343° C. per gram of the composition; at least 0.3 gram of hydrocarbons having a boiling point in the range from 343° C. to 538° C. per gram of the composition; and at most 0.03 gram of hydrocarbons having a boiling point of greater than 538° C. per gram of the composition; at least 0.0005 gram of sulfur per gram of the composition, wherein at least 40 wt. % of the sulfur is contained in hydrocarbon compounds having a carbon number of 17 or less as determined by GC-GC sulfur chemiluminescence, where at least 60 wt. % of the sulfur in the sulfur-containing hydrocarbon compounds having a carbon number of 17 or less is contained in benzothiophenic compounds as determined by GC-GC sulfur chemiluminescence.

Abstract translation: 提供一种烃组合物，其含有：至少0.05克沸点在组合物的初沸点至204℃（400°F）范围内的烃/克组合物; 至少0.1克沸点为每克组合物的204℃至260℃（500℉）的烃; 至少0.25克沸点为每克组合物的260℃至343℃的烃; 至少0.3克沸点为每克组合物的343℃至538℃的烃; 和至多0.03克每克组合物沸点大于538℃的烃; 每克组合物至少0.0005克硫，其中至少40重量％ 通过GC-GC硫化学发光测定，碳含量为17或更低的烃化合物中含有的硫％，其中至少60wt。 通过GC-GC硫化学发光测定的苯并噻吩类化合物中含有碳数为17以下的含硫烃化合物中的硫的％。

公开(公告)号：US20110177336A1

公开(公告)日：2011-07-21

申请号：US13010894

申请日：2011-01-21

Applicant: Charles Roy Donaho ,  Michael Anthony Reynolds

Inventor： Charles Roy Donaho ,  Michael Anthony Reynolds

IPC: B32B5/16

CPC classification number: C01G39/006 ,  B01J23/8878 ,  B01J27/049 ,  B01J27/0515 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/088 ,  B82Y30/00 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/80 ,  C10G47/02

Abstract: The present invention is directed to a composition comprising a solid material comprised of a first metal/metalloid comprised of a metal or metalloid selected from the group consisting of Cu, Fe, Ag, Co, Mn, Zr, Zn, Sn, Re, Rh, Ru, Pd, Ir, Pt, B, Al, Ce, La, Pb, Cd, Sb, Ge, Ga, In, Bi, and Au; and a second metal selected from molybdenum, tungsten, or vanadium, where the first metal/metalloid and the second metal form a bimetallic tetrathiometallate or a bimetallic tetraselenometallate with sulfur or with selenium. The solid material is comprised of particles and has a particle size distribution, where the mean particle size of the particle size distribution is from about 50 nm to about 5 μm.

Abstract translation: 本发明涉及包含固体材料的组合物，该固体材料由选自Cu，Fe，Ag，Co，Mn，Zr，Zn，Sn，Re，Rh中的金属或准金属构成的第一金属/准金属构成 ，Ru，Pd，Ir，Pt，B，Al，Ce，La，Pb，Cd，Sb，Ge，Ga，In，Bi和Au; 和选自钼，钨或钒的第二种金属，其中第一金属/准金属和第二金属与硫或硒形成双金属四金属酸金属或双金属四硒金属盐酸盐。 固体材料由颗粒组成并且具有粒度分布，其中粒度分布的平均粒径为约50nm至约5μm。

公开(公告)号：US20110177334A1

公开(公告)日：2011-07-21

申请号：US13010879

申请日：2011-01-21

Applicant: Michael Anthony REYNOLDS ,  Charles Roy Donaho

Inventor： Michael Anthony REYNOLDS ,  Charles Roy Donaho

IPC: C01G45/00 ,  C01B17/00 ,  D02G3/02 ,  B01J23/34 ,  B82Y30/00

CPC classification number: B01J35/06 ,  B01J27/047 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/082 ,  C01G45/006 ,  C10G33/02 ,  C10G47/02 ,  C10G47/06

Abstract: The present invention is directed to a manganese tetrathiotungstate composition.

Abstract translation: 本发明涉及一种四硫酸锰组合物。

公开(公告)号：US07841407B2

公开(公告)日：2010-11-30

申请号：US12425240

申请日：2009-04-16

Applicant: Scott Lee Wellington ,  Mahendra Ladharam Joshi ,  Jingyu Cui ,  Stanley Nemec Milam ,  Michael Anthony Reynolds

Inventor： Scott Lee Wellington ,  Mahendra Ladharam Joshi ,  Jingyu Cui ,  Stanley Nemec Milam ,  Michael Anthony Reynolds

IPC: E21B43/24 ,  E21B43/40

CPC classification number: E21B43/2408 ,  C09K8/592 ,  E21B36/02 ,  E21B43/20 ,  E21B43/2406 ,  E21B43/305

Abstract: Methods of generating subsurface heat for treating a hydrocarbon containing formation are described herein. The methods include providing a stream that includes water to a plurality of wellbores. Fuel and oxidant is provided to one or more flameless distributed combustors positioned in at least one of the wellbores. The fuel and oxidant is mixed to form a fuel/oxidant mixture. At least a portion of the mixture is flamelessly combusted in at least one of the flameless distributed combustors to generate heat. The fuel includes at least 0.1% hydrogen sulfide by volume.

Abstract translation: 本文描述了产生用于处理含烃地层的地下热的方法。 所述方法包括向多个井筒提供包括水的流。 燃料和氧化剂被提供给位于至少一个井筒中的一个或多个无焰分布式燃烧器。 将燃料和氧化剂混合以形成燃料/氧化剂混合物。 至少一部分混合物在至少一个无焰分布式燃烧器中无火焰燃烧以产生热量。 燃料包括至少0.1体积％的硫化氢。