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    Laminate
    3.
    发明授权
    Laminate 失效
    层压板

    公开(公告)号：US5445883A

    公开(公告)日：1995-08-29

    申请号：US272629

    申请日：1994-07-11

    申请人： Seizo Kobayashi ,  Takashi Mizoe ,  Yoshimu Iwanami ,  Shigeki Yokoyama ,  Keizi Jimbo

    发明人： Seizo Kobayashi ,  Takashi Mizoe ,  Yoshimu Iwanami ,  Shigeki Yokoyama ,  Keizi Jimbo

    IPC分类号： B32B27/32 ,  C09J7/02

    CPC分类号： B32B27/32 ,  Y10S428/91 ,  Y10T428/2878 ,  Y10T428/31913 ,  Y10T428/31928

    摘要： An anisotropy-free laminate having much higher strength and stiffness as compared with conventional articles is here disclosed which can be prepared by laminating an orientated ultra-high-molecular-weight polyethylene onto an adhesive layer obtained by modifying an olefin polymer with an unsaturated carboxylic acid and/or its derivative at a temperature lower than the melting point of the orientated ultra-high-molecular-weight polyethylene. The anisotropy-free material having high strength and high stiffness of the present invention can be substituted for various materials such as metals, lumber and FRP, and is also lightweight and excellent in water resistance.

    摘要翻译： 这里公开了与常规制品相比具有高得多的强度和刚度的无向异性层压材料，其可以通过将取向的超高分子量聚乙烯层压到通过用不饱和羧酸改性烯烃聚合物获得的粘合剂层上来制备 和/或其衍生物在低于取向的超高分子量聚乙烯的熔点的温度下进行。 本发明的具有高强度和高硬度的各向异性材料可以代替金属，木材和FRP等各种材料，并且重量轻且耐水性优异。

    Thermoplastic elastomer compositions
    6.
    发明授权
    Thermoplastic elastomer compositions 失效
    热塑性弹性体组合物

    公开(公告)号：US4822855A

    公开(公告)日：1989-04-18

    申请号：US81464

    申请日：1987-08-04

    申请人： Seizo Kobayashi ,  Katumi Usui ,  Takashi Mizoe ,  Noboru Yamaoka ,  Kazuo Matsuura

    发明人： Seizo Kobayashi ,  Katumi Usui ,  Takashi Mizoe ,  Noboru Yamaoka ,  Kazuo Matsuura

    IPC分类号： C08L23/00 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L23/16 ,  C08L53/00 ,  C08L23/28 ,  C08L23/18

    CPC分类号： C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L2205/03 ,  C08L23/0815 ,  C08L23/142 ,  C08L2312/00 ,  C08L53/00

    摘要： A thermoplastic elastomer composition prepared by partially crosslinking a composition comprising the following components (A), (B) and (C):(A) 30-70 parts by weight of an ethylene/.alpha.-olefin copolymer prepared by copolymerizing ethylene and an .alpha.-olefin having 3 to 12 carbon atoms in the presence of a catalyst comprising a solid component and an organoaluminum compound which solid component contains at least magnesium and titanium, said ethylene/.alpha.-olefin copolymer having the following properties (I) to (IV):______________________________________ (I) Melt index 0.01-100 g/10 min (II) Density 0.860-0.910 g/cm.sup.3 (III) Maximum peak not lower than 100.degree. C. temperature as measured according to a differential scanning calorimetry (DSC) (IV) Insolubles in boiling not less than 10 wt. % n-hexane ______________________________________ (B) 70-30 parts by weight of a propylene polymer; and(C) 70-200 parts by weight, based on 100 parts by weight of the components (A) and (B), of an ethylene/.alpha.-olefin copolymer rubber.

    摘要翻译： 通过部分交联包含以下组分（A），（B）和（C）的组合物制备的热塑性弹性体组合物：（A）30-70重量份通过乙烯共聚合制备的乙烯/α-烯烃共聚物 所述乙烯/α-烯烃共聚物具有以下特性（I）至（IV），所述催化剂包含固体组分和有机铝化合物，所述有机铝化合物至少含有镁和钛， ： - （I）熔体指数0.01-100g / 10min - （II）密度0.860-0.910g / cm3 - （III）最高峰不低于100℃ - 测量温度 - 根据差示扫描 - 量热法（DSC） - （Ⅳ）不溶物不溶于10重量％ ％ - 正己烷 - （B）70-30重量份丙烯聚合物; 和（C）基于100重量份的组分（A）和（B））为70-200重量份的乙烯/α-烯烃共聚物橡胶。

    Thermoplastic elastomer compositions
    7.
    发明授权
    Thermoplastic elastomer compositions 失效
    热塑性弹性体组合物

    公开(公告)号：US4775722A

    公开(公告)日：1988-10-04

    申请号：US91831

    申请日：1987-09-01

    申请人： Seizo Kobayashi ,  Katumi Usui ,  Takashi Mizoe ,  Noboru Yamaoka ,  Kazuo Matsuura

    发明人： Seizo Kobayashi ,  Katumi Usui ,  Takashi Mizoe ,  Noboru Yamaoka ,  Kazuo Matsuura

    IPC分类号： C08K5/14 ,  C08L23/00 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L23/16 ,  C08L53/00 ,  C08L23/26 ,  C08L23/04

    CPC分类号： C08L23/0815 ,  C08L23/0869 ,  C08L23/10 ,  C08L23/12 ,  C08L23/142 ,  C08L23/16 ,  C08L2205/035 ,  C08L2207/04 ,  C08L2312/00 ,  C08L53/00

    摘要： A thermoplastic elastomer composition prepared by partially crosslinking a composition comprising the following components (A), (B), (C) and (D):(A) 10-40% by weight of an ethylene/.alpha.-olefin copolymer prepared by copolymerizing ethylene and an .alpha.-olefin having 3 to 12 carbon atoms in the presence of a catalyst comprising a solid component and an organoaluminum compound which solid component contains at least magnesium and titanium, said ethylene/.alpha.-olefin copolymer having the following properties (I) to (IV):(I) Melt index: 0.01-50 g/10 min(II) Density: 0.860-0.910 g/cm.sup.3(III) Maximum peak temperature as measured according to a differential scanning calorimetry (DSC): not lower than 100.degree. C.(IV) Insolubles in boiling n-hexane: not less than 10 wt. %(B) 15-35% by weight of a propylene polymer;(C) 10-40% by weight of an ethylene/.alpha.-olefin copolymer rubber; and(D) 10-40% by weight of an ethylene/unsaturated monocarboxylic acid ester copolymer in which the carboxylate unit content is 2-10 mol %.

    摘要翻译： 通过将包含以下组分（A），（B），（C）和（D））的组合物部分交联制备的热塑性弹性体组合物：（A）10-40重量％的通过共聚制备的乙烯/α-烯烃共聚物 乙烯和具有3至12个碳原子的α-烯烃，在包含固体组分和固体组分至少含有镁和钛的有机铝化合物的催化剂存在下，所述乙烯/α-烯烃共聚物具有以下性质（I） 至（IV）：（I）熔融指数：0.01-50g / 10分钟（II）密度：0.860-0.910g / cm3（III）根据差示扫描量热法（DSC）测量的最大峰值温度：不低于 100℃（Ⅳ）沸腾正己烷不溶物不少于10wt。 ％（B）15-35重量％的丙烯聚合物; （C）10-40重量％的乙烯/α-烯烃共聚物橡胶; 和（D）10-40重量％的羧酸酯单元含量为2-10摩尔％的乙烯/不饱和一元羧酸酯共聚物。

    Method of manufacturing foamed thermoplastic resin profiles
    8.
    发明授权
    Method of manufacturing foamed thermoplastic resin profiles 失效
    发泡热塑性树脂型材的制造方法

    公开(公告)号：US4071591A

    公开(公告)日：1978-01-31

    申请号：US603766

    申请日：1975-08-11

    申请人： Seizo Kobayashi ,  Toshiharu Hirayama ,  Takeshi Kamiya ,  Seiju Kezuka ,  Hidesuke Takeuchi

    发明人： Seizo Kobayashi ,  Toshiharu Hirayama ,  Takeshi Kamiya ,  Seiju Kezuka ,  Hidesuke Takeuchi

    IPC分类号： B29C44/50 ,  B29D27/00

    CPC分类号： B29C47/0042 ,  B29C44/50 ,  B29K2023/00 ,  B29K2025/00 ,  B29K2105/12 ,  B29K2105/24 ,  B29K2309/08 ,  Y10S264/14 ,  Y10S264/18

    摘要： A method for producing foamed thermoplastic resin profiles with an outer skin layer of increased hardness and an inner foam structure which may be used in place of wooden articles. The outer skin has a smooth surface and a good appearance, and the inner portion enclosed by the skin has a uniform foam structure. Also, with this method an improved foaming efficiency can be obtained. The method comprises a step of melting and kneading a mixture consisting of a thermoplastic resin and a foaming agent without causing the gasification of the foaming agent, a step of heating the melted and kneaded mixture obtained in the previous step to cause the gasification of the foaming agent without agitating the mixture and under a pressure sufficient to supress the substantial foaming of the mixture, thereby forming an expandable melted resin mixture containing microbubbles which are prevented from gathering and uniting, and a third step of causing the melted resin obtained in the previous step to expand while cooling the resin by leading the resin to a foaming die under low temperature and low pressure conditions.

    摘要翻译： 一种生产发泡热塑性树脂轮廓的方法，其具有增加硬度的外层和可用于代替木制品的内泡沫结构。 外皮具有光滑的表面和良好的外观，并且由皮肤包围的内部部分具有均匀的泡沫结构。 此外，通过该方法，可以获得改善的发泡效率。 该方法包括将由热塑性树脂和发泡剂组成的混合物熔融和捏合而不引起发泡剂气化的步骤，加热在前一步骤中获得的熔融和捏合的混合物以使发泡气化 在不搅拌混合物的条件下，在足以抑制混合物的大量发泡的压力下，形成包含防止聚集和结合的微泡的可膨胀熔融树脂混合物，以及第三步骤，使上一步骤中获得的熔融树脂 通过在低温低压条件下将树脂引入发泡模具来冷却树脂。