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    Molybdenum sulfide/carbide catalysts
    3.
    发明授权
    Molybdenum sulfide/carbide catalysts 有权
    钼硫化物/碳化物催化剂

    公开(公告)号：US07223713B2

    公开(公告)日：2007-05-29

    申请号：US10819893

    申请日：2004-04-07

    申请人： Gabriel Alonso ,  Russell R. Chianelli ,  Sergio Fuentes ,  Brenda Torres

    发明人： Gabriel Alonso ,  Russell R. Chianelli ,  Sergio Fuentes ,  Brenda Torres

    IPC分类号： B01J27/22 ,  B01J27/24

    CPC分类号： B01J37/10 ,  B01J27/051 ,  B01J27/0515 ,  B01J27/20 ,  B01J35/1019 ,  B01J37/0201 ,  C01G39/06 ,  C01P2006/12

    摘要： The present invention provides methods of synthesizing molybdenum disulfide (MoS2) and carbon-containing molybdenum disulfide (MoS2-xCx) catalysts that exhibit improved catalytic activity for hydrotreating reactions involving hydrodesulfurization, hydrodenitrogenation, and hydrogenation. The present invention also concerns the resulting catalysts. Furthermore, the invention concerns the promotion of these catalysts with Co, Ni, Fe, and/or Ru sulfides to create catalysts with greater activity, for hydrotreating reactions, than conventional catalysts such as cobalt molybdate on alumina support.

    摘要翻译： 本发明提供了合成二硫化钼（MoS 2 H 2）和含碳二硫化钼（MoS 2-x C x X）催化剂的方法，其中 对加氢脱硫，加氢脱氮和氢化的加氢处理反应表现出改善的催化活性。 本发明还涉及所得的催化剂。 此外，本发明涉及使用Co，Ni，Fe和/或Ru硫化物促进这些催化剂，以产生比常规催化剂（例如氧化铝载体上的钼酸钴）具有更大活性的催化剂，用于加氢处理反应。

    Catalytic process for hydroconversion of solid carbonaceous materials
    6.
    发明授权
    Catalytic process for hydroconversion of solid carbonaceous materials 失效
    固体碳质材料加氢转化催化工艺

    公开(公告)号：US4604183A

    公开(公告)日：1986-08-05

    申请号：US741993

    申请日：1985-06-06

    申请人： Edward H. Edelson ,  Edward I. Stiefel ,  Russell R. Chianelli ,  Catherine L. Coyle

    发明人： Edward H. Edelson ,  Edward I. Stiefel ,  Russell R. Chianelli ,  Catherine L. Coyle

    IPC分类号： C10G1/08 ,  C10G1/00

    CPC分类号： C10G1/086

    摘要： An improved hydroconversion process for carbonaceous materials wherein an ammonium or hydrocarbyl substituted ammonium salt of a metal-sulfur analog of cubane having an anion with a core structure of M.sub.4 S.sub.4 is used as a catalyst precursor. In the general formula, M may be the same or a different metal having hydrogenation catalytic activity when used as a sulfide and capable of occupying one or more vertices in a cubane structure. The metal may also have the capability of bridging one or more such structures. The improved process is effective for both normally solid and normally liquid carbonaceous materials and for carbonaceous materials which are either solid or liquid at the conversion conditions. The hydroconversion will be accomplished at a temperature within the range from about 500.degree. to about 900.degree. F., at a total pressure within the range from about 500 to about 7000 psig and at a hydrogen partial pressure within the range from about 400 to about 5000 psig.

    摘要翻译： 用于含碳材料的改进的加氢转化方法，其中使用具有核心结构为M4S4的阴离子的立方烷金属 - 硫类似物的铵或烃基取代的铵盐作为催化剂前体。 在通式中，当用作硫化物并且能够占据立方体结构中的一个或多个顶点时，M可以是相同或不同的具有氢化催化活性的金属。 金属也可以具有桥接一个或多个这样的结构的能力。 改进的方法对于常规固体和常规含碳材料以及在转化条件下为固体或液体的碳质材料都是有效的。 加氢转化将在约500至约900°F范围内的温度下进行，总压力范围为约500至约7000psig，氢分压为约400至约 5000 psig

    Method of preparing chalocogenides of group VIII by low temperature precipitation from nonaqueous solution, the products produced by said method and their use as catalysts
    7.
    发明授权
    Method of preparing chalocogenides of group VIII by low temperature precipitation from nonaqueous solution, the products produced by said method and their use as catalysts 失效
    通过从非水溶液中低温沉淀制备Ⅷ族致化子的方法，所述方法生产的产物及其用作催化剂

    公开(公告)号：US4390514A

    公开(公告)日：1983-06-28

    申请号：US206053

    申请日：1980-11-12

    申请人： Russell R. Chianelli ,  Theresa A. Pecoraro

    发明人： Russell R. Chianelli ,  Theresa A. Pecoraro

    IPC分类号： B01J27/045 ,  B01J27/057 ,  C01B17/20 ,  C01B19/00 ,  C01G55/00 ,  C01G1/12

    CPC分类号： B82Y30/00 ,  B01J27/045 ,  B01J27/0573 ,  B01J27/0576 ,  C01B17/20 ,  C01B19/007 ,  C01G55/00 ,  C01P2002/02 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/80 ,  Y10S505/81 ,  Y10S505/815

    摘要： A method is described for the preparation of chalcogenides of ruthenium, rhodium, osmium and iridium transition metals of the Periodic Table of the Elements which comprises mixing in the absence of an aqueous solvent a Group VIII transition metal salt with a source of chalcognide, said chalcogenide being selected from the group consisting of sulfur, selenium, tellurium and mixtures thereof, yielding a precipitate of the formula MX.sub.y wherein M is selected from the group consisting of ruthenium, rhodium, and osmium and iridium, X is sulfur, selenium, tellurium and mixtures thereof and y is a number ranging from about 0.1 to about 3, preferably 0.1 to about 2.5. By the practice of the nonaqueous synthesis technique, Group VIII chalcogenides are prepared which are finely divided, have a high surface area, small particle size and small crystallite size which are also free of excess sulfur, water and/or hydrolysis products. Layered stoichiometric osmium disulfide is prepared by this technique. The precipitates may be cleaned of any anion salt coproduct by any technique common to the art.Compounds of the formula MX.sub.y thus prepared are superior sulfur-tolerant catalysts in catalytic processes, for example, hydrodesulfurization, hydrodenitrogenation, hydroconversion, hydrogenation.

    摘要翻译： 描述了用于制备元素周期表的钌，铑，锇和铱过渡金属的硫族化物的方法，该方法包括在不含水溶剂的情况下混合第VIII族过渡金属盐与硫族化合物源，所述硫族化物 选自硫，硒，碲及其混合物，得到式MXy的沉淀物，其中M选自钌，铑，锇和铱，X是硫，硒，碲和混合物 并且y是约0.1至约3，优选0.1至约2.5的数。 通过非水合成技术的实践，制备了细分的，具有高表面积，小颗粒尺寸和小微晶尺寸的第VIII族硫属化物，其也不含过量的硫，水和/或水解产物。 通过该技术制备分层化学计量的二硫化锇。 通过本领域普通技术可以将沉淀物清除任何阴离子盐副产物。 如此制备的式MXy的化合物是催化方法中优异的耐硫催化剂，例如加氢脱硫，加氢脱氮，加氢转化，氢化。

    Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts
    8.
    发明授权
    Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts 失效
    通过从水溶液中低温沉淀制备第Ⅷ族硫族化物的方法，所述方法生产的产物及其用作催化剂

    公开(公告)号：US4288422A

    公开(公告)日：1981-09-08

    申请号：US160106

    申请日：1980-06-16

    申请人： Russell R. Chianelli ,  Theresa A. Pecoraro

    发明人： Russell R. Chianelli ,  Theresa A. Pecoraro

    IPC分类号： B01J27/045 ,  B01J27/057 ,  C01B19/04 ,  C01G55/00 ,  C01G3/12

    CPC分类号： C01B19/04 ,  B01J27/045 ,  B01J27/0573 ,  B01J27/0576 ,  B82Y30/00 ,  C01G55/00 ,  C01P2002/02 ,  C01P2002/22 ,  C01P2002/60 ,  C01P2002/77 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/80 ,  Y10S505/81

    摘要： A method is described for the preparation of chalcogenides of ruthenium, rhodium, osmium and iridium transition metals of the Periodic Table of the Elements which comprises mixing in the absence of an aqueous solvent a Group VIII transition metal salt with a source of chalcogenide, said chalcogenide being selected from the group consisting of sulfur, selenium, tellurium and mixtures thereof, yielding a precipitate of the formula MX.sub.y wherein M is selected from the group consisting of ruthenium, rhodium, osmium and iridium, X is sulfur, selenium, tellurium and mixtures thereof and y is a number ranging from about 0.1 to about 3, preferably 0.1 to about 2.5. By the practice of the nonaqueous synthesis technique, Group VIII chalcogenides are prepared which are finely divided, have a high surface area, small particle size and small crystallite size which are also free of excess sulfur, water and/or hydrolysis products. Layered stoichiometric osmium disulfide is prepared by this technique. The precipitates may be cleansed of any anion salt coproduct by any technique common to the art.Compounds of the formula MX.sub.y thus prepared are superior sulfur-tolerant catalysts in catalytic processes, for example, hydrodesulfurization, hydrodenitrogenation, hydroconversion, hydrogenation.

    摘要翻译： 描述了用于制备元素周期表的钌，铑，锇和铱过渡金属的硫族化物的方法，该方法包括在不存在含水溶剂的情况下混合第VIII族过渡金属盐与硫族化物源，所述硫族化物 选自硫，硒，碲及其混合物，得到式MXy的沉淀物，其中M选自钌，铑，锇和铱，X是硫，硒，碲及其混合物 y为约0.1至约3，优选为0.1至约2.5的数。 通过非水合成技术的实践，制备了细分的，具有高表面积，小颗粒尺寸和小微晶尺寸的第VIII族硫属化物，其也不含过量的硫，水和/或水解产物。 通过该技术制备分层化学计量的二硫化锇。 可以通过本领域普通技术将沉淀物清除任何阴离子盐副产物。 如此制备的式MXy的化合物是催化方法中优异的耐硫催化剂，例如加氢脱硫，加氢脱氮，加氢转化，氢化。

    Commercial production of transition metal sulfides from their halides
    9.
    发明授权
    Commercial production of transition metal sulfides from their halides 失效
    从其卤化物商业生产过渡金属硫化物

    公开(公告)号：US4208394A

    公开(公告)日：1980-06-17

    申请号：US637222

    申请日：1975-12-03

    申请人： Russell R. Chianelli

    发明人： Russell R. Chianelli

    IPC分类号： C01G1/12 ,  C01G23/00 ,  C01G27/00 ,  C01G33/00 ,  H01M4/58 ,  C01B17/00

    CPC分类号： H01M4/581 ,  C01G1/12 ,  C01G23/007 ,  C01G33/00

    摘要： Sulfides of Group IVb and Vb transition metals are produced by reacting their halides with carbon disulfide. The reactions can be between liquid or gaseous halides and liquid or gaseous carbon disulfide. The reaction products are formed and recovered as solids and the other reaction product, carbon tetrahalide, is carried off as a gas and recovered. A specific example is the production of titanium disulfide by reacting titanium tetrachloride with carbon disulfide.

    摘要翻译： 通过使它们的卤化物与二硫化碳反应制备IVb族和Vb族过渡金属的硫化物。 反应可以在液体或气态卤化物与液体或气态二硫化碳之间。 作为固体形成和回收反应产物，另外的反应产物四卤化碳作为气体被排出并回收。 一个具体的例子是通过使四氯化钛与二硫化碳反应来生产二硫化钛。