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    Thermoplastic polycarbonate molding composition containing a rubber free copolymer and a combination of graft polymers
    2.
    发明授权
    Thermoplastic polycarbonate molding composition containing a rubber free copolymer and a combination of graft polymers 有权
    含有无橡胶的共聚物和接枝聚合物的组合的热塑性聚碳酸酯模塑组合物

    公开(公告)号：US06503628B1

    公开(公告)日：2003-01-07

    申请号：US09538649

    申请日：2000-03-30

    申请人： Venkatarayaloo Janarthanan ,  Roland P. Brassard ,  Karl-Erwin Piejko ,  Sara D. Graham

    发明人： Venkatarayaloo Janarthanan ,  Roland P. Brassard ,  Karl-Erwin Piejko ,  Sara D. Graham

    IPC分类号： B32B2736

    CPC分类号： C08L69/00 ,  C08L25/08 ,  C08L33/08 ,  C08L51/04 ,  C08L55/02 ,  Y10T428/31507 ,  C08L2666/02

    摘要： A thermoplastic molding composition comprising, (A) an aromatic polycarbonate; (B) a single rubber-free copolymer, e.g., of styrene and acrylonitrile; (C) a first graft polymer; (D) a second graft polymer; and (E) a wax, is described. The single rubber-free copolymer (B), and first and second graft polymers (C) and (D) are prepared from a specific selection of graft phases and graft bases. The graft base of the first graft polymer (C) comprises a crosslinked, particulate elastomer having an average particle diameter of 0.05 to 0.5 microns. The second graft polymer (D) has an average particle diameter of 0.6 to 20 microns. The thermoplastic compositions of the present invention are well suited for the preparation of molded articles that may be metalized over at least a portion of their surface by means of an electroless plating process. Such electroless plated articles are characterized as having improved heat resistance and adhesion of the metal plating.

    摘要翻译： 一种热塑性模塑组合物，其包含：（A）芳族聚碳酸酯; （B）单一无橡胶共聚物，例如苯乙烯和丙烯腈; （C）第一接枝聚合物; （D）第二接枝聚合物; 和（E）蜡。 单一无橡胶共聚物（B）和第一和第二接枝聚合物（C）和（D）由接枝相和接枝基材的特定选择制备。 第一接枝聚合物（C）的接枝基底包含平均粒径为0.05至0.5微米的交联的颗粒弹性体。 第二接枝聚合物（D）的平均粒径为0.6〜20微米。 本发明的热塑性组合物非常适用于通过化学镀方法制备可在其表面的至少一部分上金属化的模塑制品。 这种无电镀制品的特征在于具有改善的耐热性和金属镀层的粘合性。

    Thermoplastic compositions of polyurethanes and partly crosslinked alkyl acrylate copolymers
    5.
    发明授权
    Thermoplastic compositions of polyurethanes and partly crosslinked alkyl acrylate copolymers 失效
    聚氨酯和部分交联丙烯酸酯共聚物的热塑性组合物

    公开(公告)号：US5237001A

    公开(公告)日：1993-08-17

    申请号：US713663

    申请日：1991-06-11

    申请人： Karl-Erwin Piejko ,  Ernst Orthmann ,  Christian Lindner ,  Hans-Eberhard Braese

    发明人： Karl-Erwin Piejko ,  Ernst Orthmann ,  Christian Lindner ,  Hans-Eberhard Braese

    IPC分类号： C08L25/14 ,  C08F265/04 ,  C08F279/04 ,  C08L33/04 ,  C08L33/06 ,  C08L73/00 ,  C08L75/00 ,  C08L75/04

    CPC分类号： C08F265/04 ,  C08F279/04 ,  C08L33/06 ,  C08L75/04

    摘要： The present invention is directed to a thermoplastic composition which is a blend of A) a thermoplastic polyurethane and B) an at least partly crosslinked alkyl acrylate copolymer of a C.sub.1-6 alkyl acrylate and a monomer selected from the group consisting of acrylonitrile, styrene, vinyl acetate, C.sub.1-6 alkyl methacrylates and mixtures thereof. The preferred compositions also contain copolymer selected from the group consisting ofC1) a thermoplastic graft product of a rubber component having a glass transition temperature below 0.degree. C., which serves as the graft base, and at least one graft monomer selected from the group consisting of styrene, .alpha.-methyl styrene, acrylonitrile an C.sub.1-6 alkyl methacrylate,C2) a rubber-free resin copolymer of styrene or .alpha.-methyl styrene with acrylonitrile,C3) mixtures thereof.

    摘要翻译： 本发明涉及一种热塑性组合物，其是A）热塑性聚氨酯和B）至少部分交联的丙烯酸C 1-6烷基酯与选自丙烯腈，苯乙烯， 乙酸乙烯酯，甲基丙烯酸C 1-6烷基酯及其混合物。 优选的组合物还包含共聚物，其选自C1）玻璃化转变温度低于0℃的橡胶组分的热塑性接枝产物，其用作接枝基质，和至少一种选自以下的接枝单体 由苯乙烯，α-甲基苯乙烯，丙烯腈和甲基丙烯酸C 1-6烷基酯组成，C2）苯乙烯或α-甲基苯乙烯与丙烯腈的无橡胶树脂共聚物，C3）其混合物。

    Mixtures of thermoplastic polymers in powder form
    7.
    发明授权
    Mixtures of thermoplastic polymers in powder form 失效
    粉末形式的热塑性聚合物的混合物

    公开(公告)号：US5112910A

    公开(公告)日：1992-05-12

    申请号：US743678

    申请日：1991-08-12

    申请人： Karl-Erwin Piejko ,  Christian Lindner ,  Ralph Ostarek ,  Hans-Eberhard Braese ,  Karl-Heinz Ott

    发明人： Karl-Erwin Piejko ,  Christian Lindner ,  Ralph Ostarek ,  Hans-Eberhard Braese ,  Karl-Heinz Ott

    IPC分类号： C08J3/00 ,  C08L21/00 ,  C08L25/12 ,  C08L33/06 ,  C08L33/12 ,  C08L51/04

    CPC分类号： C08L33/06 ,  C08J3/005 ,  C08L21/00 ,  C08L25/12 ,  C08L33/12 ,  C08L51/04

    摘要： Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.

    摘要翻译： 制备粉末形式的热塑性聚合物的混合物的方法，该方法由以下混合物的水性乳液制备：a）丙烯酸C 2 -C 8烷基酯和/或丁二烯与（基于共聚物）的至少40重量％的颗粒部分交联的橡胶状共聚物。 丙烯腈，苯乙烯或甲基丙烯酸C 1 -C 4烷基酯，b）热塑性树脂，如果合适，c）在二烯或烷基上的苯乙烯，α-甲基苯乙烯，丙烯腈，甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物 丙烯酸酯橡胶，其橡胶含量为50〜95重量％ ％，其中a）和b）和如果合适的水性乳液c）具有15至50重量％的聚合物含量。 ％与凝固溶液同时混合，但在单独的流中，在20℃至100℃连续或半连续，聚合物a）和b），如果合适，c）凝结，将流合并，聚合物 混合物然后分离出来。

    Impact resistant polyamide moulding compounds modified with silicone graft rubbers
    8.
    发明授权
    Impact resistant polyamide moulding compounds modified with silicone graft rubbers 失效
    用聚硅氧烷接枝橡胶改性的耐冲击聚酰胺模塑料

    公开(公告)号：US4945124A

    公开(公告)日：1990-07-31

    申请号：US294216

    申请日：1989-01-09

    申请人： Uwe Westeppe ,  Christian Lindner ,  Karl-Erwin Piejko ,  Josef Merten

    发明人： Uwe Westeppe ,  Christian Lindner ,  Karl-Erwin Piejko ,  Josef Merten

    IPC分类号： C08F285/00 ,  C08L51/04 ,  C08L77/00

    CPC分类号： C08L51/04 ,  C08F285/00 ,  C08L77/00

    摘要： This invention relates to polyamides which have been modified with special silicone graft rubbers to render them impact resistant and are tough at low temperatures and have high processing stability even at high temperatures and good surface properties.The moulding compounds, which are distinguished by excellent mechanical properties even at low temperatures, consist of at least 40% by weight of polyamide and special graft rubbers with a multishell core/sheath structure having a silicone-based core.

    摘要翻译： 本发明涉及用特殊硅氧烷接枝橡胶改性的聚酰胺，使其具有耐冲击性，并且在低温下是韧性的，即使在高温下也具有高的加工稳定性和良好的表面性能。 即使在低温下也被优异的机械性能区分的成型化合物由至少40重量％的聚酰胺和具有硅酮核的多壳芯/鞘结构的特殊接枝橡胶组成。