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    Construction comprising tie layer
    1.
    发明授权
    Construction comprising tie layer 有权
    结构包括连结层

    公开(公告)号：US08580877B2

    公开(公告)日：2013-11-12

    申请号：US12091608

    申请日：2006-10-26

    申请人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Matthew Brian Measmer ,  James Peter Stokes ,  Yoshiaki Kirino ,  Arthur Joseph Sullivan

    发明人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Matthew Brian Measmer ,  James Peter Stokes ,  Yoshiaki Kirino ,  Arthur Joseph Sullivan

    IPC分类号： C09J7/02

    CPC分类号： B60C5/14 ,  B32B7/12 ,  B32B25/08 ,  B60C1/0008 ,  Y10T152/10495 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909

    摘要： A vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers is a fluid permeation prevention layer preferably comprising: (A) at least one thermoplastic engineering component and (B) at least one elastomer component; the second layer of the two layers comprises at least one high diene rubber and the tie layer comprises a mixture of: (1) at least one halogenated isobutylene containing elastomer; (2) up to 50 weight % of at least one high diene elastomer; (3) at least one filler; (4) up to 30 weight % of at least one processing oil; (5) at least one tackifier; and (6) a curing system for the elastomers.

    摘要翻译： 一种可硫化的层状组合物，其包含至少两个层和至少一个粘结层，其中所述两层的第一层是流体防渗层，优选包含：（A）至少一种热塑性工程组分和（B）至少一种弹性体 零件; 所述两层的第二层包含至少一种高二烯橡胶，所述粘结层包含以下混合物：（1）至少一种含卤代异丁烯的弹性体; （2）至多50重量％的至少一种高二烯弹性体; （3）至少一种填料; （4）至多30重量％的至少一种加工油; （5）至少一种增粘剂; 和（6）弹性体的固化体系。

    Construction Comprising Tie Layer
    2.
    发明申请
    Construction Comprising Tie Layer 有权
    构造包含层

    公开(公告)号：US20080314492A1

    公开(公告)日：2008-12-25

    申请号：US12091608

    申请日：2006-10-26

    申请人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Matthew Brian Measmer ,  Arthur Joseph Sullivan ,  Yoshiaki Kirino ,  James Peter Stokes

    发明人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Matthew Brian Measmer ,  Arthur Joseph Sullivan ,  Yoshiaki Kirino ,  James Peter Stokes

    IPC分类号： B60C5/12 ,  B29D30/00 ,  B32B27/36 ,  B32B27/08

    CPC分类号： B60C5/14 ,  B32B7/12 ,  B32B25/08 ,  B60C1/0008 ,  Y10T152/10495 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909

    摘要： This disclosure relates to a vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises a mixture of: (1) about 50 to about 100 weight % of at least one halogenated isobutylene containing elastomer; (2) about 0 to about 50 weight % of at least one high diene elastomer; (3) about 20 to about 50 weight % of at least one filler; (4) about 0 to about 30 weight % of at least one processing oil; (5) about 1 to about 20 parts per hundred (phr) of at least one tackifier; and (6) at least about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers; wherein THE fluid permeation prevention layer preferably comprises: (A) at least 10% by weight, based on the total weight of the polymer composition, of at least one thermoplastic engineering resin component, preferably one or more nylon resins, and (B) at least 10% by weight, based on the total weight of the polymer composition, of at least one elastomer component, preferably a brominated isobutylene p-methylstyrene copolymer, and where the total amount of the component (A) and the component (B) is not less than 30% by weight based on the total weight of the polymer composition, wherein the elastomer component (B) is dispersed in a vulcanized or partially vulcanized state, as a discontinuous phase, in a matrix of the thermoplastic resin component (A) in the polymer composition.

    摘要翻译： 本公开涉及包含至少两层和至少一层粘结层的可硫化层状组合物，其中两层的第一层包含防止流体渗透的层，所述两层的第二层包含至少一种高二烯橡胶， 所述粘结层包含以下混合物：（1）约50至约100重量％的至少一种含卤代异丁烯的弹性体; （2）约0至约50重量％的至少一种高二烯弹性体; （3）约20至约50重量％的至少一种填料; （4）约0至约30重量％的至少一种加工油; （5）约1至约20份/ 100（phr）的至少一种增粘剂; 和（6）至少约0.2至约15份/ 100份橡胶（phr）的弹性体固化体系; 其中，所述流体渗透防止层优选包含：（A）至少10重量％，基于所述聚合物组合物的总重量，至少一种热塑性工程树脂组分，优选一种或多种尼龙树脂，和（B） 至少10重量％，基于聚合物组合物的总重量，至少一种弹性体组分，优选溴化异丁烯对甲基苯乙烯共聚物，并且其中组分（A）和组分（B）的总量为 不低于30重量％，其中弹性体组分（B）以硫化或部分硫化的状态作为不连续相分散在热塑性树脂组分（A）的基质中， 在聚合物组合物中。

    CONSTRUCTION COMPRISING TIE LAYER
    3.
    发明申请
    CONSTRUCTION COMPRISING TIE LAYER 审中-公开
    施工包括层层

    公开(公告)号：US20090218024A1

    公开(公告)日：2009-09-03

    申请号：US12091670

    申请日：2006-09-29

    申请人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Matthew Brian Measmer ,  Arthur Joseph Sullivan ,  Yoshiaki Kirino ,  James Peter Stokes

    发明人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Matthew Brian Measmer ,  Arthur Joseph Sullivan ,  Yoshiaki Kirino ,  James Peter Stokes

    IPC分类号： B60C5/00 ,  B32B27/08 ,  B32B27/32 ,  B32B27/06 ,  B32B1/08 ,  B29D30/08

    CPC分类号： B32B7/12 ,  B32B25/04 ,  B32B25/08 ,  B32B25/16 ,  B32B2307/724 ,  B32B2307/7265 ,  B32B2319/00 ,  B32B2377/00 ,  B32B2605/00 ,  B60C1/0008 ,  B60C1/0025 ,  B60C5/14 ,  C08L9/00 ,  C08L23/16 ,  C08L23/283 ,  C08L2312/00 ,  Y10T152/10495 ,  Y10T152/10855 ,  Y10T428/1386 ,  Y10T428/31721 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31826 ,  Y10T428/3183 ,  Y10T428/31917 ,  C08L2666/04 ,  C08L2666/06 ,  C08L2666/08 ,  C08L2666/02

    摘要： This disclosure relates to a vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises a mixture of: (1) about 50 to about 100 weight % of at least one halogenated isobutylene containing elastomer; (2) about 0 to about 50 weight % of at least one high diene elastomer; (3) about 20 to about 50 weight % of at least one filler; (4) about 0 to about 30 weight % of at least one processing oil; (5) about 1 to about 20 parts per hundred (phr) of at least one tackifier; and (6) at least about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers; wherein THE fluid permeation prevention layer preferably comprises: (A) at least 10% by weight, based on the total weight of the polymer composition, of at least one thermoplastic engineering resin component, preferably one or more nylon resins; and (B) at least 10% by weight, based on the total weight of the polymer composition, of at least one elastomer component, preferably a brominated isobutylene p-methylstyrene copolymer, and where the total amount of the component (A) and the component (B) is not less than 30% by weight based on the total weight of the polymer composition, wherein the elastomer component (B) is dispersed in a vulcanized or partially vulcanized state, as a discontinuous phase, in a matrix of the thermoplastic resin component (A) in the polymer composition.

    摘要翻译： 本公开涉及包含至少两层和至少一层粘结层的可硫化层状组合物，其中两层的第一层包含防止流体渗透的层，所述两层的第二层包含至少一种高二烯橡胶， 所述粘结层包含以下混合物：（1）约50至约100重量％的至少一种含卤代异丁烯的弹性体; （2）约0至约50重量％的至少一种高二烯弹性体; （3）约20至约50重量％的至少一种填料; （4）约0至约30重量％的至少一种加工油; （5）约1至约20份/ 100（phr）的至少一种增粘剂; 和（6）至少约0.2至约15份/ 100份橡胶（phr）的弹性体固化体系; 其中，所述流体渗透防止层优选包含：（A）至少10重量％，基于所述聚合物组合物的总重量，至少一种热塑性工程树脂组分，优选一种或多种尼龙树脂; 和（B）至少10重量％，基于聚合物组合物的总重量，至少一种弹性体组分，优选溴化异丁烯对甲基苯乙烯共聚物，并且其中组分（A）和 组分（B）基于聚合物组合物的总重量不小于30重量％，其中弹性体组分（B）作为不连续相以硫化或部分硫化的状态分散在热塑性塑料的基质中 聚合物组合物中的树脂组分（A）。

    Low permeability thermoplastic elastomer composition
    4.
    发明授权
    Low permeability thermoplastic elastomer composition 有权
    低渗透性热塑性弹性体组合物

    公开(公告)号：US08021730B2

    公开(公告)日：2011-09-20

    申请号：US12091535

    申请日：2005-10-27

    申请人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Yuichi Hara ,  Matthew Brian Measmer

    发明人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Yuichi Hara ,  Matthew Brian Measmer

    IPC分类号： C08L19/00 ,  C08L77/00 ,  B29D30/06 ,  B60C5/14

    CPC分类号： B60C1/0008 ,  B60C1/00 ,  C08L23/26 ,  C08L23/28 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L2205/02 ,  C08L2205/03 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139 ,  Y10T428/1397 ,  C08L2666/20 ,  C08L2666/06

    摘要： A thermoplastic elastomer composition possessing superior air impermeability, excellent durability and flexibility. In particular, the composition includes (A) at least one halogenated isobutylene-containing elastomer; and (B) at least one nylon resin having a melting point of about 170° C. to about 260° C.; and (C) a low molecular weight polymeric nylon plasticizer; wherein: (1) the at least one elastomer is present as a dispersed phase of small vulcanized particles in a continuous nylon phase; and (2) the elastomer particles are formed by dynamic vulcanization. Use of a low molecular weight nylon plasticizer provides for improved mixing and rubber dispersion while retaining the high levels of impermeability achievable by the use of nylon resin and halogenated isobutylene-containing elastomer in a dynamically vulcanized composition. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers as well as hoses.

    摘要翻译： 具有优异的防空气性，优异的耐久性和柔软性的热塑性弹性体组合物。 特别地，组合物包括（A）至少一种含卤代异丁烯的弹性体; 和（B）至少一种熔点为约170℃至约260℃的尼龙树脂; 和（C）低分子量聚合尼龙增塑剂; 其中：（1）所述至少一种弹性体作为连续尼龙相中的小硫化颗粒的分散相存在; 和（2）弹性体颗粒通过动态硫化形成。 使用低分子量尼龙增塑剂可提供改进的混合和橡胶分散体，同时保持在动态硫化组合物中使用尼龙树脂和含卤代异丁烯的弹性体可实现的高水平的不渗透性。 这样的组合物在诸如轮胎内衬和阻隔膜或层以及软管的应用中特别有用。

    Low Permeability Thermoplastic Elastomer Composition
    8.
    发明申请
    Low Permeability Thermoplastic Elastomer Composition 有权
    低渗透性热塑性弹性体组合物

    公开(公告)号：US20080275187A1

    公开(公告)日：2008-11-06

    申请号：US12091535

    申请日：2005-10-27

    申请人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Yuichi Hara ,  Matthew Brian Measmer

    发明人： Andy Haishung Tsou ,  Yoshihiro Soeda ,  Yuichi Hara ,  Matthew Brian Measmer

    IPC分类号： C08L77/02

    CPC分类号： B60C1/0008 ,  B60C1/00 ,  C08L23/26 ,  C08L23/28 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L2205/02 ,  C08L2205/03 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139 ,  Y10T428/1397 ,  C08L2666/20 ,  C08L2666/06

    摘要： A thermoplastic elastomer composition possessing superior air impermeability, excellent durability and flexibility. In particular, the composition includes (A) at least one halogenated isobutylene-containing elastomer; and (B) at least one nylon resin having a melting point of about 170° C. to about 260° C.; and (C) a low molecular weight polymeric nylon plasticizer; wherein: (1) the at least one elastomer is present as a dispersed phase of small vulcanized particles in a continuous nylon phase; and (2) the elastomer particles are formed by dynamic vulcanization. Use of a low molecular weight nylon plasticizer provides for improved mixing and rubber dispersion while retaining the high levels of impermeability achievable by the use of nylon resin and halogenated isobutylene-containing elastomer in a dynamically vulcanized composition. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers as well as hoses.

    摘要翻译： 具有优异的防空气性，优异的耐久性和柔软性的热塑性弹性体组合物。 特别地，组合物包括（A）至少一种含卤代异丁烯的弹性体; 和（B）至少一种熔点为约170℃至约260℃的尼龙树脂; 和（C）低分子量聚合尼龙增塑剂; 其中：（1）所述至少一种弹性体作为连续尼龙相中的小硫化颗粒的分散相存在; 和（2）弹性体颗粒通过动态硫化形成。 使用低分子量尼龙增塑剂可提供改进的混合和橡胶分散体，同时保持在动态硫化组合物中使用尼龙树脂和含卤代异丁烯的弹性体可实现的高水平的不渗透性。 这样的组合物在诸如轮胎内衬和阻隔膜或层以及软管的应用中特别有用。