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38 条记录 (耗时 0.017 秒)

    N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives
    3.
    发明授权
    N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives 失效
    N-（β-羰基 - 和β-氰基乙烯基）-2,2,6,6-四甲基 - 哌啶衍生物

    公开(公告)号：US5434202A

    公开(公告)日：1995-07-18

    申请号：US244209

    申请日：1994-06-03

    申请人： Alfred Krause ,  Alexander Aumueller ,  Hubert Trauth

    发明人： Alfred Krause ,  Alexander Aumueller ,  Hubert Trauth

    IPC分类号： C07D211/46 ,  C07D211/54 ,  C07D211/58 ,  C07D401/04 ,  C07D405/06 ,  C07D409/06 ,  C08K5/3432 ,  C08K5/3435

    CPC分类号： C07D211/58 ,  C07D211/46 ,  C08K5/3435

    摘要： N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.

    摘要翻译： PCT No.PCT / EP92 / 02733 Sec。 371日期：1994年6月3日 102（e）日期1994年6月3日PCT提交1992年11月27日PCT公布。 出版物WO93 / 11109 日期：6月10日，1993.N-（β-羰基 - 和β-氰基乙酰基）-2,2,6,6-四甲基哌啶衍生物，其中R1是COOR3，COR4，CONR4R5或CN，R2 具有R 1的意义或是C 1 -C 12 - 烷基或氢，R 3是氢，C 1 -C 8 - 烷基，C 5 -C 8 - 环烷基，C 3 -C 5 - 烯基或苯基，其可以被C1-C4- 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基，R 4和R 5各自为氢，C 1 -C 12烷基，C 5 -C 8环烷基或苯基， - 被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基三取代，n为1-4，各个n的X和A定义 在规范中。

    Preparation of 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids
    4.
    发明授权
    Preparation of 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids 失效
    4-烷基-2-羟基苯并噻吩-5-磺酸的制备

    公开(公告)号：US5072034A

    公开(公告)日：1991-12-10

    申请号：US627895

    申请日：1990-12-13

    申请人： Peter Neumann ,  Heinz Eilingsfeld ,  Alexander Aumueller

    发明人： Peter Neumann ,  Heinz Eilingsfeld ,  Alexander Aumueller

    IPC分类号： C07C309/42 ,  C07C303/08 ,  C07C309/44 ,  C07C309/59

    CPC分类号： C07C303/08

    摘要： 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by halogen, cyanao, hydroxyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.2 -C.sub.20 -alkoxycarbonyl, acyloxy and/or phenyl which is unsubstituted or substituted by C.sub.1 -c.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, R.sup.2 and R.sup.3 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.4 -C.sub.12 -cycloalkylalkyl, cyano, hydroxyl or hydroxyethyl or are each phenoxy, C.sub.7 -C.sub.10 -phenalkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, and R.sup.4 is hydrogen or sulfo, are prepared by reacting a 4-alkoxy-2-hydroxybenzophenone of the general formula II ##STR2## with chlorosulfonic acid at from -20.degree. to +100.degree. C., by a novel and improved process in which the reaction is carried out in an aliphatic, cycloaliphatic and/or aromatic carboxylate as solvent.

    摘要翻译： 其中R 1是未被取代或被卤素，氰基，羟基，C 1 -C 20烷氧基，C 2 -C 20烷氧基取代的C 1 -C 20烷基的4-烷氧基-2-羟基二苯甲酮-5-磺酸 -C 20 - 烷氧基羰基，未被取代或被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基和/或卤素取代的酰氧基和/或苯基，R 2和R 3彼此独立地为氢，卤素，C 1 -C 12 - 烷基 C 1 -C 12烷氧基，C 1 -C 4卤代烷基，C 3 -C 8环烷基，C 4 -C 12环烷基烷基，氰基，羟基或羟乙基，或各自为苯氧基，未取代或被C1- C4-烷基，C1-C4-烷氧基和/或卤素，R4是氢或磺基，是通过使通式II的4-烷氧基-2-羟基二苯甲酮与（II）的4-磺酰基-2- 通过一种新的改进的方法，其中反应在脂族，脂环族和/或芳族羧酸酯作为溶剂中进行。

    Process for the preparation of 2,4-dihydroxybenzophenone
    5.
    发明授权
    Process for the preparation of 2,4-dihydroxybenzophenone 失效
    2,4-二羟基二苯甲酮的制备方法

    公开(公告)号：US4990680A

    公开(公告)日：1991-02-05

    申请号：US463365

    申请日：1990-01-11

    申请人： Peter Neumann ,  Alexander Aumueller

    发明人： Peter Neumann ,  Alexander Aumueller

    IPC分类号： C07C45/45 ,  C07C45/00 ,  C07C49/83

    CPC分类号： C07C45/008

    摘要： A process for the preparation of 2,4-dihydroxybenzophenone by reacting resorcinol with benzotrichloride in water, wherein the reaction mixture contains a surfactant or a dispersing or emulsifying agent in a concentration of from 0.05 to 5%, by weight of the water.The product is obtained in high yield and good purity.

    摘要翻译： 一种通过使间苯二酚与苯并三氯在水中反应制备2,4-二羟基二苯甲酮的方法，其中反应混合物含有浓度为0.05至5重量％水的表面活性剂或分散或乳化剂。 得到产物，产率高，纯度高。

    Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials
    6.
    发明授权
    Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials 失效
    双酚（3.3.1）壬烷衍生物，用于稳定有机物质

    公开(公告)号：US4943391A

    公开(公告)日：1990-07-24

    申请号：US286295

    申请日：1988-12-10

    申请人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

    发明人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

    IPC分类号： C07D471/08 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3442 ,  C09D7/12 ,  C09K15/18

    CPC分类号： C07D471/08

    摘要： Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.

    摘要翻译： 双环[3.3.1]通式（I）的壬烷衍生物其中n是1至70的整数，R 1是氢，R 2是氢或羟基，或者基团R 3和R 4 各自独立地为其它苯基或1-或2-萘基，该苯基或萘基各自可被1,2或3个C 1 -C 12烷基，C 1 -C 12烷氧基，氯，溴，氟，三氟甲基或氰基取代 在2或3个取代基的情况下，这些取代基相同或不同，A和B各自独立地为化学键，C 1 -C 22 - 亚烷基，亚环烷基，其中m和o分别为 1至20，R 10为氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 7 -C 18 - 苯基烷基，苯基或C 2 -C 22 - 氰基烷基，M为式 A不仅通过氮原子而且通过碳原子，并且R 11，R 12，R 13和R 14各自独立地为C 1 -C 4 - 烷基，或者R 11和R 12和/或R 13和R 14分别为四甲基 烯或五亚甲基，R 5是氢，氰基，羟基，R 15是氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 5 -C 16 - 苯基烷基或5-或6-元杂环 或者当n为1时，-MB-R 5为式（VI）的基团，其中R 16为C 1 -C 4 - 烷基，R 17为氢，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基 和R18是氢或C1-C12烷基，在塑料方面具有非常好的稳定性，是无色的，与有机聚合物高度相容并且对热分解是稳定的。

    Production of an electrically conductive surface layer on moldings consisting of plastics
    7.
    发明授权
    Production of an electrically conductive surface layer on moldings consisting of plastics 失效
    在由塑料制成的模制品上制造导电表面层

    公开(公告)号：US4897289A

    公开(公告)日：1990-01-30

    申请号：US312310

    申请日：1989-02-17

    申请人： Alexander Aumueller ,  Peter Neumann ,  Gerd Blinne ,  Gerhard Lindenschmidt

    发明人： Alexander Aumueller ,  Peter Neumann ,  Gerd Blinne ,  Gerhard Lindenschmidt

    IPC分类号： H05F1/02 ,  C08J7/02 ,  C09K3/16 ,  H01B1/12 ,  H01B13/00

    CPC分类号： H01B1/121

    摘要： An electrically conductive surface layer is produced on moldings consisting of plastics which are soluble or swellable in organic solvents, the conductivity of the said layer being based on a system, incorporated therein, oforganic electron acceptors (I) on the one hand andorganic electron donors (II), iodides (III) or a mixture of (II) and (III) as electron donors, on the other hand,by a process in which the moldings are treated with organic solutions of these components.The products have a surface resistance of from 10.sup.8 to 10.sup.2 ohm and have the advantage that the remaining properties of the moldings are virtually unaffected by the agents (I) to (III).

    摘要翻译： 导电表面层在由塑料制成的成型体上产生，该塑料在有机溶剂中是可溶的或可溶胀的，所述层的导电性基于其中并入有机电子受体（I）的系统和有机电子 供体（II），碘化物（III）或作为电子给体的（II）和（III）的混合物，另一方面，通过这些成分用这些组分的有机溶液处理的方法。 产品具有108至102欧姆的表面电阻，并且具有的优点是模制品的剩余性能几乎不受试剂（I）至（III）的影响。

    Maleimide/.alpha.-olefin copolymers and their use as light stabilizers and stabilizers for organic material
    8.
    发明授权
    Maleimide/.alpha.-olefin copolymers and their use as light stabilizers and stabilizers for organic material 失效
    马来酰亚胺/α-烯烃共聚物及其用作有机材料的光稳定剂和稳定剂

    公开(公告)号：US5710228A

    公开(公告)日：1998-01-20

    申请号：US644123

    申请日：1996-05-10

    申请人： Alfred Krause ,  Walter Denzinger ,  Albert Hettche ,  Alexander Aumueller ,  Hubert Trauth

    发明人： Alfred Krause ,  Walter Denzinger ,  Albert Hettche ,  Alexander Aumueller ,  Hubert Trauth

    IPC分类号： C08F2/06 ,  C08F8/32 ,  C08F210/14 ,  C08F222/40 ,  C08F210/00

    CPC分类号： C08F8/32 ,  C08F210/14

    摘要： Maleimide/.alpha.-olefin copolymers are composed of structural units I ##STR1## where R.sup.1 is a tetramethylpiperidinyl radical of the formula II ##STR2## R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, formyl, C.sub.2 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.5 - or C.sub.6 -cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula --CR.sup.4 =CH--CO--OR.sup.5, R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.5, and R.sup.5 is C.sub.5 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.18 -aralkyl, phenyl or tolyl, and up to 8 mol %, based on II, of R.sup.1 may furthermore be hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and R.sup.2 is a mixture of C.sub.14 -C.sub.28 -alkyl groups, where two of these alkyl groups, which may differ by no more than two carbon atoms, each account for at least 30% of this mixture, having an average molecular weight of from 1,000 to 50,000. The copolymers described are suitable as light stabilizers and stabilizers for organic material, in particular plastics and coatings.

    摘要翻译： 马来酰亚胺/α-烯烃共聚物由结构单元Ⅰ（II）组成，其中R 1是式II的四甲基哌啶基，其中R 3是氢，C 1 -C 6烷基，甲酰基，C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 - 或C 6 - 环烷氧基，氰基甲基，2-羟乙基，苄基或式-CR 4 = CH-CO-OR 5基团，R 4是氢，C 1 -C 6烷基或 式-CO-OR5和R5是C5-C18-烷基，C5-C8-环烷基，C7-C18-芳烷基，苯基或甲苯基，并且基于II的至多8摩尔％的R 1还可以是氢， C 1 -C 22 - 烷基或C 5 -C 8 - 环烷基，并且R 2是C 14 -C 28 - 烷基的混合物，其中两个可以不超过两个碳原子的烷基各自占据至少30％ 的该混合物，其平均分子量为1,000至50,000。 所述的共聚物适合用作有机材料的光稳定剂和稳定剂，特别是塑料和涂料。

    Amino compounds as processing stabilizers for thermoplastic materials
    9.
    发明授权
    Amino compounds as processing stabilizers for thermoplastic materials 失效
    氨基化合物作为热塑性材料的加工稳定剂

    公开(公告)号：US5496877A

    公开(公告)日：1996-03-05

    申请号：US313115

    申请日：1994-10-12

    申请人： Alexander Aumueller ,  Hubert Trauth

    发明人： Alexander Aumueller ,  Hubert Trauth

    IPC分类号： C07D233/61 ,  C08K5/17 ,  C08K5/34 ,  C08K5/3445 ,  C08K5/3462 ,  C08L101/00 ,  C08K3/20

    CPC分类号： C08K5/3462 ,  C08K5/17 ,  C08K5/3445

    摘要： Compounds of the general formula (I) or (II) ##STR1## where m is 2 or 3,n is an integer from 1 to 6,R.sup.1 and R.sup.2 are, independently of one another, hydrogen, C.sub.1 - to C.sub.18 -alkyl, C.sub.3 - to C.sub.8 -alkenyl or C.sub.5 - to C.sub.12 cycloalkyl, R.sup.4 and R.sup.5 are, independently of one another, hydrogen, C.sub.1 - to C.sub.18 -alkyl, C.sub.3 - to C.sub.8 -alkenyl, C.sub.5 - to C.sub.12 -cycloalkyl or C.sub.7 - to C.sub.12 -phenylalkyl, in which the phenyl ring may be substituted by up to 3 C.sub.1 - to C.sub.12 -alkyl or C.sub.1 - to C.sub.12 -alkoxy groups,X is oxygen or NR.sup.3,R.sup.3 is an R.sup.1 radical or a group of the formula ##STR2## B completes a 3- to 12-membered heterocycle, A when n=1 is an aliphatic radical or unsubstituted or substituted phenyl, andA when n>1 is a divalent organic radical, are used as processing stabilizers for thermoplastic materials.

    摘要翻译： PCT No.PCT / EP93 / 00951 Sec。 371日期：1994年10月12日 102（e）日期1994年10月12日PCT提交1993年4月20日PCT公布。 公开号WO93 / 22376 （I）或（II）的化合物其中m为2或3，n为1至6的整数，R 1和R 2为 彼此独立地为氢，C 1至C 18烷基，C 3至C 8链烯基或C 5至C 12环烷基，R 4和R 5彼此独立地为氢，C 1 -C 18 - 烷基，C 3 - C 8 - 烯基，C 5 - 至C 12 - 环烷基或C 7 - 至C 12 - 苯基烷基，其中苯环可被至多3个C 1 -C 12 - 烷基或C 1 -C 12烷氧基取代，X为氧或NR 3 R 3为R 1基团或式VIII所示基团，当n = 1是脂族基团或未取代或取代的苯基时，A完成3至12元杂环，当n> 1是二价 有机基团用作热塑性材料的加工稳定剂。