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1.发明授权Process for the facilitated waste disposal of working substances based on water-in-oil invert emulsions 失效基于油包水反相乳液促进废物处理工作物质的方法
公开(公告)号：US6165946A
公开(公告)日：2000-12-26
申请号：US297481
申请日：1999-04-30
申请人： Heinz Mueller , Claus-Peter Herold , Thomas Foerster , Stephan von Tapavicza , Johann-Friedrich Fues
发明人： Heinz Mueller , Claus-Peter Herold , Thomas Foerster , Stephan von Tapavicza , Johann-Friedrich Fues
CPC分类号： E21B21/068 , C09K8/28 , C09K8/36 , Y10S507/927
摘要： The invention relates to a process for facilitating the disposal of flowable and pumpable working fluids based on emulsifiers containing W/O invert emulsions--more particularly corresponding auxiliaries of the type used in geological exploration, such as oil-based w/o invert drilling muds--and for the simplified cleaning of solid surfaces soiled therewith, if desired using flowable spraying aids, the process being characterized in that, by selecting and adapting the emulsifiers/emulsifier systems to the oil phase of the invert emulsion, temperature-controlled phase inversion is achieved at temperatures below the in-use temperatures of the w/o invert emulsions, but above the freezing point of the aqueous phase and in that disposal and cleaning are carried out at temperatures in and/or below the phase inversion temperature range. The invention also relates to the use of this process for the cleaning and disposal of roc cuttings covered with residual drilling mud from geological exploration during and/or preferably before their on-shore or off-shore dumping
摘要翻译： PCT No.PCT / EP97 / 05798 Sec。 371日期1999年4月30日 102（e）1999年4月30日PCT PCT 1997年10月21日PCT公布。 第WO98 / 18882号公报 日期1998年5月7日本发明涉及一种促进基于含有W / O反相乳液的乳化剂处理可流动和可泵送的工作流体的方法，更具体地说涉及在地质勘探中使用的类型的相应助剂，例如油基w / o 反转钻井泥浆 - 并且为了简化清洁其中污染的固体表面，如果需要，使用可流动的喷洒助剂，该方法的特征在于通过选择和适应乳化剂/乳化剂体系到反相乳液的油相，温度控制 在低于w / o反相乳液的使用温度但高于水相的凝固点的温度下实现相转化，并且处理和清洗在相转变温度范围内和/或低于相转变温度范围的温度下进行 。 本发明还涉及这种方法用于清洁和处理在其在岸或离岸倾倒期间和/或优选在其岸上倾倒之前的地质勘探中覆盖有残留钻井泥浆的罗切切割
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公开(公告)号：US6022833A
公开(公告)日：2000-02-08
申请号：US933188
申请日：1997-09-18
申请人： Heinz Mueller , Claus-Peter Herold , Thomas Foerster , Stephan von Tapavicza , Johann-Friedrich Fues , Marcus Claas
发明人： Heinz Mueller , Claus-Peter Herold , Thomas Foerster , Stephan von Tapavicza , Johann-Friedrich Fues , Marcus Claas
摘要： The invention relates to flowable and pumpable multicomponent mixtures based on a multiphase mixture of water and oil containing emulsifiers and, if desired, other soluble, emulsifiable and/or dispersible auxiliaries for their use in exploration by drilling and/or for the further treatment of the wells thus drilled. The invention is characterized by the use of emulsifiers or emulsifier systems which, in the particular multicomponent mixture in question, lead to temperature-controlled phase inversion at a phase inversion temperature (PIT) in a temperature range of which the upper limit is so far below the working temperature of the multicomponent mixture in geological exploration that the water-based part of the multicomponent mixture is present as a disperse (invert) phase in the continuous oil phase (w/o invert emulsion) while the lower limit of this temperature range enables the multicomponent mixture to be converted into an o/w emulsion with a continuous aqueous phase. At least partly nonionic emulsifiers or emulsifier systems with a PIT of 0 to 100.degree. C. are particularly suitable. The invention enables the requirements in regard to technical performance, ecological compatibility and cost/effectiveness ratio to be optimally satisfied.
摘要翻译： 本发明涉及可流动和可泵送的多组分混合物，其基于水和油的多相混合物，其包含乳化剂，并且如果需要，其它可溶性，可乳化和/或可分散的助剂用于通过钻井和/或进一步处理 所钻的井。 本发明的特征在于使用乳化剂或乳化剂体系，其在所述特定的多组分混合物中在相转变温度（PIT）下导致温度控制的相转化，其温度范围远远低于 多组分混合物在地质勘探中的工作温度，多组分混合物的水基部分作为连续油相（w / o反相乳液）中的分散（反相）相存在，而该温度范围的下限允许 将多组分混合物转化成具有连续水相的o / w乳液。 PIT为0至100℃的至少部分非离子乳化剂或乳化剂体系是特别合适的。 本发明使技术性能，生态兼容性和成本效益比方面的要求得到最佳的满足。
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3.发明授权Use of selected ester oils in water-based drilling fluids of the O/W emulsion type and corresponding drilling fluids with improved ecological acceptability 失效在O / W乳液型水相钻井液和相应的钻井液中使用选定的酯油，具有改善的生态可接受性
公开(公告)号：US5318956A
公开(公告)日：1994-06-07
申请号：US055409
申请日：1993-04-29
CPC分类号： C09K8/26
摘要： The use is disclosed of water-dispersible esters, which are fluid or at least plastically deformable at working temperature and have flash points of at least 80.degree. C., from saturated and/or unsaturated carboxylic acids with up to 36 carbon atoms and mono- and/or polyhydric alcohols, as at least the main constituent of the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally friendly development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
摘要翻译： 公开了水分散性酯，其是在工作温度下为流体或至少可塑性变形的具有至多80℃的闪点的水分散性酯，其具有至多36个碳原子的饱和和/或不饱和羧酸， 和/或多元醇作为至少是水性O / W乳液钻井液的分散油相的主要成分，其适用于地质构造的环境友好型开发，并且如果需要，其含有不溶性的细颗粒 用于形成水基O / W乳液钻井泥浆的增重剂和/或其它添加剂，例如乳化剂，流体损失添加剂，润湿剂，碱储备和/或用于抑制高水钻岩的辅助物质 -灵敏度。
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4.发明授权Use of selected oleophilic ethers in water-based drilling fluids of the O/W emulsion type and corresponding drilling fluids with improved ecological acceptability 失效在O / W乳液型水相钻井液和相应的钻井液中使用选定的亲油醚，具有改善的生态可接受性公开(公告)号：US06596670B1
公开(公告)日：2003-07-22
申请号：US08025915
申请日：1993-03-03
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Gerhard Stoll , Rainer Jeschke , Johann Friedrich Fues
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Gerhard Stoll , Rainer Jeschke , Johann Friedrich Fues
IPC分类号： C09K702
CPC分类号： C09K8/26
摘要： The use is disclosed of at least substantially water-insoluble ethers which are fluid and/or at least plastically deformable at working temperature and have flash points of at least 80° C., of mono- and/or polyfunctional alcohols of natural and/or synthetic origin or corresponding solutions of such ethers in ecologically acceptable water-insoluble oils as the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally acceptable development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
摘要翻译： 公开了使用至少基本上不溶于水的醚，其在工作温度下为流体和/或至少可塑性变形，并且具有至少80℃的闪点和/或多官能醇的天然和/或 合成来源或这些醚在生态可接受的水不溶性油中的相应溶液，作为水性O / W乳液钻井液的分散油相，其适用于地质构造的环境可接受的开发，并且如果需要，其含有不溶性 用于形成水基O / W乳液钻井泥浆和/或其它添加剂的细颗粒增重剂，例如用于抑制钻孔岩石的乳化剂，流体损失添加剂，润湿剂，碱储备和/或辅助物质 水敏感度高。
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5.发明授权Multiphase lubricant concentrates for use in water based systems in the field of exploratory soil drilling 失效多相润滑剂浓缩物用于探索性土壤钻井领域的水基系统公开(公告)号：US06211119B1
公开(公告)日：2001-04-03
申请号：US09308399
申请日：1999-06-01
IPC分类号： C09K702
CPC分类号： C10M173/00 , C09K8/26 , C09K8/36 , C10M2201/02 , C10M2203/00 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2207/021 , C10M2207/022 , C10M2207/04 , C10M2207/046 , C10M2207/08 , C10M2207/126 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2207/32 , C10M2209/102 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2209/12 , C10M2211/00 , C10M2211/06 , C10M2215/00 , C10M2215/042 , C10M2215/062 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/10 , C10M2215/12 , C10M2215/122 , C10M2215/202 , C10M2215/28 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10M2217/044 , C10M2219/02 , C10M2219/022 , C10M2219/024 , C10M2223/02 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2223/065 , C10M2223/10 , C10M2229/02 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10M2229/051 , C10M2229/052 , C10M2229/053 , C10M2229/054 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C10N2270/02
摘要： The invention relates to multiphase lubricant concentrates with improved properties for use in aqueous fluids for geological exploration by drilling which contain organic lubricating components which are solid and/or liquid at room temperature (O phase) together with emulsifiers finely dispersed in a continuous aqueous phase (W phase). These concentrates are characterized in that the system of O phase/W phase and emulsifiers has a phase inversion temperature (PIT) above room temperature and has been produced by heating the multiphase system to temperatures equal to or above the PIT and subsequent cooling to temperatures below the PIT. The present invention also relates to the use of the multiphase lubricant concentrates as an additive in water-based fluids for use in geological exploration by drilling and for the subsequent treatment of the resulting boreholes.
摘要翻译： 本发明涉及具有改进性能的多相润滑剂浓缩物，其用于通过钻井进行地质勘探的含水流体，其包含在室温（O相）下固体和/或液体的有机润滑组分以及细分散在连续水相中的乳化剂（ W相）。 这些浓缩物的特征在于，O相/ W相和乳化剂的体系具有高于室温的相转化温度（PIT），并且通过将多相体系加热至等于或高于PIT的温度并随后冷却至低于 PIT。本发明还涉及多相润滑剂浓缩物作为添加剂在水基流体中的用途，用于通过钻孔进行地质勘探和随后处理所得到的钻孔。
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6.发明授权Free-flowing borehole servicing preparations containing linear .alpha.-olefins, more patricularly corresponding drilling fluids 失效自由流动的钻孔维护准备，包含线性α-烯烃，更多的是相应的钻井液
公开(公告)号：US5869434A
公开(公告)日：1999-02-09
申请号：US750829
申请日：1996-12-13
CPC分类号： C09K8/34 , C09K8/26 , Y10S507/905
摘要： The invention relates to the use of at least predominantly linear hydrocarbon compounds olefinically unsaturated in the alpha-position with flashpoints of at least about 80.degree. as the oil phase or as part of the oil phase of oil- or water-based free-flowing borehole servicing preparations. Particular significance is attributed to corresponding drilling fluids which, together with the alpha-olefins, contain other oil phases from the field of borehole servicing preparations and are distinguished by ecological compatibility, being degradable under both aerobic and anaerobic conditions. Suitable mixture components for the oil phase are, in particular, oleophilic alcohols, ethers and corresponding esters selected from carboxylic acid esters and/or carbonic acid esters.
摘要翻译： PCT No.PCT / EP95 / 02143 Sec。 371日期1996年12月13日第 102（e）日期1996年12月13日PCT归档1995年6月6日PCT公布。 公开号WO95 / 34610 日期1995年12月21日本发明涉及至少主要是在α-位上烯属不饱和的烃类化合物的使用，其中至少约80℃的闪点为油相或作为油相或水 - 油的油相的一部分， 基于自由流动的钻孔维修准备。 特别的意义归因于相应的钻井液，其与α-烯烃一起含有来自钻孔维修制剂领域的其他油相，并且通过生态相容性来区分，在有氧和无氧条件下都是可降解的。 用于油相的合适的混合物组分特别是亲油醇，醚和选自羧酸酯和/或碳酸酯的相应的酯。
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7.发明授权Process for rock consolidation and/or cavity filling e.g. in tunnel construction and mining 失效用于岩石固结和/或空腔填充的方法，例如 在隧道施工和采矿
公开(公告)号：US5322392A
公开(公告)日：1994-06-21
申请号：US853755
申请日：1992-07-29
IPC分类号： C09K17/00 , C09K8/508 , C09K17/24 , C09K17/28 , C09K17/42 , C09K17/48 , C09K103/00 , E02D3/12 , E21B33/138 , E21D9/04
CPC分类号： C09K8/5086 , C09K17/48
摘要： A process is described for rock consolidation, e.g. in tunnel construction and mining, by injection of aqueous preparations of melamine resin condensates and/or urea formaldehyde condensates together with an acid curing agent. The process is characterized by the use of aqueous solutions of hydrogen sulfate salts, especially solutions of alkali and/or ammonium bisulfates, as curing agents. The curing agent solutions can contain additional auxiliary agents and active substances such as corrosion inhibitors, structurizers and adhesion agents. Preferred resin solutions for consolidation with these aqueous curing agents contain added zeolite NaA and/or hydrosodalite for increasing their serviceability, and especially for prolonging their storage life.
摘要翻译： PCT No.PCT / EP90 / 02026 Sec。 371日期：1992年7月29日 102（e）日期1992年7月29日PCT 1990年11月26日PCT PCT。 公开号WO91 / 08271 日期1991年6月13日。描述了用于岩石固结的方法，例如 在隧道施工和采矿中，通过与酸固化剂一起注入三聚氰胺树脂缩合物和/或脲甲醛缩合物的水性制剂。 该方法的特征在于使用硫酸氢盐的水溶液，特别是碱和/或硫酸铵铵的溶液作为固化剂。 固化剂溶液可以含有另外的辅助剂和活性物质如腐蚀抑制剂，结构剂和粘合剂。 用于与这些水性固化剂固结的优选树脂溶液含有添加的沸石NaA和/或氢硅酸盐以提高其可使用性，特别是延长其储存寿命。
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公开(公告)号：US06806235B1
公开(公告)日：2004-10-19
申请号：US09856082
申请日：2001-08-24
IPC分类号： C09K702
CPC分类号： C09K8/06
摘要： A process for imparting lubricity to an aqueous drilling fluid used in geological exploration involving: (a) providing an aqueous drilling fluid; (b) providing a lubricant component containing a partial glyceride of predominantly unsaturated fatty acids having from about 16 to 24 carbon atoms; and (c) introducing the partial glyceride into the aqueous drilling fluid.
摘要翻译： 用于赋予地质勘探中使用的含水钻井液的润滑性的方法，涉及：（a）提供含水钻井液; （b）提供含有具有约16至24个碳原子的主要不饱和脂肪酸的偏甘油酯的润滑剂组分; 和（c）将部分甘油酯引入含水钻井液中。
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9.发明授权Low-foam surfactant concentrates for use in the domain of plant growth stimulation 失效低泡表面活性剂浓缩物用于植物生长刺激的领域公开(公告)号：US06350788B1
公开(公告)日：2002-02-26
申请号：US09341731
申请日：1999-10-22
IPC分类号： B01F1756
CPC分类号： A01N25/30 , Y10S71/903 , Y10S516/06
摘要： A low-foam wetting composition which, when mixed with water, enhances the penetration and spread of water on a plant, the composition containing: (a) an alkyl polyglycoside corresponding to formula I R—O—(G)x (I) wherein R is a primary hydrocarbon radical having from 8 to 18 carbon atoms, G is a glycose unit having 5 or 6 carbon atoms, and x is a number from 1 to 10; (b) an olefinically unsaturated alcohol; and (c) a lower water-soluble alcohol.
摘要翻译： 一种低泡沫润湿组合物，当与水混合时，其增强水对植物的渗透和扩散，该组合物包含：（a）对应于式I的烷基多糖苷，其中R是具有8至18个碳原子的伯烃基 原子，G是具有5或6个碳原子的糖苷单元，x是1至10的数; （b）烯属不饱和醇; 和（c）较低水溶性醇。
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公开(公告)号：USRE36066E
公开(公告)日：1999-01-26
申请号：US506458
申请日：1995-08-01
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Douglas J. Grimes , Jean-Marc Braun , Stuart P. T. Smith
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Douglas J. Grimes , Jean-Marc Braun , Stuart P. T. Smith
CPC分类号： C09K8/34
摘要： Invert emulsion muds for drilling of gas and oil, which are environmentally safe, and which contain:A. a continuous oil phase composed predominantly of at least one monocarboxylic acid ester of a C.sub.2 -C.sub.12 monofunctional alkalol wherein the monocarboxylic acid contains from 16 to 24 carbon atoms and is olefinically mono- or poly-unsaturated,B. a disperse aqueous phase,C. at least one emulsifier,D. at least one weighing agent,E. at least one fluid loss additive, andF. a mild alkaline reserve.
摘要翻译： 反转用于钻井气体和油的乳液泥浆，其是环境安全的，并且其包含：A.主要由至少一种C2-C12单官能碱醇的单羧酸酯组成的连续油相，其中所述单羧酸含有16至24 碳原子并且是烯属单或多不饱和的，B.分散水相，C.至少一种乳化剂，D.至少一种称重剂，E.至少一种流体损失添加剂，和F.弱碱性储备 。
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