公开(公告)号：US08691900B2

公开(公告)日：2014-04-08

申请号：US13451588

申请日：2012-04-20

申请人： Peter Wrobel

发明人： Peter Wrobel

IPC分类号： C09D133/00 ,  C09D133/02

CPC分类号： F16B39/225 ,  C08F222/1006 ,  C08F265/02 ,  C09D151/00 ,  C08F222/10 ,  C08F220/16 ,  C08F2/10 ,  C08L2666/24 ,  C08L2666/02

摘要： The present invention relates to aqueous-based compositions suitable for use in threadlocking applications comprising: a) at least one carboxyl group containing (co)polymer; b) at least one polymerizable monomer A containing one acryloyl group; c) at least one polymerizable compound B containing at least two acryloyl groups; d) at least one encapsulated free radical initiator; and e) water. The inventive aqueous-based compositions are preferably substantially free of volatile organic solvents.

摘要翻译： 本发明涉及适用于螺纹锁定应用的水基组合物，其包含：a）至少一种含羧基（共）聚合物; b）至少一种含有一个丙烯酰基的可聚合单体A; c）至少一种含有至少两个丙烯酰基的可聚合化合物B; d）至少一个包封的自由基引发剂; 和e）水。 本发明的水基组合物优选基本上不含挥发性有机溶剂。

公开(公告)号：US20110290418A1

公开(公告)日：2011-12-01

申请号：US13177921

申请日：2011-07-07

申请人： Philip T. Klemarczyk ,  David Birkett ,  David Farrell ,  Peter Wrobel ,  Ciaran McArdle ,  Greg Clarke

发明人： Philip T. Klemarczyk ,  David Birkett ,  David Farrell ,  Peter Wrobel ,  Ciaran McArdle ,  Greg Clarke

IPC分类号： B32B37/12 ,  C07C233/31 ,  C07C275/02 ,  C07D207/26 ,  C09J4/02 ,  C09K3/00

CPC分类号： C07C275/02 ,  C07C275/06 ,  C09J4/00 ,  C09J5/06

摘要： Provided is a complex of hydrogen peroxide and at least one compound represented by Formula I: wherein X is: —C(R3)3, —C≡C(R3), —O(R3), —N(R3)2, or —S(R3); and R1, R2, and R3 are each independently selected from H, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl heteroarylalkyl, heterocyclyl, and cycloalkyl, or R2 and an R3 are optionally taken together to form an alicyclic ring. Also provided are anaerobic cure systems and curable compositions employing the complexes described herein.

摘要翻译： 提供了过氧化氢和至少一种由式I表示的化合物的络合物：其中X是：-C（R 3）3，-C≡C（R 3），-O（R 3），-N（R 3）2或 -S（R 3）; 并且R 1，R 2和R 3各自独立地选自H，烷基，烯基，炔基，芳烷基，芳基，杂芳基杂芳基烷基，杂环基和环烷基，或者R 2和R 3任选地一起形成脂环族环。 还提供了使用本文所述复合物的厌氧固化体系和可固化组合物。

公开(公告)号：US4497916A

公开(公告)日：1985-02-05

申请号：US525351

申请日：1983-08-22

申请人： Bernard Cooke ,  Peter Wrobel

发明人： Bernard Cooke ,  Peter Wrobel

IPC分类号： C09J4/00 ,  C09J4/06 ,  F16B33/06 ,  F16B39/22 ,  B32B7/12 ,  C08K9/10 ,  C09J5/02 ,  F16B39/00

CPC分类号： F16B39/225 ,  C09J4/00 ,  C09J4/06 ,  F16B33/06 ,  Y10T428/31699 ,  Y10T428/31935

摘要： An improved sealing or adhesive composition comprising a stable slurry of solid meltable wax-like particles dispersed in a liquid adhesive or sealant composition, such as an anaerobic adhesive of sealant, which may be caused to cure at a time later than the time of application. The composition may be applied to threaded bolts or other articles by pumping the slurry through a heated applicator head to dispense homogeneous liquid on the article which hardens on cooling to a non-mobile setable coating.

摘要翻译： 一种改进的密封或粘合剂组合物，其包含分散在液体粘合剂或密封剂组合物中的固体可熔融蜡状颗粒的稳定淤浆，例如密封剂的厌氧粘合剂，其可以在施用时间之后的时间固化。 组合物可以通过将浆料泵送通过加热的涂抹器头部来分配在制品上的均匀液体，以冷却到不可移动的可设置涂层上而将其施加到螺纹螺栓或其它制品上。

公开(公告)号：US20090255594A1

公开(公告)日：2009-10-15

申请号：US12397047

申请日：2009-03-03

申请人： Matthias Haller ,  Martin J. Fitzpatrick ,  Fergal A. Gordon ,  Karen O'Flynn ,  Peter Wrobel

发明人： Matthias Haller ,  Martin J. Fitzpatrick ,  Fergal A. Gordon ,  Karen O'Flynn ,  Peter Wrobel

IPC分类号： B05C11/10 ,  C08L33/08 ,  C08L33/10 ,  F16B39/00

CPC分类号： B05C13/025 ,  B05B13/0235 ,  B05C5/001 ,  B05C5/02 ,  B05C9/02 ,  B05C9/14 ,  B05C11/10 ,  C08F290/06 ,  Y10T137/85986

摘要： An apparatus (1) for the application of a composition curable by irradiation to a fastener (2) having: a conveyor (3) for conveying fasteners to an application station (5); an application station (10) comprising an applicator from which the composition is dispensed. The conveyor rotates the fasteners past the applicator for application of composition. The same or another conveyor (8) conveys the fasteners to an irradiation station (10) and rotates the fasteners for irradiation thereof. The irradiation station irradiates and thus cures the composition applied to each fastener. The invention also provides A curable composition for application to a threaded article, comprising a dispersion of: (i) components of a first cure mechanism comprising: (a) a (meth)acrylate functional monomer component; (b) a (meth)acrylate functional oligomer component; and (c) a photoinitiator component; (ii) components of a second cure mechanism comprising: (e) an amine component; and (f) an encapsulated epoxy resin component; together with (iii) a thickener component suitable to impart sufficient viscosity to the uncured composition to maintain the dispersion of the other components in the composition; wherein the photoinitiator component is suitable upon irradiation of the composition to achieve a first cure through the depth of the composition applied to a threaded article so that a binder matrix is formed with the components of the second cure mechanism dispersed through the matrix.

摘要翻译： 一种用于将通过照射固化的组合物施用于紧固件（2）的装置（1），其具有：用于将紧固件输送到施加站（5）的输送机（3）; 包括施用组件（10），其中分配有组合物。 输送机将紧固件旋转通过施加器以施加组合物。 相同或另一个输送机（8）将紧固件传送到照射站（10）并旋转紧固件以进行照射。 照射站照射并因此固化施加到每个紧固件上的组合物。 本发明还提供了一种用于螺纹制品的可固化组合物，其包含以下分散体：（i）第一固化机构的组分，其包含：（a）（甲基）丙烯酸酯官能单体组分; （b）（甲基）丙烯酸酯官能低聚物组分; 和（c）光引发剂组分; （ii）第二固化机理的组分，其包含：（e）胺组分; 和（f）包封的环氧树脂组分; 以及（iii）适于赋予未固化的组合物足够的粘度以保持其它组分在组合物中的分散体的增稠剂组分; 其中光引发剂组分适于照射组合物以实现通过施加到螺纹制品的组合物的深度的第一次固化，使得形成粘合剂基质，其中第二固化机理的组分分散在基质中。

公开(公告)号：US07503979B2

公开(公告)日：2009-03-17

申请号：US10527152

申请日：2003-09-11

申请人： Matthias Haller ,  Martin J. Fitzpatrick ,  Fergal A. Gordon ,  Karen O'Flynn ,  Peter Wrobel

发明人： Matthias Haller ,  Martin J. Fitzpatrick ,  Fergal A. Gordon ,  Karen O'Flynn ,  Peter Wrobel

IPC分类号： B05B5/00 ,  B05B13/02 ,  B05C11/00

CPC分类号： B05C13/025 ,  B05B13/0235 ,  B05C5/001 ,  B05C5/02 ,  B05C9/02 ,  B05C9/14 ,  B05C11/10 ,  C08F290/06 ,  Y10T137/85986

摘要： An apparatus (1) for the application of a composition curable by irradiation to a fastener (2) having a conveyor (3) for conveying fasteners to an application station (5); an application station (10) comprising an applicator from which the composition is dispensed. The conveyor rotates the fasteners past the applicator for application of composition. The same or another conveyor (8) conveys the fasteners to an irradiation station (10) and rotates the fasteners for irradiation thereof. The irradiation station irradiates and thus cures the composition applied to each fastener.

摘要翻译： 一种用于将通过照射固化的组合物施用于具有用于将紧固件输送到施用站（5）的传送带（3）的紧固件（2）的装置（1）; 包括施用组件（10），其中分配有组合物。 输送机将紧固件旋转通过施加器以施加组合物。 相同或另一个输送机（8）将紧固件传送到照射站（10）并旋转紧固件以进行照射。 照射站照射并因此固化施加到每个紧固件上的组合物。

公开(公告)号：US08524034B2

公开(公告)日：2013-09-03

申请号：US13177921

申请日：2011-07-07

申请人： Philip T. Klemarczyk ,  David Birkett ,  David Farrell ,  Peter Wrobel ,  Ciaran McArdle ,  Greg Clarke

发明人： Philip T. Klemarczyk ,  David Birkett ,  David Farrell ,  Peter Wrobel ,  Ciaran McArdle ,  Greg Clarke

IPC分类号： B32B37/12 ,  C07C233/31 ,  C07C275/02 ,  C07D207/26

CPC分类号： C07C275/02 ,  C07C275/06 ,  C09J4/00 ,  C09J5/06

摘要： Provided is a complex of hydrogen peroxide and at least one compound represented by Formula I: wherein X is: —C(R3)3, —C≡C(R3), —O(R3), —N(R3)2, or —S(R3); and R1, R2, and R3 are each independently selected from H, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl heteroarylalkyl, heterocyclyl, and cycloalkyl, or R2 and an R3 are optionally taken together to form an alicyclic ring. Also provided are anaerobic cure systems and curable compositions employing the complexes described herein.

摘要翻译： 提供了过氧化氢和至少一种由式I表示的化合物的络合物：其中X是：-C（R 3）3，-C = C（R 3），-O（R 3），-N（R 3）2或 -S（R 3）; 并且R 1，R 2和R 3各自独立地选自H，烷基，烯基，炔基，芳烷基，芳基，杂芳基杂芳基烷基，杂环基和环烷基，或者R 2和R 3任选地一起形成脂环族环。 还提供了使用本文所述复合物的厌氧固化体系和可固化组合物。

公开(公告)号：US20120201628A1

公开(公告)日：2012-08-09

申请号：US13451588

申请日：2012-04-20

申请人： Peter Wrobel

发明人： Peter Wrobel

IPC分类号： F16B33/06 ,  B32B7/04 ,  B05D3/02 ,  C09D133/00 ,  C09D133/02

CPC分类号： F16B39/225 ,  C08F222/1006 ,  C08F265/02 ,  C09D151/00 ,  C08F222/10 ,  C08F220/16 ,  C08F2/10 ,  C08L2666/24 ,  C08L2666/02

摘要： The present invention relates to aqueous-based compositions suitable for use in threadlocking applications comprising: a) at least one carboxyl group containing (co)polymer; b) at least one polymerizable monomer A containing one acryloyl group; c) at least one polymerizable compound B containing at least two acryloyl groups; d) at least one encapsulated free radical initiator; and e) water. The inventive aqueous-based compositions are preferably substantially free of volatile organic solvents.

摘要翻译： 本发明涉及适用于螺纹锁定应用的水基组合物，其包含：a）至少一种含羧基（共）聚合物; b）至少一种含有一个丙烯酰基的可聚合单体A; c）至少一种含有至少两个丙烯酰基的可聚合化合物B; d）至少一个包封的自由基引发剂; 和e）水。 本发明的水基组合物优选基本上不含挥发性有机溶剂。

公开(公告)号：US20060096535A1

公开(公告)日：2006-05-11

申请号：US10527152

申请日：2003-09-11

申请人： Matthias Haller ,  Martin Fitzpatrick ,  Fergal Gordon ,  Karen O'Flynn ,  Peter Wrobel

发明人： Matthias Haller ,  Martin Fitzpatrick ,  Fergal Gordon ,  Karen O'Flynn ,  Peter Wrobel

IPC分类号： C23C16/00

CPC分类号： B05C13/025 ,  B05B13/0235 ,  B05C5/001 ,  B05C5/02 ,  B05C9/02 ,  B05C9/14 ,  B05C11/10 ,  C08F290/06 ,  Y10T137/85986

摘要： An apparatus (1) for the application of a composition curable by irradiation to a fastener (2) having a conveyor (3) for conveying fasteners to an application station (5); an application station (10) comprising an applicator from which the composition is dispensed. The conveyor rotates the fasteners past the applicator for application of composition. The same or another conveyor (8) conveys the fasteners to an irradiation station (10) and rotates the fasteners for irradiation thereof. The irradiation station irradiates and thus cures the composition applied to each fastener. The invention also provides a curable composition for application to a threaded article, comprising a dispersion of: (i) components of a first cure mechanism comprising: (a) a (meth)acrylate functional monomer component; (b) a (meth)acrylate functional oligomer component; and (c) a photoinitiator component; (ii) components of a second cure mechanism comprising: (e) an amine component; and (f) an encapsulated epoxy resin component; together with (iii) a thickener component suitable to impart sufficient viscosity to the uncured composition to maintain the dispersion of the other components in the composition; wherein the photoinitiator component is suitable upon irradiation of the composition to achieve a first cure through the depth of the composition applied to a threaded article so that a binder matrix is formed with the components of the second cure mechanism dispersed through the matrix.

摘要翻译： 一种用于将通过照射固化的组合物施用于具有用于将紧固件输送到施用站（5）的传送带（3）的紧固件（2）的装置（1）; 包括施用组件（10），其中分配有组合物。 输送机将紧固件旋转通过施加器以施加组合物。 相同或另一个输送机（8）将紧固件传送到照射站（10）并旋转紧固件以进行照射。 照射站照射并因此固化施加到每个紧固件上的组合物。 本发明还提供一种用于螺纹制品的可固化组合物，其包含以下分散体：（i）第一固化机构的组分，其包含：（a）（甲基）丙烯酸酯官能单体组分; （b）（甲基）丙烯酸酯官能低聚物组分; 和（c）光引发剂组分; （ii）第二固化机理的组分，其包含：（e）胺组分; 和（f）包封的环氧树脂组分; 以及（iii）适于赋予未固化的组合物足够的粘度以保持其它组分在组合物中的分散体的增稠剂组分; 其中光引发剂组分适于照射组合物以实现通过施加到螺纹制品的组合物的深度的第一次固化，使得形成粘合剂基质，其中第二固化机理的组分分散在基质中。

公开(公告)号：US5116558A

公开(公告)日：1992-05-26

申请号：US546212

申请日：1990-06-28

申请人： Peter Wrobel ,  James Houlihan

发明人： Peter Wrobel ,  James Houlihan

IPC分类号： B29C45/00 ,  B29L31/26 ,  C08F283/00 ,  C08F290/06 ,  C08J3/24 ,  C08L51/00 ,  C09K3/10 ,  F16J15/14 ,  F16L13/11

CPC分类号： C08L51/00 ,  B29C45/0001 ,  C08F283/006 ,  C08F290/067 ,  C08J3/241 ,  F16J15/14 ,  F16L13/11 ,  B29L2031/26

摘要： A method of forming a gasket in situ between two components which includes injecting into a groove in at least one of said components a curable composition including:one or more free-radical polymerizable vinyl esters, and ingredients of a rapid free-radical cure system therefor,the cure system being inactivated prior to injection of the composition,and the composition having a viscosity at 25.degree. C. in the range from 200 to 500,000 mPas;and permitting the composition to cure.The composition can be a two part composition wherein the first part contains a prepolymer, monomer and activator and the second part a prepolymer, monomer and activator. The composition can also include two expansion reactants, each in a separate part of the composition prior to injection, which react to form a gas in situ in the composition. The gasketing composition is suitable for use in engines and other machines e.g. in industrial manufacturing plants.