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公开(公告)号：US4810119A
公开(公告)日：1989-03-07
申请号：US115453
申请日：1987-10-30
申请人： Ali Afzali-Ardakani , Ronald T. Cannavaro , Walter Crooks , Mukesh Desai , Keith S. Pennington , Jean-Piet Hoekstra , Eva E. Simonyi
发明人： Ali Afzali-Ardakani , Ronald T. Cannavaro , Walter Crooks , Mukesh Desai , Keith S. Pennington , Jean-Piet Hoekstra , Eva E. Simonyi
CPC分类号： B41M5/3825 , B41J31/05 , Y10S428/913
摘要： An improved thermal transfer resistive ribbon usable in high resolution printing comprising a dual resistive layer formed of a first layer of low resistivity and a second layer of high resistivity, method of production thereof, use thereof and apparatus including the same.
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公开(公告)号：US5176947A
公开(公告)日：1993-01-05
申请号：US624003
申请日：1990-12-07
申请人： Ali Afzali-Ardakani , Mukesh K. Desai , Jahn P. Hoekstra , Keith S. Pennington , Eva E. Simonyi
发明人： Ali Afzali-Ardakani , Mukesh K. Desai , Jahn P. Hoekstra , Keith S. Pennington , Eva E. Simonyi
IPC分类号： B41C1/04 , B23H9/06 , B41C1/10 , B41M5/24 , B41N1/14 , C08F8/00 , C08F8/38 , C08L29/14 , C09D129/14
CPC分类号： B41C1/1033 , B23H9/06 , B41M5/245 , Y10T428/24802 , Y10T428/24901 , Y10T428/24917 , Y10T428/254 , Y10T428/259 , Y10T428/31678
摘要： Improved electroerosion recording media can be prepared by utilizing, on top of a polyester, paper, or metal substrate, a polyvinylbutyral polymer cross-linked with a mixed phenol-tert-butylphenol formaldehyde cross-linking agent as a base layer, and an erodible metallic layer sufficiently thin to be erodible in response to current pulses delivered by a stylus of an electroerosion printer. In a preferred embodiment, the polymeric layer further contains silica. The recording medium may also be top coated with a lubricating agent. The formulation provides excellent adhesion of the conductive layer, and allows the thickness of the aluminum to be increased up to 75%, resulting in an optical density (with aluminum as the metallic layer) of up to 3.5.
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公开(公告)号：US4915519A
公开(公告)日：1990-04-10
申请号：US115227
申请日：1987-10-30
CPC分类号： B41M5/3825 , G03F7/202 , Y10S428/913 , Y10T156/1189 , Y10T428/24901 , Y10T428/24917
摘要： An improved apparatus and process are described in which a direct negative is formed using commercially available multi-stylus recording heads. A negative precursor comprised of a transparent support and an opaque thermoplastic ink layer carried thereon, is brought into contact with an ink receiving medium comprised of a resistive layer and a thin conductive ink receiving layer thereon. Electrical currents are provided by the recording styli of the multi-stylus recording head to the resistive layer to provide sufficient heat to soften regions of the opaque ink brought into contact with the conductive layer, by which regions of said opaque ink are transferred to the ink receiving conductive layer. In this manner, a pattern of opaque ink regions is removed from the surface of said transparent support, whereby a direct negative is formed having light opaque and light transparent regions.
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公开(公告)号：US4800397A
公开(公告)日：1989-01-24
申请号：US115471
申请日：1987-10-30
申请人： Ali Afzali-Ardakani , Mukesh Desai , Bradford J. Factor , Jan-Pieter Hoekstra , Keith S. Pennington
发明人： Ali Afzali-Ardakani , Mukesh Desai , Bradford J. Factor , Jan-Pieter Hoekstra , Keith S. Pennington
IPC分类号： B41M5/382 , B41C1/055 , B41C1/06 , B41C1/10 , B41J2/42 , B41M5/26 , G01D15/10 , H05K3/04 , G01D9/00
CPC分类号： B41M5/3825 , H05K3/046 , H05K2201/0129 , H05K2203/0528 , H05K2203/1105 , Y10T29/49155
摘要： An improved apparatus and process are described in which metal images are transferred to a softenable receiving layer using commercially available multi-stylus recording heads. The transfer medium is comprised of a resistive layer and a thin metal layer thereon. Electrical currents are provided by the recording styli of the multi-stylus recording head. Localized electrical currents in the resistive layer provide sufficient heat in the metal layer to soften regions of a metable receiving layer when it is brought into contact with said heated metal layer. Metal imaging for use in printed circuit board manufacture and in formation of printing masters can be transferred by this technique.
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5.发明授权Scratch resistant recording materials for electroerosion printing not requiring a lubricant overcoat 失效用于电腐蚀印刷的防刮擦记录材料不需要润滑剂外涂层
公开(公告)号：US4554562A
公开(公告)日：1985-11-19
申请号：US567297
申请日：1983-12-30
CPC分类号： B41M5/245 , Y10T428/24893 , Y10T428/25 , Y10T428/254 , Y10T428/3154
摘要： Electroerosion recording materials of superior scratch resistance are provided without the need for a lubricant overcoat by incorporating a hard, lubricating hydrophobic polymer layer between the support and the removable, thin conductive layer to reduce plastic deformation of the support under stylus writing pressure. The intermediate polymer layer provides a highly adhering surface for the overlying aluminum film and contains graphite fluoride and/or fluorocarbon resins such as Teflon.RTM. and hard particles such as silica. The materials may be used in various printing processes including making directly readable images, direct negatives and wear resistant offset printing masters.
摘要翻译： 通过在支撑体和可移除的薄导电层之间并入硬的润滑的疏水性聚合物层，在不需要润滑剂外涂层的情况下，提供了优异的耐刮擦性的电蚀记录材料，以减少支架在笔写压力下的塑性变形。 中间聚合物层为覆盖的铝膜提供高度粘附的表面，并且包含氟化石墨氟化物和/或氟碳树脂如Teflon TM和硬颗粒如二氧化硅。 这些材料可以用于各种印刷工艺中，包括制造直接可读的图像，直接的底片和耐磨胶版印刷主机。
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公开(公告)号：US5084331A
公开(公告)日：1992-01-28
申请号：US657270
申请日：1991-02-11
IPC分类号： B41M5/24
CPC分类号： B41M5/245 , Y10T428/30
摘要： Electroerosion recording material with improved corrosion resistance provided by an overlayer of a protective lubricant composition of conductive particles of high lubricity dispersed in a partially crosslinked, water insoluble, hydrophilic polymeric binder.
摘要翻译： 具有改善的耐腐蚀性的电蚀记录材料由分散在部分交联的水不溶性的亲水性聚合物粘合剂中的高润滑性的导电颗粒的保护性润滑剂组合物的覆盖层提供。
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公开(公告)号：US4678701A
公开(公告)日：1987-07-07
申请号：US793525
申请日：1985-10-31
CPC分类号： B41M5/3825 , B41J31/05 , Y10S428/913 , Y10S428/914 , Y10T428/24917 , Y10T428/24942 , Y10T428/25 , Y10T428/261 , Y10T428/31 , Y10T428/31507 , Y10T428/3154 , Y10T428/31544
摘要： An improved resistive ribbon for resistive thermal transfer printing is described in which the resistive layer of the ribbon has enhanced thermal and mechanical properties. The ribbon is a multi-layer ribbon including a resistive layer, an electrical current return layer, and an ink layer. The resistive layer has an additive therein which phase separates and concentrates in a thin surface region near the interface of the resistive layer and the current return layer. This thin region has superior thermal and mechanical properties, and protects the remainder of the resistive layer during the printing operation, without adversely affecting the mechanical, electrical, and thermal properties of the overall resistive layer. These additives are those which will form a polymer having a sufficiently high dissociation temperature to withstand the adverse effects of heat build-up at the interface. Suitable additives include graphite fluorides, fluorocarbon resins such as Teflon.RTM., and CeF.sub.4.
摘要翻译： 描述了用于电阻热转移印刷的改进的电阻带，其中带的电阻层具有增强的热和机械性能。 带是包括电阻层，电流返回层和油墨层的多层带状物。 电阻层具有添加剂，其中相分离并集中在电阻层和电流返回层的界面附近的薄表面区域中。 该薄区域具有优异的热和机械性能，并且在打印操作期间保护电阻层的其余部分，而不会不利地影响整个电阻层的机械，电气和热性能。 这些添加剂是形成具有足够高解离温度的聚合物的那些添加剂，以承受界面处的热积累的不利影响。 合适的添加剂包括石墨氟化物，氟碳树脂如Teflon TM和CeF 4。
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公开(公告)号：US4567490A
公开(公告)日：1986-01-28
申请号：US567300
申请日：1983-12-30
IPC分类号： B41M5/24 , B41N1/14 , H05K3/00 , H05K3/08 , H05K3/28 , G01D15/34 , B05D5/12 , B32B5/16 , G03C5/24
CPC分类号： B41M5/245 , H05K3/0002 , H05K3/08 , Y10T428/25 , Y10T428/254 , Y10T428/31692
摘要： Electroerosion recording materials are provided with a surface lubricant film of particulate lubricating nonconductive graphite fluoride and optional conductive materials in a polymeric binder. The lubricating agents reduce stylus scratching of the conductive layer during electroerosion printing, improve contrast, provide a beneficial coating on the writing electrode or stylus and improve the handling and writing characteristics of the recording material. The lubricating agents/polymer films are especially useful (1) where the substrate of the recording material is light transmissive and, after the electroerosion process, the resulting product is suitable for direct-negative applications and (2) where direct offset masters are produced by removal of noneroded lubricant film.
摘要翻译： 电解记录材料在聚合物粘合剂中设置有颗粒润滑非导电氟化石墨和可选导电材料的表面润滑剂膜。 润滑剂在电腐蚀印刷期间降低导电层的触针刮擦，改善对比度，在书写电极或触控笔上提供有益的涂层，并提高记录材料的处理和书写特性。 润滑剂/聚合物膜是特别有用的（1）其中记录材料的基底是透光的，并且在电腐蚀过程之后，所得到的产品适用于直接阴性应用，和（2）其中直接偏移主体由 去除非润滑油膜。
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公开(公告)号：US4617579A
公开(公告)日：1986-10-14
申请号：US597148
申请日：1984-04-05
摘要： Electroerosion recording materials for "direct negative" and "offset master" are provided with a surface protective coating of solid conductive lubricant dispersed in a hydrophilic, crosslinked polymeric matrix. The protective films are especially useful where direct offset masters are produced without removal of non-eroded lubricant film.The recording medium of this invention provides use as a defect-free "direct negative" and/or "direct offset master", without requiring the removal of the overlayer prior to use on the printing press. The protective coatings are applied from aqueous dispersions of polymer-particulate compositions and thus avoiding the use of organic solvents.
摘要翻译： “直接负极”和“偏移母版”的电极记录材料设置有分散在亲水交联聚合物基体中的固体导电润滑剂的表面保护涂层。 保护膜特别适用于直接胶印主机而不去除未被侵蚀的润滑剂膜。 本发明的记录介质提供用作无缺陷的“直接负极”和/或“直接偏移主控”，而不需要在印刷机上使用之前去除覆盖层。 保护涂层由聚合物 - 颗粒组合物的水性分散体施加，从而避免使用有机溶剂。
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公开(公告)号：US4836106A
公开(公告)日：1989-06-06
申请号：US115232
申请日：1987-10-30
CPC分类号： B41C1/1041
摘要： This invention describes a direct master for offset printing. The master comprises a thin metal layer, a thermoplastic layer disposed on the metal layer, and a conductive oxide layer evaporated on the metal layer. When this master is subjected to electrical pulses from the styli of a printer, some of the thermoplastic layer diffuses through the oxide layer changing selected regions of the oxide layer to oleophilic regions.
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