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公开(公告)号：US10792228B2
公开(公告)日：2020-10-06
申请号：US15775040
申请日：2016-10-11
发明人： Michael Jahns , Markus Mikulla , Robert F. Peez , Adrian S. Eckert , Rainer A. Guggenberger , Simone Raynoschek , Afshin Falsafi , Bradley D. Craig , Jimmie R. Baran, Jr. , Joel D. Oxman
摘要： The invention relates to a kit of parts for preparing a glass ionomer composition for dental use, the kit of parts comprising a Powder Part P and a Liquid Part L, Powder Part P comprising: acid-reactive inorganic filler, Liquid Part L comprising: water, complexing agent, polyacid, either the Powder Part P or the Liquid Part L or the Powder Part P and the Liquid Part L comprising non-aggregated nano-sized particles based on silica or alumina, the composition obtained by combining the components of Powder Part P and Liquid Part L before hardening comprising the components in the following amounts: non-aggregated nano-sized particles: from 0.1 to 15 wt.-%, acid-reactive filler in an amount from 50 to 75 wt.-%, polyacid: 7 to 20 wt.-%, complexing agent: 0.5 to 3 wt.-%, water: 5 to 18 wt.-%, wt.-% with respect to the weight of the whole composition.
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公开(公告)号：US10004669B2
公开(公告)日：2018-06-26
申请号：US15119241
申请日：2015-02-18
发明人： Adrian S. Eckert , Michael Cub , Bettina Hailand-Newhook , Marion B. Kestel , Christoph Thalacker , Karsten Dede , Uwe H. Hoheisel , Reinhold Hecht , Henry Loll , Bernhard Hofmann
CPC分类号： A61K6/083 , A61K6/005 , A61K6/0052 , A61K6/0073 , A61K6/0088 , A61K6/0091 , C08L33/10 , C08L33/08
摘要： The invention relates to a dental composition comprising polymerizable monomer (1), initiator component(s), filler component(s) in an amount of more than about 20 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, and oxygen, bisphenol moieties. The invention also relates to the use of the dental composition as or for producing a dental filling material, crown and bridge material, inlay, onlay, veneer or dental mill blank.
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公开(公告)号：US09844493B2
公开(公告)日：2017-12-19
申请号：US15119172
申请日：2015-02-18
发明人： Adrian S. Eckert , Michael Cub , Bettina Hailand , Ines Edelmann , Christoph Thalacker , Karsten Dede , Uwe H. Hoheisel , Reinhold Hecht
CPC分类号： A61K6/0023 , A61K6/0052 , A61K6/0088 , C08L33/10 , C08L33/08
摘要： An adhesive dental composition comprising a polymerizable monomer (1), a polymerizable monomer (2) comprising an acidic moiety, initiator component(s), filler component(s) in an amount of less than about 15 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, and oxygen, bisphenol moieties. The invention also relates to the use of the adhesive dental composition as dental adhesive, sealant, cement or for bonding or cementing a material to the surface of hard dental tissue.
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公开(公告)号：US11612548B2
公开(公告)日：2023-03-28
申请号：US16762172
申请日：2018-11-05
摘要： The invention relates to a radiation-curable radiopaque dental composition comprising a resin matrix comprising cross-linkable component(s) as Component A, ethylenically unsaturated component(s) with acidic moiety as Component B, an initiator system comprising photoinitiator(s) as Component C, reducing agent(s) as Component D, Component A containing at least two (meth)acrylate moieties and a brominated aromatic moiety selected from brominated resorcinol, catechol, tyrosol, benzoic acid, or phenol moieties. The composition can be used for producing an x-ray visible dental adhesive composition, restoration primer or dental sealant.
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公开(公告)号：US11583373B2
公开(公告)日：2023-02-21
申请号：US16327111
申请日：2017-08-14
IPC分类号： B29C35/08 , C08F2/46 , C08F2/50 , C08G61/04 , A61C13/00 , B33Y70/00 , B33Y10/00 , B29C64/124 , C08K5/00 , C08K5/08 , B22C9/04 , B22C7/02 , C08K5/05 , C08F222/10 , C08K5/3437 , C08L35/02 , A61C13/20 , A61C13/08 , A61C7/14 , C08F220/28 , B33Y70/10 , C08F220/20
摘要： The invention relates to a coloured curable composition for use in an additive manufacturing process, the composition comprising a curable resin composition comprising radiation curable components, a photo initiator, a dye composition comprising a dye D1 and a dye D2, dye D1 having a light absorption maximum within a wave length range from 400 to 530 nm, dye D2 showing a light absorption maximum within a wave length range from 540 to 650 nm. The invention also relates to a 3-dim composite article obtained by processing the curable composition in an additive manufacturing process.
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公开(公告)号：US20210361389A1
公开(公告)日：2021-11-25
申请号：US17052536
申请日：2019-06-25
发明人： Benjamin C. Mac Murray , Saswata Chakraborty , John M. Riedesel , Thomas P. Klun , Chad M. Amb , Karl J.L. Geisler , Zeba Parkar , Adrian S. Eckert , Mark T. Gibson , Tianyu Wu
摘要： The present disclosure provides methods of making a hydrated orthodontic article is provided. One method includes a) providing a photopolymerizable composition; b) selectively curing the photopolymerizable composition using actinic radiation to form an article in the shape of an orthodontic article having a plurality of layers of at least one photopolymerized polymer; and c) exposing the article to water by submersion in water, thereby hydrating the article. A sheet of the at least one photopolymerized polymer has a bending modulus when hydrated of 100 MPa or greater and 2200 MPa or less. Another method includes exposing the orthodontic article to water vapor and hermetically sealing the hydrated orthodontic article in a container. Hydrated orthodontic articles are also provided, including an orthodontic article that is prepared according to one of the methods. The present disclosure further provides kits, including an orthodontic article and instructions for exposing the orthodontic article to water to hydrate the orthodontic article, as well as including a hydrated orthodontic article hermetically sealed in a container.
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7.发明申请公开(公告)号：US20190176394A1
公开(公告)日：2019-06-13
申请号：US16321534
申请日：2017-01-28
发明人： Malte Korten , Gioacchino Raia , Adrian S. Eckert , Bernhard Hofmann , Christian A. Richter , Bastian P. Kirchner , Anja Friedrich , Helmar B. Mayr , Carsten Franke , Gallus Schechner
IPC分类号： B29C64/245 , A61C13/00 , A61C13/08 , B29C64/135 , B33Y10/00 , B33Y30/00
摘要： A device for progressively building up an object from a light hardenable material. The device has a perforated build platform for the object. The build platform forms a build surface that faces a light source. The build platform and the light source are positionable relative to each other by computer control. The device is further configured for supplying the light hardenable material through the perforation of the build platform for building up the object. The invention enables the making of colored objects by stereolithography.
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公开(公告)号：US20170056298A1
公开(公告)日：2017-03-02
申请号：US15119241
申请日：2015-02-18
发明人： Adrian S. Eckert , Michael Cub , Bettina Hailand , Marion B. Kestel , Christoph Thalacker , Karsten Dede , Uwe H. Hoheisel , Reinhold Hecht , Henry Loll , Bernhard Hofmann
CPC分类号： A61K6/083 , A61K6/005 , A61K6/0052 , A61K6/0073 , A61K6/0088 , A61K6/0091 , C08L33/10 , C08L33/08
摘要： The invention relates to a dental composition comprising polymerizable monomer (1), initiator component(s), filler component(s) in an amount of more than about 20 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, and oxygen, bisphenol moieties. The invention also relates to the use of the dental composition as or for producing a dental filling material, crown and bridge material, inlay, onlay, veneer or dental mill blank.
摘要翻译： 本发明涉及一种牙科用组合物，其包含可聚合单体（1），引发剂组分，多于约20重量％，重量％的填料组分，相对于 组合物，可聚合单体（1）的特征如下：具有正好两个（甲基）丙烯酸酯反应性部分，在（甲基）丙烯酸酯反应性部分之间具有不对称主链作为连接，两个（甲基）丙烯酸酯反应性部分连接到 不对称单体主链作为烷基酯，不对称主链包含一个酚类芳族部分，不含酸性部分的可聚合单体（1），其它原子比碳，氢和氧，双酚部分。 本发明还涉及将牙科用组合物用于或用于制造牙科填充材料，冠和桥材料，镶嵌，镶嵌，单板或牙磨机坯料的用途。
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公开(公告)号：US20240150551A1
公开(公告)日：2024-05-09
申请号：US18550489
申请日：2022-03-31
发明人： Tom Gaide , Jens Eichler , Christian Weinmann , Friedrich M. Wolff , Stefan V. Friedrich , Karoline Anne Ostrowski , Adrian S. Eckert , Michael H. Stalder , Philipp Jurgen Semmler , Badri Veeraraghavan , Klaus Hintzer , Jennifer J. Sokol
IPC分类号： C08K9/04 , B29C64/124 , C08K9/02 , H05K9/00 , B29K509/08
CPC分类号： C08K9/04 , B29C64/124 , C08K9/02 , H05K9/0083 , B29K2509/08 , B29K2995/0011 , B29K2995/0063 , C08K2201/003
摘要： The present disclosure provides compositions, articles, and methods related to altering electromagnetic radiation. An actinic radiation curable precursor composition of a three-dimensional article includes a) a resin comprising an actinic radiation curable component, wherein the resin has a viscosity no greater than 500 cP; b) hollow glass microspheres having a density no greater than 2 g/mL and an average diameter no greater than 200 micrometers; and c) a photoinitiator. At least part of the surface of the hollow glass microspheres comprises a surface coating or modification. An article includes a photo(co)polymerization reaction product of the composition. A method of manufacturing a three-dimensional article includes the steps of a) providing an actinic radiation curable precursor composition; and b) selectively exposing a portion of the composition to a source of actinic radiation to at least partially cure the exposed portion of the composition, thereby forming a cured layer. Steps a) and b) are repeated so as to form a three-dimensional article. A three-dimensional article is provided, obtained according to the method. Methods of interfering with electromagnetic radiation originating from an electromagnetic radiation producing device are provided, including integrating an article into the electronic device or placing an article in the vicinity of the electromagnetic radiation producing device.
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10.发明授权公开(公告)号：US11345087B2
公开(公告)日：2022-05-31
申请号：US16321534
申请日：2017-07-28
发明人： Malte Korten , Gioacchino Raia , Adrian S. Eckert , Bernhard Hofmann , Christian A. Richter , Bastian P. Kirchner , Anja Friedrich , Helmar B. Mayr , Carsten Franke , Gallus Schechner
IPC分类号： B29C64/245 , A61C13/00 , B33Y10/00 , B33Y30/00 , B29C64/135 , B29C64/129 , A61C13/087 , B29C64/20 , A61C13/08 , B29K105/00 , B29K509/00 , B29L31/00
摘要： A device for progressively building up an object from a light hardenable material. The device has a perforated build platform for the object. The build platform forms a build surface that faces a light source. The build platform and the light source are positionable relative to each other by computer control. The device is further configured for supplying the light hardenable material through the perforation of the build platform for building up the object. The invention enables the making of colored objects by stereolithography.
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