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1.发明申请Catalyst systems for converting alkanes to alkenes and to their corresponding oxygenated products 审中-公开将烷烃转化为烯烃及其相应的氧化产物的催化剂体系公开(公告)号：US20050131255A1
公开(公告)日：2005-06-16
申请号：US10987367
申请日：2004-11-12
申请人： Abraham Benderly , Nitin Chadda , Anne Gaffney , Scott Han , Dominique Le , Mark Silvano
发明人： Abraham Benderly , Nitin Chadda , Anne Gaffney , Scott Han , Dominique Le , Mark Silvano
IPC分类号： B01J23/887 , B01J23/00 , B01J23/38 , B01J23/54 , B01J23/62 , B01J23/648 , B01J23/652 , B01J23/76 , B01J27/057 , B01J27/14 , B01J35/00 , B01J35/04 , B01J37/00 , B01J37/02 , B01J37/08 , C07B61/00 , C07C5/327 , C07C5/333 , C07C5/48 , C07C11/06 , C07C51/16 , C07C51/215 , C07C53/122 , C07C57/05 , C07C67/39
CPC分类号： B01J35/0006 , B01J23/002 , B01J23/54 , B01J23/62 , B01J23/6484 , B01J23/6525 , B01J27/0576 , B01J35/04 , B01J37/0036 , B01J37/0215 , B01J2523/00 , C07C5/3335 , C07C5/3337 , C07C51/215 , C07C67/39 , C07C2521/04 , C07C2523/62 , C07C2523/648 , C07C11/02 , C07C57/04 , B01J2523/31 , B01J2523/56 , B01J2523/828 , B01J2523/55 , B01J2523/64 , B01J2523/68 , B01J2523/824 , B01J2523/33 , C07C69/54
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared directly from corresponding alkanes utilizing using a mixed bed catalyst at flame temperatures in a short contact time reactor.
摘要翻译： 烯烃，不饱和饱和羧酸，饱和羧酸及其较高的类似物，可以在短时间接触时间反应器中，在火焰温度下使用混合床催化剂直接从相应的烷烃制备。
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2.发明申请Process for the selective (AMM)oxidation of lower molecular weight alkanes and alkenes 有权低分子量烷烃和烯烃的选择性（AMM）氧化方法公开(公告)号：US20050137415A1
公开(公告)日：2005-06-23
申请号：US10993729
申请日：2004-11-19
申请人： Leonard Bogan , Fernando Cavalcanti , Nitin Chadda , Sanjay Chaturvedi , Anne Gaffney , Scott Han , Peter Klugherz , Daniel Martenak , Mark Silvano , Elsie Vickery , Donald Zolotorofe
发明人： Leonard Bogan , Fernando Cavalcanti , Nitin Chadda , Sanjay Chaturvedi , Anne Gaffney , Scott Han , Peter Klugherz , Daniel Martenak , Mark Silvano , Elsie Vickery , Donald Zolotorofe
IPC分类号： B01J23/652 , C07B61/00 , C07C51/16 , C07C51/215 , C07C51/25 , C07C57/05 , C07C57/07 , C07C67/39 , C07C67/48 , C07C253/24 , C07C253/26 , C07C255/08
CPC分类号： C07C253/26 , C07C51/215 , C07C51/252 , C07C253/24 , Y02P20/52 , Y02P20/582 , C07C57/04 , C07C255/08
摘要： An improved process for the production of unsaturated carboxylic acids and unsaturated nitrites from their corresponding C3 to C5 alkanes, or mixtures of C3 to C5 alkanes and alkenes, that involves a multi-stage reaction system which employs both separation of the oxidation product from one or more intermediate effluent streams, as well as feeding additional oxygen to reaction zones subsequent to the first reaction zone.
摘要翻译： 一种用于从其相应的C 3至C 5烷烃生产不饱和羧酸和不饱和亚硝酸盐的改进方法，或其中C 3〜3的混合物与 其包括多阶段反应体系，其使用两个分离来自一个或多个中间体流出物流的氧化产物，以及在第一个 反应区。
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公开(公告)号：US20050239643A1
公开(公告)日：2005-10-27
申请号：US11112225
申请日：2005-04-22
申请人： Abraham Benderly , Anne Gaffney , Scott Han , Stephen Maroldo
发明人： Abraham Benderly , Anne Gaffney , Scott Han , Stephen Maroldo
IPC分类号： B01J23/00 , B01J23/20 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/652 , B01J23/887 , B01J27/057 , B01J35/04 , B01J37/02 , B01J37/34 , C07B61/00 , C07C51/215 , C07C51/25 , C07C57/055
CPC分类号： B01J23/002 , B01J23/20 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/6525 , B01J23/8877 , B01J27/0576 , B01J35/04 , B01J37/0238 , B01J37/347 , B01J2523/00 , C07C51/215 , C07C51/252 , B01J2523/55 , B01J2523/57 , B01J2523/64 , B01J2523/68 , B01J2523/56 , B01J2523/53 , B01J2523/69 , B01J2523/33 , B01J2523/821 , B01J2523/31 , B01J2523/47 , B01J2523/824 , B01J2523/72 , B01J2523/845 , C07C57/04
摘要： Structured catalysts useful for oxidizing alkanes, alkenes and combinations of alkanes and alkenes are described. The structure catalysts comprise one or more mixed metal oxide catalysts having a three dimensional structure that is self-supporting and that facilitates movement of gas phase reactants and products and one or more mixed metal oxide catalysts deposited on a three dimensional form of continuous unitary structures having openings that facilitates movement of gas phase reactants and products.
摘要翻译： 描述了可用于氧化烷烃，烯烃以及烷烃和烯烃组合的结构化催化剂。 结构催化剂包括一种或多种具有自支撑的三维结构的混合金属氧化物催化剂，并且促进气相反应物和产物的移动，以及沉积在三维形式的连续单一结构上的一种或多种混合金属氧化物催化剂，其具有 有助于气相反应物和产物运动的开口。
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公开(公告)号：US20090054678A1
公开(公告)日：2009-02-26
申请号：US12229118
申请日：2008-08-20
申请人： Nitin Chadda , Scott Han , Andrew Michael Lemonds
发明人： Nitin Chadda , Scott Han , Andrew Michael Lemonds
IPC分类号： C07C253/24 , C07C51/21
CPC分类号： C07C51/215 , C07C51/47 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08
摘要： The present invention relates to an improved alkane (amm)oxidation process in which sulfur-bearing impurities present in the alkane feedstock are removed upstream from the (amm)oxidation reaction.
摘要翻译： 本发明涉及一种改进的烷烃（amm）氧化方法，其中存在于烷烃原料中的含硫杂质从（amm）氧化反应的上游除去。
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公开(公告)号：US07880027B2
公开(公告)日：2011-02-01
申请号：US12229118
申请日：2008-08-20
申请人： Nitin Chadda , Scott Han , Andrew Michael Lemonds
发明人： Nitin Chadda , Scott Han , Andrew Michael Lemonds
IPC分类号： C07C253/24 , C07C51/21
CPC分类号： C07C51/215 , C07C51/47 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08
摘要： The present invention relates to an improved alkane (amm)oxidation process in which sulfur-bearing impurities present in the alkane feedstock are removed upstream from the (amm)oxidation reaction.
摘要翻译： 本发明涉及一种改进的烷烃（amm）氧化方法，其中存在于烷烃原料中的含硫杂质从（amm）氧化反应的上游除去。
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6.发明授权Process for the selective (amm)oxidation of lower molecular weight alkanes and alkenes 有权低分子量烷烃和烯烃的选择性（氨）氧化方法公开(公告)号：US07553986B2
公开(公告)日：2009-06-30
申请号：US10993729
申请日：2004-11-19
申请人： Leonard Edward Bogan, Jr. , Fernando A. P. Cavalcanti , Nitin Chadda , Sanjay Chaturvedi , Anne Mae Gaffney , Scott Han , Peter D. Klugherz , Daniel Martenak , Mark Anthony Silvano , Elsie Mae Vickery , Donald L. Zolotorofe
发明人： Leonard Edward Bogan, Jr. , Fernando A. P. Cavalcanti , Nitin Chadda , Sanjay Chaturvedi , Anne Mae Gaffney , Scott Han , Peter D. Klugherz , Daniel Martenak , Mark Anthony Silvano , Elsie Mae Vickery , Donald L. Zolotorofe
IPC分类号： C07C253/24
CPC分类号： C07C253/26 , C07C51/215 , C07C51/252 , C07C253/24 , Y02P20/52 , Y02P20/582 , C07C57/04 , C07C255/08
摘要： An improved process for the production of unsaturated carboxylic acids and unsaturated nitrites from their corresponding C3 to C5 alkanes, or mixtures of C3 to C5 alkanes and alkenes, that involves a multi-stage reaction system which employs both separation of the oxidation product from one or more intermediate effluent streams, as well as feeding additional oxygen to reaction zones subsequent to the first reaction zone.
摘要翻译： 一种用于从其相应的C3至C5烷烃或C3至C5烷烃和烯烃的混合物生产不饱和羧酸和不饱和亚硝酸盐的改进方法，涉及多阶段反应体系，其采用将氧化产物从一种或多种 更多的中间流出物流，以及在第一反应区之后向反应区域供给额外的氧气。
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7.发明授权公开(公告)号：US07906699B2
公开(公告)日：2011-03-15
申请号：US12221591
申请日：2008-08-05
IPC分类号： C07C5/02
CPC分类号： C07C67/343 , C07C5/42 , C07C5/48 , C07C45/50 , C07C45/75 , C07C67/38 , C07C2523/64 , Y02P20/142 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24 , C07C47/02
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过在至少500℃的温度下使乙烷和氧源接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种制备丙酸烷基酯的方法，其步骤为：（a）在至少500℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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8.发明申请Catalytic process for producing ethylene and carbon monoxide mixtures from ethane 审中-公开从乙烷生产乙烯和一氧化碳混合物的催化方法公开(公告)号：US20090082530A1
公开(公告)日：2009-03-26
申请号：US12283955
申请日：2008-09-17
申请人： Rajiv Manohar Banavali , Abraham Benderly , Scott Han , Daniel Joseph Martenak , Jose Antonio Trejo
发明人： Rajiv Manohar Banavali , Abraham Benderly , Scott Han , Daniel Joseph Martenak , Jose Antonio Trejo
CPC分类号： C07C5/42 , B01J23/78 , B01J37/0201 , B01J37/03 , C07C45/75 , C07C67/343 , C07C67/38 , C07C2523/745 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising iron oxide supported on an inorganic material to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 600° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过使乙烷和氧源与包含负载在无机材料上的氧化铁的催化剂接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种通过以下步骤生产丙酸烷基酯的方法：（a）在至少600℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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9.发明申请Supported catalyst for conversion of propane to propene and its use in a process for that conversion 审中-公开用于将丙烷转化成丙烯的载体催化剂及其在该转化过程中的用途公开(公告)号：US20090182186A1
公开(公告)日：2009-07-16
申请号：US12319765
申请日：2009-01-12
申请人： Abraham Benderly , Wolfgang Ruettinger , Scott Han
发明人： Abraham Benderly , Wolfgang Ruettinger , Scott Han
IPC分类号： C07C5/32
CPC分类号： B01J23/685 , B01J21/08 , B01J23/26 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J35/1066 , B01J37/0201 , C07C5/3332 , C07C5/42 , C07C2521/06 , C07C2521/08 , C07C2523/06 , C07C2523/10 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/50 , Y02P20/52 , C07C11/06
摘要： A process for the conversion of propane to propene is disclosed wherein a silica chromium catalyst composition is contacted with a propane feed stream and a carbon dioxide. The silica chromium catalyst composition is further disclosed wherein the composition, optionally, includes a promoter component.
摘要翻译： 公开了一种将丙烷转化为丙烯的方法，其中将二氧化硅铬催化剂组合物与丙烷进料流和二氧化碳接触。 进一步公开了二氧化硅铬催化剂组合物，其中组合物任选地包含促进剂组分。
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10.发明申请公开(公告)号：US20090048411A1
公开(公告)日：2009-02-19
申请号：US12221591
申请日：2008-08-05
CPC分类号： C07C67/343 , C07C5/42 , C07C5/48 , C07C45/50 , C07C45/75 , C07C67/38 , C07C2523/64 , Y02P20/142 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24 , C07C47/02
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过在至少500℃的温度下使乙烷和氧源接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种制备丙酸烷基酯的方法，其步骤为：（a）在至少500℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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