摘要:
A method for producing foamed thermoplastic resin profiles with an outer skin layer of increased hardness and an inner foam structure which may be used in place of wooden articles. The outer skin has a smooth surface and a good appearance, and the inner portion enclosed by the skin has a uniform foam structure. Also, with this method an improved foaming efficiency can be obtained. The method comprises a step of melting and kneading a mixture consisting of a thermoplastic resin and a foaming agent without causing the gasification of the foaming agent, a step of heating the melted and kneaded mixture obtained in the previous step to cause the gasification of the foaming agent without agitating the mixture and under a pressure sufficient to supress the substantial foaming of the mixture, thereby forming an expandable melted resin mixture containing microbubbles which are prevented from gathering and uniting, and a third step of causing the melted resin obtained in the previous step to expand while cooling the resin by leading the resin to a foaming die under low temperature and low pressure conditions.
摘要:
A process for producing polyethylene materials is disclosed in which particulate polyethylene is drawn at lower temperatures than its melting point, the polymer having an intrinsic viscosity of 5-50 dl/g at 135.degree. C. in decalin and resulting from the polymerization of ethylene at temperatures below the above melting point and with use of a selected catalyst. The polyethylene materials excel in mechanical strength and elastic modulus.
摘要:
A process for producing a polyethylene material for use in products requiring high mechanical strength and high elastic modulus is disclosed. The process involves the use of a specific class of particulate polyethylenes having an intrinsic viscosity of 5-50 dl/g in decalin at 135.degree. C. and the steps of compression molding, solvent immersing, solid-phase extruding or rolling and finally drawing the material in that order.
摘要:
The present invention provides a prepreg obtained by stretching a material including, as a main component, an ultra-high-molecular-weight polyethylene having an intrinsic viscosity of 5-50 dl/g as measured at 135.degree. C. in decalin, to a total draw ratio of at least 20, subjecting the resulting stretched polyethylene material to a splitting treatment, and impregnating the resulting material with a thermosetting resin, and a process for producing said prepreg. The split stretched polyethylene material has improved adhesion to the impregnant resin and can be used as a good base material for prepreg.
摘要:
An anisotropy-free laminate having much higher strength and stiffness as compared with conventional articles is here disclosed which can be prepared by laminating an orientated ultra-high-molecular-weight polyethylene onto an adhesive layer obtained by modifying an olefin polymer with an unsaturated carboxylic acid and/or its derivative at a temperature lower than the melting point of the orientated ultra-high-molecular-weight polyethylene. The anisotropy-free material having high strength and high stiffness of the present invention can be substituted for various materials such as metals, lumber and FRP, and is also lightweight and excellent in water resistance.
摘要:
The present invention provides a prepreg obtained by stretching a material including, as a main component, an ultra-high-molecular-weight polyethylene having an intrinsic viscosity of 5-50 dl/g as measured at 135.degree. C. in decalin, to a total draw ratio of at least 20, subjecting the resulting stretched polyethylene material to a splitting treatment, and impregnating the resulting material with a thermosetting resin. The split stretched polyethylene material has improved adhesion to the impregnant resin and can be used as a good base material for prepreg.
摘要:
The present invention discloses a colored stretched polyethylene material which comprises an ultra-high-molecular-weight polyethylene having an intrinsic viscosity of 5-50 dl/g in decalin at 135.degree. C. and 0.001-50 parts by weight, per 100 parts by weight of the polyethylene, of a dye and/or a pigment and which has been stretched at a temperature lower than the melting point of the polyethylene, and a process for producing said polyethylene material. This colored stretched polyethylene material has a tensile modulus of 120 Gpa or more and a tensile strength of 1.5 GPa or more.
摘要:
A high-strength and high-modulus polyolefin material can be continuously produced from a polyolefin in a powder form by feeding the polyolefin powder between a combination of endless belts disposed in an up-and-down opposing relation, compression-molding the polyolefin powder at a temperature lower than the melting point of the polyolefin powder by means of a pressing device while holding the polyolefin powder between the endless belts and conveying the same, and then rolling and stretching the resultant compression-molded polyolefin. The pressing device is constructed of pressing platens and corresponding sets of rollers, which are all accommodated within the respective endless belts. The rollers in each set are connected together, and the sets of rollers are arranged movably in an endless fashion between the respective platens and the endless belts associated therewith.
摘要:
A method for the preparation of masterbatch compositions for use in thermoplastic resin modification by blending polybutene with an ethylene..alpha.-olefin copolymer which is obtained by copolymerizing ethylene and .alpha.-olefin in the presence of specific catalysts and has specific characteristics such as a density of exceeding 0.910 g/cm.sup.3 and 0.940 g/cm.sup.3 or less, and successively by kneading and extruding the blend in the temperature range from the maximum peak temperature (Tm) to (Tm-45.degree. C.) in accordance with differential scanning calorimetry (DSC).
摘要翻译:一种通过将聚丁烯与乙烯混合来制备用于热塑性树脂改性的母料组合物的方法。 α-烯烃共聚物,其通过在特定催化剂存在下共聚合乙烯和α-烯烃而获得,具有特定的特性如密度超过0.910g / cm 3和0.940g / cm 3以下,然后通过捏合和挤出共混物 在根据差示扫描量热法(DSC)的最大峰值温度(Tm)至(Tm-45℃)的温度范围内。
摘要:
A thermoplastic elastomer composition prepared by crosslinking a composition comprising the following components (A), (B) and (C) by using a phenolic curing agent:(A) 30-70 parts by weight of an ethylene/.alpha.-olefin copolymer prepared by copolymerizing ethylene and an .alpha.-olefin having 3 to 12 carbon atoms in the presence of a catalyst comprising a solid component and an organoaluminum compound which solid component contains at least magnesium and titanium, said ethylene/.alpha.-olefin copolymer having the following properties (I) to (IV):______________________________________ (I) Melt index 0.01-100 g/10 min (II) Density 0.860-0.910 g/cm.sup.3 (III) Maximum peak temperature as measured according to a not lower than 100.degree. C. differential scanning calorimetry (DSC) (IV) Insolubles in boiling n-hexane not less than 10 wt. % ______________________________________ (B) 70-30 parts by weight of a propylene polymer; and(C) 70-150 parts by weight, based on 100 parts by weight of the components (A) and (B), of an ethylene/.alpha.-olefin/non-conjugated diene copolymer rubber.