Process for making aromatic hydrocarbons using an acid treated zeolite
    1.
    发明授权
    Process for making aromatic hydrocarbons using an acid treated zeolite 失效
    使用酸处理的沸石制备芳烃的方法

    公开(公告)号:US06593503B1

    公开(公告)日:2003-07-15

    申请号:US08695482

    申请日:1996-08-12

    IPC分类号: C07C600

    摘要: A catalyst composition and a process for converting a hydrocarbon stream such as, for example, gasoline to C6 to C8 aromatic hydrocarbons such as toluene and xylenes are disclosed. The catalyst composition includes an alumina, a silica, and a metal wherein the weight ratio of aluminum to silicon is in the range of from about 0.002:1 to about 0.6:1. The process includes contacting a hydrocarbon stream with the catalyst composition under a condition sufficient to effect the conversion of a hydrocarbon to a C6 to C8 aromatic hydrocarbon. Also disclosed is a process for producing the catalyst composition which includes: (1) contacting a zeolite with an effective amount of an acid under a condition sufficient to effect a reduction in aluminum content of the zeolite to produce an acid-leached zeolite; and (2) impregnating the acid-leached zeolite with an effective amount of a metal compound under a condition sufficient to effect the production of a metal-promoted zeolite.

    摘要翻译: 公开了一种催化剂组合物和将烃流例如汽油转化为C 6至C 8芳族烃如甲苯和二甲苯的方法。 催化剂组合物包括氧化铝,二氧化硅和金属,其中铝与硅的重量比在约0.002:1至约0.6:1的范围内。 该方法包括使烃流与催化剂组合物在足以使碳氢化合物转化为C 6至C 8芳族烃的条件下接触。 还公开了一种生产催化剂组合物的方法,其包括:(1)在足以使沸石的铝含量降低以产生酸浸出的沸石的条件下使沸石与有效量的酸接触; 和(2)在足以产生金属促进的沸石的条件下,用有效量的金属化合物浸渍酸浸出的沸石。

    Transalkylation/hydrodealkylation of C.sub.9 + aromatic compounds with a
zeolite
    2.
    发明授权
    Transalkylation/hydrodealkylation of C.sub.9 + aromatic compounds with a zeolite 失效
    C9 +芳族化合物与沸石的烷基转移/加氢脱烷基化

    公开(公告)号:US5866742A

    公开(公告)日:1999-02-02

    申请号:US905886

    申请日:1997-08-04

    摘要: A catalyst composition, a process for producing the composition and a hydrocarbon conversion process for converting a C.sub.9 + aromatic compound to a C.sub.6 to C.sub.8 aromatic hydrocarbon such as a xylene are disclosed. The composition comprises a zeolite having incorporated therein a promoter comprising carbon and a metal or metal oxide. The composition can be produced by incorporating a metal compound into the zeolite followed by thermal treatment of the resulting zeolite with a hydrocarbon. The hydrocarbon conversion process comprises contacting a fluid which comprises a C.sub.9 + aromatic compound with the catalyst composition under a condition sufficient to effect the conversion of a C.sub.9 + aromatic compound to a C.sub.6 to C.sub.8 aromatic hydrocarbon.

    摘要翻译: 公开了一种催化剂组合物,该组合物的制造方法和将C9 +芳族化合物转化成C6〜C8芳香族烃如二甲苯的碳氢转化方法。 该组合物包括其中掺入了包含碳和金属或金属氧化物的促进剂的沸石。 可以通过将金属化合物引入沸石中,然后用烃对所得沸石进行热处理来制备组合物。 烃转化方法包括使C9 +芳族化合物的流体与催化剂组合物在足以使C9 +芳族化合物转化为C6至C8芳族烃的条件下接触。

    Catalyst composition and processes therefor and therewith
    3.
    发明授权
    Catalyst composition and processes therefor and therewith 失效
    催化剂组合物及其工艺及其

    公开(公告)号:US5714660A

    公开(公告)日:1998-02-03

    申请号:US705926

    申请日:1996-08-29

    IPC分类号: C07C4/18 C07C4/12

    摘要: A catalyst composition and a process for hydrodealkylating a C.sub.9 + aromatic compound such as, for example, 1,2,4-trimethylbenzene to a C.sub.6 to C.sub.8 aromatic hydrocarbon such as a xylene are disclosed. The composition comprises an alumina, a metal oxide, and an acid site modifier selected from the group consisting of silicon oxides, phosphorus oxides, boron oxides, magnesium oxides, tin oxides, titanium oxides, zirconium oxides, molybdenum oxides, germanium oxides, indium oxides, lanthanum oxides, cesium oxides, and combinations of any two or more thereof. The process comprises contacting a fluid which comprises a C.sub.9 + aromatic compound with the catalyst composition under a condition sufficient to effect the conversion of a C.sub.9 + aromatic compound to a C.sub.6 to C.sub.8 aromatic hydrocarbon.

    摘要翻译: 公开了一种催化剂组合物和将C 9+芳族化合物例如1,2,4-三甲基苯加氢脱烷基化成C6-C8芳族烃如二甲苯的方法。 该组合物包含氧化铝,金属氧化物和酸性位点改性剂,其选自氧化硅,氧化磷,氧化硼,氧化镁,氧化锡,氧化钛,氧化锆,氧化钼,氧化锗,氧化铟 ,氧化镧,氧化铯及其任意两种以上的组合。 该方法包括在足以使C 9+芳族化合物转化为C 6至C 8芳族烃的条件下使包含C 9+芳族化合物的流体与催化剂组合物接触。

    Process and catalyst for upgrading liquid hydrocarbons
    8.
    发明授权
    Process and catalyst for upgrading liquid hydrocarbons 失效
    液化烃升级的工艺和催化剂

    公开(公告)号:US6162353A

    公开(公告)日:2000-12-19

    申请号:US469202

    申请日:1999-12-21

    IPC分类号: C10G45/04

    CPC分类号: C10G45/04 C10G2400/02

    摘要: An improved process and novel catalyst for upgrading catalytically cracked liquid hydrocarbons whereby the hydrodesulfurization and liquid yield of the hydrocarbons are enhanced while the octane number thereof is substantially maintained. The process basically comprises contacting the hydrocarbons with the catalyst composition which is comprised of a sulfided, molybdenum carbide and zinc hexaborate promoted, binder bound zeolite in the presence of hydrogen and under conditions sufficient to effect said upgrading.

    摘要翻译: 一种用于改进催化裂化液体烃的改进方法和新型催化剂,从而提高烃的加氢脱硫和液体产率,同时基本维持其辛烷值。 该方法基本上包括使烃与催化剂组合物接触,所述催化剂组合物由硫化物,碳化钼和六硼酸锌组成,所述催化剂组合物在氢的存在下和足以实现所述升级的条件下与粘合剂结合的沸石接触。