DENSELY FUNCTIONALIZED POLYMERS DERIVED FROM BAYLIS-HILLMAN ADDUCTS
    6.
    发明申请
    DENSELY FUNCTIONALIZED POLYMERS DERIVED FROM BAYLIS-HILLMAN ADDUCTS 有权
    来自BAYLIS-HILLMAN ADDUCTS的DENSELY功能化聚合物

    公开(公告)号:US20160002389A1

    公开(公告)日:2016-01-07

    申请号:US14776006

    申请日:2014-03-14

    申请人: Abraham JOY Chao PENG

    发明人: Abraham Joy Chao Peng

    摘要: A method of preparing a polymer is provided comprising preparing a Baylis-Hillman adduct by reacting an activated alkene with a carbon electrophile; and polymerizing the Baylis-Hillman adduct. The Baylis-Hillman reaction provides an efficient platform for the synthesis of densely functionalized monomers, from which polymers with multiple functional groups can be readily synthesized. It has been discovered that that Baylis-Hillman adducts are versatile monomers for both controlled radical and step-growth polymerizations.

    摘要翻译: 提供一种制备聚合物的方法,包括通过使活化烯与碳亲电子试剂反应制备Baylis-Hillman加合物; 并使Baylis-Hillman加合物聚合。 Baylis-Hillman反应为致密官能化单体的合成提供了有效的平台,可以容易地合成具有多个官能团的聚合物。 已经发现,Baylis-Hillman加合物是用于受控自由基和逐步增长聚合的通用单体。