公开(公告)号：US11904290B2

公开(公告)日：2024-02-20

申请号：US17265623

申请日：2019-08-05

申请人： BASF SE

发明人： Grigorios Kolios ,  Bernd Zoels ,  Hagen Appel ,  Jens Bernnat ,  Friedrich Glenk ,  Dieter Flick ,  Gerhard Olbert ,  Frederik Scheiff ,  Christopher Alec Anderlohr

IPC分类号： B01J19/24 ,  C01B32/05 ,  B01J3/00 ,  B01J3/04 ,  B01J6/00 ,  C01B3/26 ,  C04B35/80 ,  C04B35/14 ,  C04B35/18

CPC分类号： B01J19/24 ,  B01J3/002 ,  B01J3/048 ,  B01J6/008 ,  C01B3/26 ,  C01B32/05 ,  C04B35/14 ,  C04B35/18 ,  C04B35/80 ,  C04B2235/522 ,  C04B38/10 ,  C04B35/18 ,  C04B38/0061

摘要： An apparatus contains at least one pressure-rated apparatus shell and at least one modular framework system containing ceramic fiber composite materials and arranged within the apparatus shell. A modular lining apparatus includes the modular framework system and refractory bricks. The apparatus can be used for high-temperature reactors, especially electrically heated high-temperature reactors.

公开(公告)号：US20230010059A1

公开(公告)日：2023-01-12

申请号：US17757084

申请日：2020-11-30

申请人： BASF SE

发明人： Frederik SCHEIFF ,  Dieter Flick ,  Lothar Seidemann ,  Jens Bernnat ,  Grigorios Kolios

IPC分类号： B01J6/00 ,  B01J19/08 ,  B01J19/28 ,  B01J8/08 ,  B01J8/10 ,  B01J8/12 ,  C10G9/24

摘要： A process can be used for performing a pyrolysis of hydrocarbons in a rotary drum reactor at a temperature in the range of from 600 to 1800° C. The heat for the endothermic pyrolysis is provided by resistive heating of at least one particulate electrically conductive material introduced into said rotary drum reactor and moved through the rotary drum reactor with a flow of a hydrocarbon. The rotary drum reactor contains (A) an inner wall made of electrically insulated material, (B) a pressure-bearing outer wall, and (C) an electrical heating system attached to the inner wall and/or at least one integrated electrically conducting electrode pair. The at least one electrode pair is located at both ends of the inner wall of the rotary drum.

公开(公告)号：US20220387954A1

公开(公告)日：2022-12-08

申请号：US17755333

申请日：2020-10-20

申请人： BASF SE ,  thyssenkrupp AG ,  thyssenkrupp Industrial Solutions AG

发明人： Grigorios Kolios ,  Frederik Scheiff ,  Christopher Alec Anderlohr ,  Hagen Appel ,  Gerhard Olbert ,  Bernd Zoels ,  Dieter Flick ,  Achim Wechsung ,  Matthias Kern ,  Karsten Bueker ,  Nicolai Antweiler

IPC分类号： B01J8/12 ,  B01J8/00 ,  C01B3/30

摘要： A method can be used for operating a descending moving bed reactor with flowable granular material. The method involves: (i) filling an upper lock-hopper with granular material and/or emptying a lower lock-hopper, (ii) purging the lock-hoppers with purging gas, and (iii) filling the reaction chamber containing a descending moving bed from the upper lock-hopper and/or emptying the reaction chamber into the lower lock-hopper. The pressure equalization between the reaction chamber and lock-hopper is achieved with product gas. The method then involves: (iv) optionally, relieving the lock-hoppers and conveying the product gas flow into the product line, and (v) purging the lock-hoppers with purging gas.

公开(公告)号：US20210162359A1

公开(公告)日：2021-06-03

申请号：US17265623

申请日：2019-08-05

申请人： BASF SE

发明人： Grigorios Kolios ,  Bernd Zoels ,  Hagen Appel ,  Jens Bernnat ,  Friedrich Glenk ,  Dieter Flick ,  Gerhard Olbert ,  Frederik Scheiff ,  Christopher Alec Anderlohr

IPC分类号： B01J3/04 ,  B01J3/00 ,  B01J6/00 ,  C04B35/80 ,  C01B3/26 ,  C01B32/05

摘要： An apparatus contains at least one pressure-rated apparatus shell and at least one modular framework system containing ceramic fiber composite materials and arranged within the apparatus shell. A modular lining apparatus includes the modular framework system and. refractory bricks. The apparatus can be used for high-temperature reactors, especially electrically heated high-temperature reactors.

公开(公告)号：US09834440B2

公开(公告)日：2017-12-05

申请号：US14652346

申请日：2013-12-17

申请人： BASF SE

发明人： Matthias Kern ,  Friedrich Glenk ,  Dirk Klingler ,  Andreas Bode ,  Grigorios Kolios ,  Stephan Schunk ,  Guido Wasserschaff ,  Jens Bernnat ,  Bernd Zoels ,  Sabine Schmidt ,  Rene Koenig

IPC分类号： C01B3/24 ,  C01B31/00 ,  C01B31/18 ,  C01B3/38 ,  C10K3/02 ,  C10J3/06

CPC分类号： C01B3/24 ,  C01B3/38 ,  C01B32/40 ,  C01B2203/0238 ,  C01B2203/0272 ,  C01B2203/0283 ,  C01B2203/1235 ,  C10J3/06 ,  C10K3/026 ,  Y02P20/129 ,  Y02P20/146

摘要： The invention relates to a process for the parallel preparation of hydrogen, carbon monoxide and a carbon-comprising product, wherein one or more hydrocarbons are thermally decomposed and at least part of the pyrolysis gas formed is taken off from the reaction zone of the decomposition reactor at a temperature of from 800 to 1400° C. and reacted with carbon dioxide to form a gas mixture comprising carbon monoxide and hydrogen (synthesis gas).

公开(公告)号：US20220352721A1

公开(公告)日：2022-11-03

申请号：US17596030

申请日：2020-05-28

申请人： BASF SE ,  thyssenkrupp AG ,  thyssenkrupp Industrial Solutions AG

发明人： Frederik SCHEIFF ,  Grigorios Kolios ,  Andreas Bode

IPC分类号： H02J3/38 ,  H02J15/00 ,  H02J3/28 ,  C01B3/24

摘要： A method of continuously performing one or more heat-consuming processes, where at least one heat-consuming process is electrically heated. The maximum temperature in the reaction zone of the heat-consuming process is higher than 500° C., at least 70% of products of the heat-consuming process are continuously processed further downstream and/or fed to a local energy carrier network, and the electrical energy required for the heat-consuming process is drawn from an external power grid and from at least one local power source. The local power source is fed by at least one local energy carrier network and by products from the heat-consuming process. The local energy carrier network stores natural gas, naphtha, hydrogen, synthesis gas, and/or steam as energy carrier, and has a total capacity of at least 5 GWh. The local energy carrier network is fed with at least one further product and/or by-product from at least one further chemical process.

公开(公告)号：US20220228280A1

公开(公告)日：2022-07-21

申请号：US17596000

申请日：2020-05-28

申请人： BASF SE ,  thyssenkrupp AG ,  thyssenkrupp Industrial Solutions AG

发明人： Frederik Scheiff ,  Marc Leduc ,  Grigorios Kolios ,  William Daloz ,  Karsten Bueker ,  Nicolai Antweiler ,  Andreas Bode

IPC分类号： C25C7/02 ,  C01B3/24 ,  C01B32/05 ,  C25C3/06 ,  C25C3/12

摘要： An integrated process contains the following steps of: (i) pyrolysis of hydrocarbons to carbon and hydrogen, (iia) removal of at least a part of the produced carbon in step (i) and at least partly further processing of said carbon into a carbon containing electrode, and (iib) removal of the hydrogen produced in step (i) and at least partly using said hydrogen for providing energy, preferably electric energy or heat, for the electrode production in step (iia). A joint plant is also useful, which contains (a) at least one reactor for a pyrolysis process, (b) at least one reactor for the production of electrodes for an aluminum process, (c) a power plant and/or at least one gas-fired burner, and optionally, (d) at least one reactor for the electrolysis for producing aluminum.

公开(公告)号：US10351422B2

公开(公告)日：2019-07-16

申请号：US14651862

申请日：2013-12-12

申请人： BASF SE ,  LINDE AG

发明人： Otto Machhammer ,  Wolfgang Alois Hormuth ,  Christian Schneider ,  Andreas Bode ,  Volker Goeke ,  Hans-Juergen Maass ,  Matthias Kern ,  Dirk Klingler ,  Rene Koenig ,  Philipp Brueggemann ,  Jens Bernnat ,  Grigorios Kolios

IPC分类号： C01B3/28 ,  B01J19/00 ,  B01J8/00

摘要： The invention relates to a method of carrying out heat-consuming processes, wherein the total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required, and three different energy modes can individually provide the total power required for the heat-consuming process: (i) exclusively electric energy, (ii) a mixture of electric energy and at least one further nonelectric energy source or (iii) exclusively nonelectric energy, where the changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes.

公开(公告)号：US11882629B2

公开(公告)日：2024-01-23

申请号：US16964472

申请日：2019-01-22

申请人： BASF SE

发明人： Hagen Appel ,  Jens Bernnat ,  Friedrich Glenk ,  Grigorios Kolios ,  Gerhard Olbert ,  Frederik Scheiff ,  Bernd Zoels ,  Matthias Kern ,  Dieter Flick ,  Christopher Alec Anderlohr ,  Dirk Klingler ,  Achim Wechsung

IPC分类号： B01J8/24 ,  H05B3/00 ,  H05B3/60 ,  C01B3/26 ,  C01B3/30

CPC分类号： H05B3/0004 ,  B01J8/24 ,  C01B3/26 ,  C01B3/30 ,  H05B3/60 ,  B01J2208/00176

摘要： The present invention relates to an electrically heatable packed pressure-bearing apparatus for conducting endothermic reactions having an upper (3), middle (1) and lower (3) apparatus section, where at least one pair of electrodes (4, 5) in a vertical arrangement is installed in the middle section (1) and all electrodes are disposed in an electrically conductive solid-state packing (26), the upper and lower apparatus sections have a specific conductivity of 105 S/m to 108 S/m, and the middle apparatus section is electrically insulated against the solid-state packing, wherein the upper and lower apparatus sections are electrically insulated from the middle apparatus section, the upper electrode is connected via the upper apparatus section and the lower electrodes via the lower apparatus section or the electrodes are each connected via one or more connecting elements (10, 16) that are in electrical contact with these sections and the ratio of the cross-sectional areas of the upper and lower electrode to the cross-sectional area of the respective current-conducting connecting element or, without use of a connecting element, the ratio of the cross-sectional area of the upper and lower electrode to the cross-sectional area of the respective current-conducting apparatus section is 0.1 to 10.

公开(公告)号：US11691115B2

公开(公告)日：2023-07-04

申请号：US16346672

申请日：2017-10-26

申请人： BASF SE

发明人： Grigorios Kolios ,  Bernd Zoels ,  Matthias Kern ,  Jens Bernnat ,  Rene Koenig ,  Friedrich Glenk ,  Achim Wechsung

IPC分类号： B01J8/04 ,  B01J38/32 ,  C01B3/56 ,  C01B32/05 ,  C01B3/04 ,  C01B3/26 ,  C01B3/38 ,  C01B13/02 ,  C04B2/10 ,  C07C5/333

CPC分类号： B01J8/04 ,  B01J8/0492 ,  B01J8/0496 ,  B01J38/32 ,  C01B3/045 ,  C01B3/26 ,  C01B3/38 ,  C01B13/0207 ,  C01B32/05 ,  C04B2/108 ,  C07C5/3337 ,  B01J2208/00522 ,  B01J2219/0004 ,  C01B3/56 ,  C01B2203/043

摘要： The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.