公开(公告)号：US10689468B2

公开(公告)日：2020-06-23

申请号：US15532355

申请日：2015-11-20

申请人： BASF Coatings GmbH

发明人： Andreas Poppe ,  Norbert Loew ,  Cathrin Corten ,  Britta Schnieders ,  Wei Qiu Hu

IPC分类号： C08F220/14 ,  C09D143/04 ,  C09D133/06 ,  B05D7/00 ,  C09D5/00 ,  C09D133/12 ,  C09D167/02

摘要： The present invention relates to a copolymer (A) having a glass transition temperature Tg of at least −30° C. obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent and in the presence of at least one initiator, where the mixture of monomers (a) to be polymerized comprises (a1) 10 to 60 mol % of at least one monomer of the formula (I) below where R1=C1 to C4 alkoxy, R2=C1 to C4 alkyl, and m=0 to 2, and (a2) 40 to 90 mol % of at least one olefinically unsaturated monomer selected from the group consisting of monomers of the formulae H2C═CH2—(C═O)—O—Rx, H2C═CH(CH3)—(C═O)—O—Rx, and H2C═CH2—O—(C═O)—Rx, where Rx is an alkyl radical having 1 to 20 carbon atoms, and where the sum total of the molar fractions of the monomers (a1) and (a2), based on the total molar amount of monomers (a) used, is at least 90 mol %, and where the copolymerization is carried out at a temperature from 60 to 200° C. and at a pressure of at least 2 bar.

公开(公告)号：US09932483B2

公开(公告)日：2018-04-03

申请号：US15104771

申请日：2014-12-17

申请人： BASF Coatings GmbH

发明人： Audree Andersen ,  Cathrin Corten ,  Manuela Niemeier ,  Frederik Foelling ,  Simone Hesener ,  Nicole Freitag ,  Stefanie Boshe-Plois

IPC分类号： B05D7/14 ,  B05D7/16 ,  C09D167/06 ,  C09D175/06 ,  C08K5/5425 ,  C08G18/68 ,  C08G63/52 ,  C09D5/00 ,  B05D7/00 ,  C08G63/695 ,  C08G63/91 ,  C08G18/62 ,  C08G18/71 ,  C09D175/04 ,  C08L67/06

CPC分类号： C09D5/002 ,  B05D7/14 ,  B05D7/542 ,  B05D7/544 ,  B05D7/546 ,  C08G18/6225 ,  C08G18/68 ,  C08G18/718 ,  C08G63/52 ,  C08G63/6958 ,  C08G63/918 ,  C08K5/5425 ,  C09D167/06 ,  C09D175/04 ,  C08L75/06 ,  C08L67/06

摘要： The present invention relates to a solventborne primer surfacer which comprises at least one additive preparable by reacting at least one alpha,omega-hydroxy-functionalized oligoester which possesses an OH number of 30 to 160 mg KOH/g, a theoretical carbon-carbon double bond content of 1 to 2.5 mmol/g, a number-average molecular weight of 1000 to 3000 g/mol, and a weight-average molecular weight of 2800 to 10 000 g/mol, and at least one alkoxysilane which possesses an OH-reactive functional group, the sum of the weight percentage fractions of all additives of the invention being 0.5 to 10 wt %, based on the total amount of the solventborne primer surfacer. The present invention further relates to a process for producing multicoat paint systems, and to multicoat paint systems producible by means of said process. The invention further relates to the use of the additive identified above in solventborne primer surfacers for improving adhesion.

公开(公告)号：US20210205845A1

公开(公告)日：2021-07-08

申请号：US15999593

申请日：2016-02-19

申请人： BASF Coatings GmbH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Patrick Wilm ,  Klaus-Juergen Kanngiesser ,  Joerg Schwarz

IPC分类号： B05D7/00 ,  B05D1/00 ,  B05D7/14 ,  C09D5/44

摘要： A method is disclosed for producing a multicoat paint system on a metallic substrate by producing a basecoat or a plurality of directly successive basecoats directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat. At least one basecoat material used for producing the basecoats includes at least one predispersed mixture including at least one polyamide having an acid number of less than 20 mg KOH/g, at least one polymeric resin different from the polyamide, and also water and at least one organic solvent.

公开(公告)号：US20190085116A1

公开(公告)日：2019-03-21

申请号：US16081293

申请日：2017-02-23

申请人： BASF Coatings GmbH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Britta Schnieders ,  Nicole Freitag ,  Heinz-Ulrich Grumpe ,  Mechthild Vienenkoetter ,  Ralf Nickolaus

IPC分类号： C08G18/42 ,  C08G18/66 ,  C08G18/76 ,  B05D7/00 ,  B05D7/14

摘要： Described herein are aqueous dispersions including multistage-prepared polymers of olefinically unsaturated compounds and to the preparation and use thereof, in particular in the field of automobile coating.

公开(公告)号：US10160872B2

公开(公告)日：2018-12-25

申请号：US15505477

申请日：2015-08-21

申请人： BASF Coatings GmbH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Patrick Wilm ,  Joerg Schwarz ,  Stefanie Boshe-Plois ,  Susanne Katharina Fechtner ,  Ralf Nickolaus

IPC分类号： C09D167/08 ,  C09D177/00 ,  C09D7/44 ,  C09D5/02 ,  C09D177/08 ,  C09D7/65 ,  C09D7/20 ,  C08L67/00 ,  C09D133/10 ,  C09D167/00 ,  C09D175/04 ,  C08L77/00

摘要： The present invention relates to an aqueous dispersion (P) comprising at least one polymeric resin (P1) and at least one polymeric resin (P2) different therefrom, where the polymeric resin (P1) is a polyamide and the polymeric resin (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24 monocarboxylic acid with at least one diol and/or polyol, (P) being obtainable by dispersing of (P1) in water or an aqueous medium in the presence of (P2), and where (P1) has an acid number

公开(公告)号：US10160871B2

公开(公告)日：2018-12-25

申请号：US15505449

申请日：2015-08-21

申请人： BASF Coatings GmbH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Patrick Wilm ,  Joerg Schwarz ,  Susanne Katharina Fechtner

IPC分类号： C09D167/08 ,  C09D177/00 ,  C09D7/44 ,  C09D5/03 ,  C09D7/65 ,  C09D7/20 ,  C09D133/10 ,  C09D167/00 ,  C09D175/04 ,  C08L77/00 ,  C08L67/00

摘要： The present invention relates to an aqueous coating composition comprising at least one mixture (M) of at least one polymeric resin (P1) and at least one polymeric resin (P2), different therefrom, where (P1) is a polyamide and (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24-monocarboxylic acid with at least one diol and/or polyol, at least one binder (A) comprising at least one polymeric resin (A1), which is different from the polymeric resins (P1) and (P2), at least one pigment (B), where the polyamide used as polymeric resin (P1) has an acid number

公开(公告)号：US10907069B2

公开(公告)日：2021-02-02

申请号：US16319096

申请日：2017-07-20

申请人： BASF Coatings GMBH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Britta Schnieders ,  Nicole Freitag ,  Josef Rademacher ,  Michael Grabbe

IPC分类号： C09D175/14 ,  C09D7/43 ,  C08K3/013 ,  C08F2/00 ,  C08F2/22 ,  C08F212/08 ,  C08F220/06 ,  C08F220/14 ,  C08F257/02 ,  C08G18/08 ,  C08G18/12 ,  C08G18/28 ,  C08G18/32 ,  C08G18/42 ,  C08G18/48 ,  C08G18/67 ,  C08G18/75 ,  C08K5/05 ,  C08F220/18

摘要： Provided herein is a mixer system for producing refinish compositions, more particularly for the sector of automotive finishing, including at least mutually different components (1), (2), and (3), namely component (1) as base varnish, component (2) as tinting base, and component (3) as rheology module, with at least one of components (1) to (3) including at least one aqueous dispersion including at least one polymer prepared by multistage emulsion polymerization, and at least one of components (1) to (3) including at least one aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms. Further provided herein is an aqueous refinish composition that is produced by the mixing of components (1) to (3), and a method for producing aqueous refinish compositions. Further provided herein is a use of the mixer system for producing aqueous refinish compositions for automotive refinishing.

公开(公告)号：US10577505B2

公开(公告)日：2020-03-03

申请号：US15545019

申请日：2016-01-08

申请人： BASF Coatings GmbH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Britta Schnieders ,  Nicole Freitag ,  Heinz-Ulrich Grumpe ,  Elisabeth Wessling ,  Joerg Schwarz ,  Mechthild Vienenkoetter ,  Patrick Wilm

IPC分类号： C08F2/48 ,  C08F2/46 ,  C09D5/02 ,  C09D7/40 ,  B05D3/02 ,  B05D7/00 ,  C09D133/08

摘要： The invention relates to aqueous dispersions comprising multistage-prepared polymers, and also to coating material compositions comprising them, preparable by multistage polymerization of olefinically unsaturated monomers, using an emulsifier and a water-soluble initiator, under conditions of starved feed polymerization, and using particular monomer mixtures in the individual stages.The invention also relates to a pigmented aqueous basecoat material comprising the aqueous dispersion of the invention, to the use of the aqueous dispersion of the invention in aqueous basecoat materials for improving adhesion, to a process for producing a multicoat paint system on a substrate, and to a multicoat paint system produced in accordance with the stated process.

公开(公告)号：US20190062588A1

公开(公告)日：2019-02-28

申请号：US15779168

申请日：2016-06-03

申请人： BASF COATINGS GMBH

发明人： Cathrin Corten ,  Dirk Eierhoff ,  Patrick Wilm ,  Britta Schnieders ,  Nicole Freitag ,  Heinz-Ulrich Grumpe ,  Joerg Schwarz

IPC分类号： C09D153/00 ,  C09D5/00 ,  B05D7/00 ,  B05D7/14 ,  C25D13/04 ,  C25D13/22

摘要： Provided herein is a method for producing a multicoat paint system on a metallic substrate by producing a basecoat or a plurality of directly successive basecoats directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat, wherein at least one basecoat material used for producing the basecoats includes at least one aqueous dispersion which includes a polymer whose preparation includes successive radical emulsion polymerization of three mixtures of olefinically unsaturated monomers.

公开(公告)号：US09920215B2

公开(公告)日：2018-03-20

申请号：US14917722

申请日：2014-08-08

申请人： BASF Coatings GmbH

发明人： Reinhold Clauss ,  Rainer Klopsch ,  Susanne Katharina Kreth ,  Britta Schnieders ,  Ursula Heimeier ,  Cathrin Corten ,  Peter Hoffmann ,  Aaron Flores-Figueroa ,  Kristin Michel ,  Annika Werning

IPC分类号： B32B27/30 ,  C09D133/14 ,  C09D167/02

CPC分类号： C09D133/14 ,  C09D167/02 ,  C08L101/06 ,  C09D133/066

摘要： A nonaqueous coating material composition and coatings thereof are provided. The composition contains an oligomeric and/or polymeric compound (A) having at least two hydroxyl groups, an oligomeric and/or polymeric compound (B) having at least two alkylidene-1,3-dioxolan-2-one groups of formula (I′), and a catalyst (D) where # stands for the attachment to the polymer backbone and R1, R2 independently of one another are hydrogen, C1-C6 alkyl, C1-C4 alkoxy-C1-C4 alkyl, C5-C6 cycloalkyl, phenyl or phenyl-C1-C4 alkyl; R3 is hydrogen, C1-C6 alkyl, C1-C4 alkoxy-C1-C4 alkyl, C5-C6 cycloalkyl, phenyl, or phenyl-C1-C4 alkyl; A is a chemical bond or C1-C4 alkanediyl; X is O or NR7; Z is a chemical bond, PO2, SO2, or C═O, Y is a chemical bond, CH2, or CHCH3, and R7 where present is C1-C6 alkyl.