Abstract:
Provided are a nonaqueous electrolytic solution for a secondary battery that exhibits excellent cycle characteristics even in high temperature environment, and a secondary battery including the same. The nonaqueous electrolytic solution for a secondary battery of the present invention is a nonaqueous electrolyte solution for a secondary battery which is used for a secondary battery, including at least one component (A) represented by the following chemical formula (1): in which Mn+ represents at least one selected from the group consisting of a hydrogen ion, an alkali metal ion, an alkaline earth metal ion, an aluminum ion, a transition metal ion and an onium ion, X represents a halogen atom, R1 represents a hydrocarbon group having 1 to 20 carbon atoms, or a hydrocarbon group having 1 to 20 carbon atoms and having at least any one of a halogen atom, a heteroatom or an unsaturated bond, and n represents a valence.
Abstract:
A fuel cell catalyst which has high power output characteristics and suppresses degradation of power generation performance due to starting, stopping or load variation; a manufacturing method thereof; a membrane electrode assembly for fuel cell; and a fuel cell including the same. The fuel cell catalyst includes at least catalytically active species and a carrier supporting the catalytically active species. The catalytically active species are at least one selected from the group consisting of platinum, a platinum alloy, and a core-shell catalyst in which a core of a metal different from platinum is coated with a shell containing platinum, the carrier is a carbon material, and at least one of the catalytically active species and the carrier contain(s) fluorine atoms.
Abstract:
A phosphodiester salt is added to the electrolytic solution to form a nonaqueous electrolytic solution for a secondary battery. The nonaqueous electrolytic solution has excellent storage characteristics in a temperature load environment. Deterioration of the charge-discharge characteristics of the nonaqueous electrolytic solution and increase in internal resistance of the nonaqueous electrolytic solution are suppressed during storage. A secondary battery having a positive electrode and a negative electrode makes use of this electrolytic solution.
Abstract:
A hydrogen containing material comprises a first compound including hydrogen containing material and fluoride, and a second compound including a metal which becomes highly reactive with hydrogen when the metal becomes a compound including fluorine, and a compound including fluorine. The first compound and the second compound are integrally formed into a one-piece layer on the surface of the hydrogen containing material. The metal which becomes highly reactive with hydrogen when the metal becomes a compound including fluorine is at least one metal selected from a rare earth metal, rare earth alloy, Fe, Al, Mg, Ca, Mn, Zn, Zr, Li, or alloys comprising these elements.
Abstract:
Provided are a liquid dispersion of fluoride particles having a refractive index lower than that of, for example, magnesium fluoride, the liquid dispersion being excellent in dispersibility and suitable for production of an optical film such as an antireflection film; a composition for forming an optical film; and an optical film. A liquid dispersion of fluoride particles according to the present invention contains: fluoride particles; an anionic surfactant as a dispersant for the fluoride particles; and an organic solvent, wherein the fluoride particles contain at least aluminum, an alkali metal, and an alkaline earth metal as an optional element in a composition of the fluoride particles, and the fluoride particles are dispersed in the organic solvent.
Abstract:
Provided are a nonaqueous electrolyte solution for a secondary battery, which causes less degradation in charge-discharge characteristic and less increase in internal resistance after storage in temperature load environments, and a secondary battery provided with same. Disclosed is a nonaqueous electrolyte solution for a secondary battery, which is used for a secondary battery, including a component (A) which is at least one phosphorus compound represented by any one of the general formulas (1) to (4), and a component (B) which is at least one phosphoric acid diester salt represented by the general formula (5).
Abstract:
A nonaqueous electrolytic solution for a secondary battery exhibits excellent cycle characteristics even in high-temperature environments. The solution includes at least one of boric acid esters, acid anhydrides, cyclic carbonates having an unsaturated bond, cyclic carbonates having a halogen atom, cyclic sulfonic acid esters, and amines having an acetoacetyl group. A secondary battery having a positive electrode and a negative electrode makes use of this electrolytic solution.
Abstract:
A nitrogen-containing carbon material to the present invention comprises a carbon material having a carbon skeleton formed of carbon atoms and nitrogen atoms introduced into the carbon material, wherein part of carbon atoms in the carbon skeleton are substituted with nitrogen atoms. The nitrogen-containing carbon material according to the present invention can be produced by a production method including the steps of bringing the carbon material into contact with a first treatment gas containing a fluorine-containing gas to subject a surface of the carbon material to a fluorination treatment; and bringing the carbon material after being subjected to the fluorination treatment into contact with a second treatment gas containing a nitrogen-containing gas with heating to perform a nitriding treatment.
Abstract:
Provided is a method for purifying a difluorophosphate, in which a difluorophosphate is purified to a high purity. The method includes a method for purifying a difluorophosphate, comprising bringing hydrogen fluoride into contact with a difluorophosphate containing an impurity and subsequently heating and drying the difluorophosphate, or bringing the hydrogen fluoride into contact with the difluorophosphate containing the impurity while heating and drying the difluorophosphate containing the impurity, thereby removing the impurity.
Abstract:
There is provided a method for processing an inner wall surface of a micro vacancy, capable of reliably etching and cleaning even if the hole provided to the substrate to be processed is narrow and deep. The substrate has a surface on which a processing solution is to be applied and a micro vacancy with an opening on the surface. An aspect ratio (l/r) of the micro vacancy being at least 5, or the aspect ratio being less than 5 and a ratio (V/S) of a micro vacancy volume (V) to a surface area of the opening (S) being at least 3. The substrate is arranged in a processing space. Next, the processing space is depressurized, and subsequently the processing solution is introduced into the processing space so as to process the inner wall surface of the micro vacancy.