摘要:
A copolymer including units derived from fluoro monomers of formula (I): CX1X2═CX3X4 (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, the H and/or F atoms of the fluoro monomers being partially replaced with photoactive groups of formula —Y—Ar—R in the copolymer; Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, preferably a phenyl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. The fluoro monomers of formula (I) of the copolymer include vinylidene fluoride and trifluoroethylene. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from the copolymer.
摘要:
A copolymer including fluorinated units of formula (I): —CX1X2—CX3X4— (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and fluorinated units of formula (II): —CX5X6—CX7Z— (II) in which each of the X5, X6 and X7 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and in which Z is a photoactive group of formula —Y—Ar—R, Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from this copolymer.
摘要:
The invention relates to a copolymer comprising units derived from monomers of vinylidene fluoride and/or trifluoroethylene, as well as fluorinated monomers X comprising a double bond and a leaving group selected from among chlorine, bromine and iodine atoms, the leaving groups being partially replaced by azide groups in the copolymer.
摘要:
The invention relates to a process that enables the creation of nanometric structures by self-assembly of block copolymers, at least one of the blocks of which results from the polymerization of monomers comprising at least one cyclic entity corresponding to the formula I. where X═Si(R1,R2); Ge(R1,R2) Z═Si(R3,R4); Ge(R3,R4); O; S; C(R3,R4) Y═O; S; C(R5,R6) T=O; S; C(R7,R8) R1, R2, R3, R4, R5, R6, R7, R8 are selected from hydrogen, linear, branched or cyclic alkyl groups, with or without heteroatoms, and aromatic groups with or without heteroatoms.
摘要:
A copolymer including fluorinated units of formula (I): —CX1X2—CX3X4— (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and units of formula (III): —CXAXB—CXCZ— (III) in which each of the XA, XB and XC is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and Z being a polarizable group of formula —Y—Ar—R; Y representing an O atom or an S atom or an NH group, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms; and the copolymer having a heat of fusion of greater than or equal to 5 J/g. Also a process, a composition, an ink and a film.
摘要:
The invention relates to a process that enables the creation of nanometric structures by self-assembly of block copolymers, at least one of the blocks of which is crystallizable or has at least one liquid crystal phase.
摘要:
The invention relates to stable compositions of carbon nanotubes and of electrolytic polymers, these electrolytic polymers being characterized by the presence of phosphonyl imide or sulfonyl imide functions or alternatively phosphoric acid functions. The invention also relates to the manufacture of transparent electrodes comprising these compositions of carbon nanotubes and of electrolytic polymers.
摘要:
Disclosed are ion-sensitive polymers and methods for their use for monitoring biological phenomena associated with ion fluxes, as well as organic electrochemical transistors including such polymers.