摘要:
The device for measuring the internal diameter of tubes 2 consisting of two interconnected measuring units 3 and 4 that are connected to one another. The first measuring unit 3 is formed by a measuring head 9 in conjunction with a displacement transducer 7, which is axially displaceable within a tube 2. The axial displacement of the measuring head 9 is determined by a length measuring device consisting of a friction wheel 25 associated with a rotation transducer. To achieve this, the friction wheel is in functional connection with a flexible tube 24 which is rigidly connected to the measuring head 9. Thus, this measuring device makes it possible to determine internal diameters at two positions located at axially spaced locations from one another in a tube 2.
摘要:
The present invention relates to a powder coating composition having a glass transition temperature of 20.degree. to 80.degree. C. and containing(A) 56 to 86.9% by weight of a polyacrylate polyol component having a hydroxyl number of 30 to 155 and a glass transition temperature of 30.degree. to 120.degree. C.,(B) 0.1 to 9% by weight of a polyester polyol component having a hydroxyl number of 40 to 180 and a glass transition temperature of -40.degree. to 80.degree. C.,(C) 13 to 35% by weight of a polyisocyanate component having a glass transition temperature of -40.degree. to 60.degree. C. and containing at least one ketoxime-blocked polyisocyanate selected from (i) polyisocyanate derivatives prepared from 1,6-diisocyanatohexane and containing biuret, isocyanurate, uretdione, and/or urethane groups, (ii) polyisocyanate derivatives prepared from mixtures of 1,6-diisocyanatohexane and 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane and containing isocyanurate groups and optionally uretdione groups and (iii) polyisocyanate derivatives prepared from 4,4'-diisocyanato-dicyclohexylmethane and containing urethane groups, and(D) at least one catalyst for the reaction between blocked isocyanate groups and hydroxyl groups,wherein i) the percentages of components (A), (B), and (C) are based on the total weight of these components and ii) components (A), (B), and (C) are present in amounts sufficient to provide an equivalent ratio of blocked isocyanate groups to hydroxyl groups of 0.5:1 to 1.5:1.The present invention is also relates to a process for the preparation of this powder coating composition and to heat-resistant substrates, particularly automotive body parts, coated with this powder coating composition.
摘要:
The present invention relates to an implant, in particular an intraluminal endoprothesis, comprising a body containing a metallic material, and comprising at least one functional element that is fastened to the body and has a material composition in at least a portion of its volume that differs from the material of the body, the material composition preferably including radio-opaque and/or x-ray opaque material. To effectively prevent accelerated degradation due to the formation of a local cell of the material of the body and the functional element, the at least one functional element includes a first layer at least in the region of its surface where it is bonded to the body, the first layer primarily containing at least one metal oxide. Furthermore, the manufacture of an implant of this type is described.
摘要:
The present invention relates to a powder coating composition for the production of matte coatings, containing A) a hydroxyl group-containing component, B) an addition polymerization compound which is based on aliphatic and/or cycloaliphatic diisocyanates and contains uretdione groups, C) a component which contains carboxyl and/or carboxylic acid anhydride groups and is selected from C1) aliphatic and/or cycloaliphatic dicarboxylic acids containing 4 to 20 carbon atoms, C2) monomeric and/or polymeric anhydrides of the acids C1) which may optionally be modified and C3) aliphatic hydroxycarboxylic acids containing 4 to 18 carbon atoms, and D) a component which contains groups which are reactive with carboxyl and/or carboxylic acid anhydride groups, provided that components A), B), C) and D) are present in amounts such that 0.6 to 1.4 isocyanate groups of component B) are present for each hydroxyl group of component A), 0.3 to 1.5 groups of component D) which are reactive with carboxyl and/or carboxylic acid anhydride groups are present for each carboxyl equivalent of component C) and the amount of components C) and D) is 10 to 40% by weight of the total amount of components A), B), C) and D). The present invention also relates to the use of this powder coating composition for coating heat-resistant substrates.
摘要:
A powder coating composition for the production of non-yellowing, flexible coatings which contains a mixture of a polyisocyanate component which contains one or more lacquer polyisocyanates having free (unblocked) isocyanate groups bound to primary and/or secondary carbon atoms and a polyol component containing one or more polyhydroxyl compounds selected from polyhydroxy polyurethanes, polyhydroxy polyacrylates and polyhydroxy polyesters, wherein at least 50% of the hydroxyl groups are bound to secondary or tertiary carbon atoms; and its use for coating heat-resistant substrates, in particular as clear coating compositions for automobiles.
摘要:
The present invention relates to an implant, in particular an intraluminal endoprothesis, comprising a body containing a metallic material, and comprising at least one functional element that is fastened to the body and has a material composition in at least a portion of its volume that differs from the material of the body, the material composition preferably including radio-opaque and/or x-ray opaque material. To effectively prevent accelerated degradation due to the formation of a local cell of the material of the body and the functional element, the at least one functional element includes a first layer at least in the region of its surface where it is bonded to the body, the first layer primarily containing at least one metal oxide. Furthermore, the manufacture of an implant of this type is described.
摘要:
A powder coating composition which is curable at 120.degree. to 150.degree. C. and contains A) one or more copolymers prepared from olefinically unsaturated monomers and containing epoxy groups and optionally hydroxyl groups, B) one or more curing agents containing carboxylic acid or carboxylic acid anhydride groups, and C) one or more polyaddition compounds which contain uretdione groups, have a melting point or range of 40.degree. C. to 120.degree. C. and are prepared from (cyclo)aliphatic diisocyanates; and its use for coating of heat-resistant substrates, especially automotive substrates.
摘要:
The present invention relates to polyisocyanate mixtures which are solid below 40.degree. C. and liquid above 125.degree. C. and which havea) an average isocyanate functionality of at least 2.1,b) a content of free isocyanate groups bonded to tertiary (cyclo)aliphatic carbon atoms (calculated as NCO; molecular weight=42) of 5 to 22 wt. %,c) a urethane group content calculated as --NH--CO--O--; molecular weight=59) of 2 to 30 wt. %,d) an isocyanurate group content (calculated as C.sub.3 N.sub.3 O.sub.3 ; molecular weight=126) of 0 to 30 wt. % ande) a carboxylic acid ester group content (calculated as --CO--O--; molecular weight=44) of 0 to 25 wt. % and/orf) a carbonate group content (calculated as --O--CO--O--; molecular weight=60) of from 0 to 34 wt. %with the proviso that the total amount of ester groups e) and carbonate groups f) is at least 2 wt. %.The present invention also relates to a process for the production of these polyisocyanate mixtures and to their use for the production of polyurethanes, in particular as the crosslinking component in heat-curable two-component polyurethane powder coatings for coating heat-resistant substrates.
摘要:
The present invention relates to a powder coating composition for the production of non-yellowing flexible coatings which is solid below 30.degree. C. and liquid above 120.degree. C. and contains a mixture of A) a polyisocyanate component which i) has a content of blocked isocyanate groups (expressed as NCO, molecular weight=42) of 3.0 to 14.0% by weight, ii) has a functionality, based on the blocked isocyanate groups, of 1.9 to 2.3 and iii) and contains at least one .epsilon.-caprolactam-blocked polyisocyanate based on the reaction product of 4,4'-diisocyanatodicyclohexyl methane with a polyol component having an average molecular weight of 90 to 400 and containing at least 50% by weight, based on the weight of the polyol component, of one or more (cyclo)aliphatic diols containing 4 to 12 carbon atoms, B) a polyol component containing at least one polyhydroxy polyacrylate having an OH number of 40 to 120 and C) an organotin catalyst for the reaction between hydroxyl groups and blocked isocyanate groups, wherein components A) and B) are present in quantities which correspond to an equivalent ratio of blocked polyisocyanate groups to hydroxyl groups of 0.5:1 to 1.2:1. The present invention also relates to the a heat-resistant substrate which is coated with this powder coating composition.
摘要:
The present invention relates to polyaddition compounds that are solid below 40.degree. C. and liquid above 125.degree. C. and contain, based on the weight of the polyaddition compounds,a) 0 to 2% by weight of free isocyanate groups (calculated as NCO; molecular weight=42),b) 3 to 16% by weight of uretdione groups (calculated as C.sub.2 N.sub.2 O.sub.2 ; molecular weight=84),c) 10 to 22% by weight of urethane groups (calculated as --NH--CO--O--; molecular weight=59).d) 0 to 20% by weight of carboxylic add ester groups (calculated as CO--O--; molecular weight=44) ande) of 0 to 25% by weight of carbonate groups (calculated as --O--CO--O--; molecular weight=60),provided that the total content of carboxylic add ester groups and carbonate groups is at least 1% by weight.The present invention also relates to a process for the preparation of these polyaddition compounds and to their use as a starting component for the manufacture of polyurethane plastics, especially as the cross-linking component in thermally cross-linkable two-component polyurethane powder coatings for heat-resistant substrates.
摘要翻译:本发明涉及固体低于40℃,液体高于125℃并含有基于加聚化合物的重量的加成化合物,a)0至2重量%的游离异氰酸酯基团(以NCO计算 ;分子量= 42),b)3至16重量%的脲二酮基团(以C 2 N 2 O 2计算;分子量= 84),c)10至22重量%的氨基甲酸酯基团(以-NH-CO-O- ;分子量= 59)。 d)0至20重量%的羧酸酯基(以CO-O-计算;分子量= 44)和e)0至25重量%的碳酸酯基团(以-O-CO-O-计算) 分子量= 60),条件是羧酸酯基和碳酸酯基的总含量为至少1重量%。 本发明还涉及一种制备这些加聚化合物的方法及其用作制备聚氨酯塑料的起始组分的用途,特别是作为用于热交联的双组分聚氨酯粉末涂料中的交联组分 耐性基材。