摘要:
A resin composition obtained by blending a thermoplastic resin that can be melt-extruded at a solubility parameter of not smaller than 9.5 with an organic oxidizing component and with a transition metal catalyst, the organic oxidizing component being a polyene having a functional group on a side chain or at a terminal thereof. The resin composition has excellent moldability and gas shut-off property. A multi-layer container having an oxygen-absorbing layer of this resin composition exhibits excellent gas-barrier property and is capable of favorably preserving the content.
摘要:
A packaging material having an oxygen-absorbing layer of a thermoplastic resin which is blended with an organic oxidizing component and with a transition metal catalyst, wherein the thermoplastic resin is not substantially oxidized in the presence of the transition metal catalyst. The thermoplastic resin is not deteriorated by oxidation and, hence, oxygen-barrier property is not deteriorated, making it possible to stably suppress the permeation of oxygen over extended periods of time.
摘要:
A multi-layer structure for packaging formed by at least an inner layer, an outer layer and an intermediate layer, the intermediate layer having an islands-in-a-sea structure comprising a resin A constituting sea portions and a functional resin B constituting island portions, the sea portions occupying not more than 80% of the area of the intermediate layer in cross section, and the inner layer and the outer layer being resins having adhesiveness to said resin A. The adhesion among the layers is improved without providing any particular adhesive layers among the intermediate layer having a function such as gas barrier property and the inner and outer layers, and, besides, transparency is improved.
摘要:
A packing container having oxygen absorbing layers comprising a base material resin component (component A) and an oxygen absorbing functional component (component B), the oxygen absorbing layers having an islands-in-the-sea structure in which the base material resin component (component A) is forming a sea portion and the oxygen absorbing functional component (component B) is forming island portions, wherein the ratio (N/M). of the whole surface area (N cm2) of the island portions of the oxygen absorbing functional component (component B) in the oxygen absorbing layers to the volume (M cm3) of the packing container is not smaller than 20 (cm−1). The packing container exhibits excellent gas barrier property and oxygen absorbing property from the beginning of filling the content and continuously works to lower the initial concentration of oxygen in the content from the beginning of filling.
摘要翻译:具有氧吸收层的包装容器包括基材树脂组分(组分A)和氧吸收功能组分(组分B),氧吸收层具有海岛结构,其中基材树脂组分 组分A)形成海水部分,氧吸收功能组分(组分B)形成岛部分,其中比例(N / M)。 氧吸收层中氧吸收功能组分(组分B)的岛部分的整个表面积(N cm 2)的体积(M cm 3) )不小于20(cm -1)以上。 包装容器从填充内容开始时显示出优异的阻气性和氧吸收性,并且连续地起作用以从填充开始降低含量中的氧初始浓度。
摘要:
A multi-layer structure for packaging formed by at least an inner layer, an outer layer and an intermediate layer, the intermediate layer having an islands-in-a-sea structure comprising a resin A constituting sea portions and a functional resin B constituting island portions, the sea portions occupying not more than 80% of the area of the intermediate layer in cross section, and the inner layer and the outer layer being resins having adhesiveness to said resin A. The adhesion among the layers is improved without providing any particular adhesive layers among the intermediate layer having a function such as gas barrier property and the inner and outer layers, and, besides, transparency is improved.
摘要:
A preform, a method of producing the preform, and a container obtained by draw-forming the preform. The preform has at least a layer of a polyester resin and is formed by the compression-forming, wherein the time is not shorter than 300 seconds before a calorific value of isothermal crystallization of the layer of the polyester resin at 210° C. reaches a maximum value. The preform is provided suppressing the thermal decomposition of the resin at the time of forming the preform, and effectively suppressing a drop in the inherent viscosity and the formation of the acetaldehyde. Further, a biaxially drawn container is provided having excellent mechanical strength and flavor-retaining property.
摘要:
A polyester resin for compression molding comprising chiefly ethylene terephthalate units and having an inherent viscosity in a range of 0.6 to 1.3 dL/g, containing a diethylene glycol in an amount of smaller than 2.3 mol %, and containing a monohydroxyethyl terephthalate and a bishydroxyethyl terephthalate in a total amount of not larger than 0.005% by weight. A mass of a molten resin which is the polyester resin can be fed to a compression-molding apparatus maintaining stability for extended periods of time, featuring excellent properties for being conveyed and for enhancing the productivity.
摘要:
A preform, a method of producing the preform, and a container obtained by draw-forming the preform. The preform has at least a layer of a polyester resin and is formed by the compression-forming, wherein the time is not shorter than 300 seconds before a calorific value of isothermal crystallization of the layer of the polyester resin at 210° C. reaches a maximum value. The preform is provided suppressing the thermal decomposition of the resin at the time of forming the preform, and effectively suppressing a drop in the inherent viscosity and the formation of the acetaldehyde. Further, a biaxially drawn container is provided having excellent mechanical strength and flavor-retaining property.
摘要:
A polyester resin suitably used for forming preforms by compression forming, the polyester resin having an intrinsic viscosity of 0.70 to 1.00 dL/g and, a molecular weight distribution (Mz/Mn) of not smaller than 3.0, and a diethylene glycol content of not larger than 2.3 mol %. The polyester resin is effectively prevented from depositing on conveyer means of the synthetic resin feeding device, the timing of falling the molten resin mass onto the compression forming mold is not deviated and, besides, the resin can be extruded in an increased amount from the extruder without accompanied by an excess increase in the torque of the extruder. Therefore, the preforms can be formed by compression forming maintaining good productivity. Besides, since the resin has a high degree of fluidity, the preforms that are the formed articles are free of wrinkles, shade or forming distortion, featuring good formability.
摘要:
A preform having at least a layer of a polyester resin, formed by the compression forming and having a neck ring at the mouth portion, wherein a temperature difference ΔTc at the center of the bottom of the polyester layer or under the neck ring represented by the following formula (1), ΔTc=Tc2−Tc1 (1) wherein Tc1 is a temperature-elevating peak crystallization temperature of the polyester layer cut out from the preform as measured by using a differential scanning calorimeter (DSC), and Tc2 is a temperature-elevating peak crystallization temperature of the polyester layer measured by quickly cooling it after having measured Tc1 and having melted it, is not larger than 15° C. The preform has a small forming distortion and features excellent dimensional stability at the time of crystallizing the mouth portion. The article formed by draw blow-forming the preform of the invention is without irregularity in the thickness, without scars or wrinkles, and distored little, exhibits excellent appearance.