Elastomers with improved metal adhesion
    1.
    发明授权
    Elastomers with improved metal adhesion 失效
    具有改善金属附着力的弹性体

    公开(公告)号:US4154911A

    公开(公告)日:1979-05-15

    申请号:US914400

    申请日:1978-06-12

    IPC分类号: C08J5/10 C08K5/098 C08K5/56

    摘要: Vulcanizable elastomeric compositions are described which comprise an elastomer and from about 0.001 to about 0.1 lb mole of metal per 100 lbs of elastomer, the metal content comprising a mixture of copper and zinc, said metals being present as(a) an organic carboxylic acid salt consisting of copper and zinc combined with one or more carboxylic acids,(b) a combination of two or more copper and zinc salts of organic carboxylic acids, or(c) a combination of a metal salt of an organic carboxylic acid and a mixed organic acid salt complex.Such vulcanizable elastomeric compositions exhibit improved adhesion to brass plated metal surfaces and are, therefore, useful in preparing rubber laminates containing metal reinforcing elements.

    摘要翻译: 描述了可硫化的弹性体组合物,其包含弹性体和每100磅弹性体约0.001至约0.1lb摩尔金属,金属含量包含铜和锌的混合物,所述金属存在为(A)有机羧酸盐 含有一种或多种羧酸的铜和锌的组合,(B)有机碳酸的两种或多种铜和锌盐的组合,或(C)有机羧酸和混合有机物的金属盐的组合 酸盐复合物。

    Process for the aqueous impregnation of green wood with oil soluble
metal salts
    2.
    发明授权
    Process for the aqueous impregnation of green wood with oil soluble metal salts 失效
    绿色木材水溶性浸渍油溶性金属盐的方法

    公开(公告)号:US4532161A

    公开(公告)日:1985-07-30

    申请号:US598774

    申请日:1984-04-19

    摘要: A process for impregnating green wood with oil-soluble metal salts is described. The method comprises(a) contacting the green wood with an aqueous system comprising(i) water,(ii) at least one oil-soluble metal salt of an organic carboxylic acid, and(iii) at least one surfactant for a period of time sufficient to enable the metal salt to penetrate into the wood, and(b) removing the wood from contact with the aqueous system. Good penetration of the metal salt into the green wood is realized by this method when conducted under vacuum, at atmospheric pressure or at elevated pressures. Preferably, the metal salt is a preservative such as a fungicide, and the aqueous system also contains other desirable components such as fire retardants, coloring agents and insecticides.

    摘要翻译: 描述了用油溶性金属盐浸渍绿色木材的方法。 该方法包括(a)使绿色木材与水系统接触,所述水性体系包含(i)水,(ii)至少一种有机羧酸的油溶性金属盐,和(iii)至少一种表面活性剂一段时间 足以使金属盐渗透到木材中,和(b)除去木材与水系统的接触。 当在真空下,在大气压或高压下进行时,通过这种方法可以实现金属盐对绿色木材的良好渗透。 优选地,金属盐是防腐剂如杀真菌剂,并且水性体系还含有其它所需组分如阻燃剂,着色剂和杀虫剂。

    Elastomers with improved metal adhesion
    3.
    发明授权
    Elastomers with improved metal adhesion 失效
    具有改善金属附着力的弹性体

    公开(公告)号:US4137359A

    公开(公告)日:1979-01-30

    申请号:US847261

    申请日:1977-10-31

    摘要: Vulcanizable elastomeric compositions are described which comprise an elastomer and from about 0.001 to about 0.1 lb mole of metal per 100 lbs of elastomer, the metal content comprising at least one metal which is an oxidizing constituent and a second metal which is a polymerizing constituent or calcium, said metals being present as(a) an organic carboxylic acid salt of two different metals combined with one or more carboxylic acids,(b) a combination of two or more different metal salts of organic carboxylic acids, or(c) a combination of a metal salt of an organic carboxylic acid and a mixed organic acid salt complex.Such vulcanizable elastomeric compositions exhibit improved adhesion to metal surfaces and are, therefore, useful in preparing rubber laminates containing metal reinforcing elements.

    摘要翻译: {PG,1描述了可燃化的弹性体组合物,其包含弹性体和每100磅弹性体约0.001至约0.1lb摩尔的金属,金属含量包含至少一种作为氧化成分的金属和第二金属, 聚合成分或钙,所述金属作为{P1(A)有机碳酸盐与两种或更多种羧酸合并的两种不同金属的有机羧酸盐存在{P1(B)两种或更多种有机羧酸的不同金属盐的组合 ,OR {P1(C)有机羧酸的金属盐和混合有机酸盐复合物的组合。

    Metal carboxylate-alkoxy alcoholate composition and process
    4.
    发明授权
    Metal carboxylate-alkoxy alcoholate composition and process 失效
    金属羧酸盐 - 烷氧基醇化物的组成和工艺

    公开(公告)号:US3941606A

    公开(公告)日:1976-03-02

    申请号:US414654

    申请日:1973-11-12

    摘要: Metal carboxylate-glycol or carboxylate-glycol ether compositions, useful as siccatives in paint and like coating drier compositions, as internal combustion engine fuel--and other fuel--additives, and as stabilizers for polyvinyl chloride type plastics, and soluble in linseed oil and in aliphatic and aromatic hydrocarbon solvents, are prepared in liquid form by heating a mixture of (a) an appropriate metal powder or compound such as an oxide, hydroxide, acetate, or carbonate, (b) a branched chain aliphatic or a non-aromatic cyclic carboxylic acid, even an acid as low as a five carbon acid, or a mixture of such acids, and (c) a polyol or an alkoxy alkanol, e.g., a glycol or glycol ether; and, after filtration of the reaction mix, distilling off any volatile reaction by-product and also excess glycol or glycol ether. Higher than the usual equivalents of metal may be reacted for each equivalent of acid used. Certain of the products have remarkably low viscosity without special dilution. The products are believed to be metal carboxlate-glycolate, -ether glycolate-alcoholate complexes.

    摘要翻译: 金属羧酸酯 - 二醇或羧酸酯 - 二醇醚组合物,用作涂料和类似涂料干燥剂组合物中的杀螨剂,作为内燃机燃料和其它燃料添加剂,以及用作聚氯乙烯类塑料的稳定剂,并且可溶于亚麻子油和 通过加热(a)合适的金属粉末或化合物如氧化物,氢氧化物,乙酸盐或碳酸盐的混合物,(b)支链脂族或非芳族环状的 羧酸,甚至低至五碳酸的酸,或这些酸的混合物,和(c)多元醇或烷氧基烷醇,例如二醇或二醇醚; 并且在过滤反应混合物后,蒸除任何挥发性反应副产物和过量的二醇或二醇醚。 高于通常的金属当量可以使每一当量的酸反应。 某些产品在没有特殊稀释的情况下具有非常低的粘度。 据信这些产物是金属羧酸盐 - 乙醇酸盐, - 乙醇酸盐 - 醇盐络合物。

    Method for treating wood
    5.
    发明授权
    Method for treating wood 失效
    木材处理方法

    公开(公告)号:US4539235A

    公开(公告)日:1985-09-03

    申请号:US673188

    申请日:1984-11-19

    摘要: A method for treating wood with an aqueous composition having fungicidal and insecticidal properties. The aqueous composition comprises(a) at least one oil-soluble metal salt of an organic carboxylic acid having fungicidal properties wherein the metal is zinc, chromium, iron, antimony, lead, mercury or a mixture thereof,(b) at least one halopyridyl phosphate of the formula ##STR1## wherein R represents a halopyridyl group, Z represents oxygen or sulfur, and each R' is independently a lower alkoxy, amino or lower alkylamino group,(c) at least one surfactant, and(d) from about 60 to 99% of water.Such compositions penetrate into both dry and green wood rather readily, and the result is wood which is resistant to fungi and insects.

    摘要翻译: 用具有杀真菌性和杀虫性的含水组合物处理木材的方法。 含水组合物包含(a)至少一种具有杀真菌性的有机羧酸的油溶性金属盐,其中金属是锌,铬,铁,锑,铅,汞或其混合物,(b)至少一种卤代吡啶 磷酸酯,其中R代表卤代吡啶基,Z代表氧或硫,每个R'独立地是低级烷氧基,氨基或低级烷基氨基,(c)至少一种表面活性剂,和(d)约 60至99%的水。 这样的组合物相当容易地渗入干木和绿木,结果是耐真菌和昆虫的木材。

    Fungicidal and insecticidal compositions for treating wood
    6.
    发明授权
    Fungicidal and insecticidal compositions for treating wood 失效
    用于处理木材的杀真菌剂和杀虫剂组合物

    公开(公告)号:US4507152A

    公开(公告)日:1985-03-26

    申请号:US557770

    申请日:1983-12-02

    摘要: An aqueous composition having fungicidal and insecticidal properties is described which is useful particularly for treating wood. The aqueous composition comprises(a) at least one oil-soluble metal salt of an organic carboxylic acid having fungicidal properties wherein the metal is zinc, chromium, iron, antimony, lead, mercury or a mixture thereof,(b) at least one halopyridyl phosphate of the formula ##STR1## wherein R represents a halopyridyl group, Z represents oxygen or sulfur, and each R' is independently a lower alkoxy, amino or lower alkylamino group,(c) at least one surfactant, and(d) from about 60 to 99% of water.Such compositions penetrate into both dry and green wood rather readily, and the result is wood which is resistant to fungi and insects.

    摘要翻译: 描述了具有杀真菌和杀虫性质的水性组合物,其特别用于处理木材。 含水组合物包含(a)至少一种具有杀真菌性的有机羧酸的油溶性金属盐,其中金属是锌,铬,铁,锑,铅,汞或其混合物,(b)至少一种卤代吡啶 磷酸酯,其中R代表卤代吡啶基,Z代表氧或硫,每个R'独立地是低级烷氧基,氨基或低级烷基氨基,(c)至少一种表面活性剂,和(d)约 60至99%的水。 这样的组合物相当容易地渗入干木和绿木,结果是耐真菌和昆虫的木材。