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公开(公告)号：US06642172B1
公开(公告)日：2003-11-04
申请号：US08377829
申请日：1995-01-25
申请人： Carlo Perego , Gianluca Bassi , Gianni Girotti
发明人： Carlo Perego , Gianluca Bassi , Gianni Girotti
IPC分类号： B01J2112
CPC分类号： C07C2/10 , B01J21/12 , B01J37/0009 , B01J37/033 , C07C2521/12
摘要： A catalyst in the form of extruded bodies is disclosed, which consists of an inert binding agent and a catalytically active phase of a silica/alumina gel. The catalyst is particularly active in acid-catalysed reactions.
摘要翻译： 公开了一种挤出体形式的催化剂，其由惰性粘合剂和二氧化硅/氧化铝凝胶的催化活性相组成。 催化剂在酸催化反应中特别活跃。
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2.发明授权Catalytic composition and process for the alkylation and/or transalkylation of aromatic compounds 失效用于芳族化合物的烷基化和/或烷基转移的催化组合物和方法
公开(公告)号：US6034291A
公开(公告)日：2000-03-07
申请号：US988379
申请日：1997-12-10
CPC分类号： C07C6/126 , B01J29/04 , C07C2/66 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/16 , C07C2529/70
摘要： A catalytic composition is described for the alkylation and/or transalkylation of aromatic hydrocarbons consisting of beta zeolite, as such or modified by the isomorphous substitution of aluminum with boron, iron or gallium or by the introduction of alkaline and/or earth alkaline metals following an ion-exchange process, and an inorganic ligand, wherein the extrazeolite porosity, i.e. the porosity obtained by adding the mesoporosity and macroporosity fractions present in the catalytic composition itself, is such that a fraction of at least 25% is composed of pores with a radius higher than 100 .ANG., said composition being characterized by a total volume of extrazeolitic pores greater than or equal to 0.80 ml/g.
摘要翻译： 描述了一种催化组合物，用于烷基化和/或烷基转移由β沸石组成的芳族烃，如本文所述，或通过铝与硼，铁或镓的同晶取代或通过引入碱金属和/或碱土金属 离子交换过程和无机配体，其中超沸石孔隙率，即通过加入存在于催化剂组合物本身中的介孔度和大孔度组分获得的孔隙，使得至少25％的分数由具有半径的孔组成 所述组合物的特征在于大于或等于0.80ml / g的流出孔的总体积。
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公开(公告)号：US06924247B2
公开(公告)日：2005-08-02
申请号：US10014853
申请日：2001-12-14
CPC分类号： B01J29/06 , B01J29/7007 , B01J29/7034 , C01B39/026
摘要： The object of the present invention relates to a simple, rapid and inexpensive process for effecting solid-liquid separations in the case of zeolites, also having small crystals. This process, which is particularly useful for the recovery of zeolite crystals in suspension in the crystallization water, comprises treating this suspension of crystals with an acid or one of its precursors and subjecting the resulting mixture to filtration or decanting.According to a particular aspect of the invention, the crystalline phase is separated in a mixture with oxides which can be used as ligands. Said oxides can be generated by the reagents of the zeolite preparation reagent mixture, not transformed into crystalline phase during the synthesis hydrothermal treatment, or they can be added to the suspension of crystals before the separation treatment, or again they can be generated by precursors suitably added to the crystallization slurry.
摘要翻译： 本发明的目的涉及在具有小晶体的沸石的情况下实现固液分离的简单，快速和便宜的方法。 对于在结晶水中悬浮的沸石晶体的回收特别有用的该方法包括用酸或其前体之一处理该晶体悬浮液，并将所得混合物过滤或倾析。 根据本发明的特定方面，结晶相与可用作配体的氧化物以混合物分离。 所述氧化物可以通过沸石制备试剂混合物的试剂产生，在合成水热处理期间不转化为结晶相，或者可以在分离处理之前加入到晶体悬浮液中，或者再次由前体合成生成 加入到结晶浆料中。
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公开(公告)号：US5672799A
公开(公告)日：1997-09-30
申请号：US683740
申请日：1996-07-17
IPC分类号： B01J29/072 , B01J29/70 , C07B61/00 , C07C2/66 , C07C15/085
CPC分类号： C07C2/66 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/16 , C07C2529/70 , Y02P20/52
摘要： Process for the preparation of cumene by the alkylation of benzene with propylene, catalyzed by zeolite Beta into which certain quantities of suitable alkaline, alkaline-earth or metallic cations have been introduced by ion exchange.
摘要翻译： 通过用丙烯烷基化苯来制备枯烯的方法，由沸石β催化，其中通过离子交换引入了一定量的合适的碱金属，碱土金属或金属阳离子。
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公开(公告)号：US06204217B1
公开(公告)日：2001-03-20
申请号：US09172268
申请日：1998-10-14
申请人： Giannino Pazzucconi , Gianluca Bassi , Roberto Millini , Carlo Perego , Giovanni Perego , Giuseppe Bellussi
发明人： Giannino Pazzucconi , Gianluca Bassi , Roberto Millini , Carlo Perego , Giovanni Perego , Giuseppe Bellussi
IPC分类号： B01J2108
CPC分类号： B01J35/10 , B01J21/12 , B01J29/0308 , B01J29/041 , B01J35/1023 , B01J35/1042 , B01J35/1061 , B01J37/033 , B01J37/036 , B01J2229/42
摘要： Process for the preparation of a micro-mesoporous gel consisting of a silica matrix in which one or more metal oxides are possibly dispersed comprising: (a) subjecting to hydrolysis and gelification a tetra-alkylorthosilicate with an alkyl-trimethylammonium hydroxide having the formula R(CH3)3N—OH, wherein R is selected from n-butyl, n-pentyl, n-hexyl and n-heptyl, possibly in the presence of one or more metal compounds, the molar ratios in this mixture being: R—OH/SiO2=0-10; R(CH3)3N—OH/SiO2=0.05-0.4; H2O/SiO2=5-40; metal oxides/SiO2=0-0.02; whereas the ratio H2O/R(CH3)3N—OH varies according to the number of carbon atoms in the alkylic chain R as follows: R=n-butyl, H2O/R(CH3-)3N—OH
摘要翻译： 用于制备由二氧化硅基质组成的微孔介质凝胶的方法，其中一种或多种金属氧化物可能被分散，包括：（a）使原硅酸四烷基酯与具有式R的烷基 - 三甲基氢氧化铵进行水解和凝胶化 CH3）3N-OH，其中R选自正丁基，正戊基，正己基和正庚基，可能在一种或多种金属化合物存在下，该混合物中的摩尔比为：R-OH / SiO2 = 0-10; R（CH3）3N-OH / SiO2 = 0.05-0.4; H2O / SiO2 = 5-40; 金属氧化物/ SiO2 = 0-0.02; 而H 2 O / R（CH 3）3 N-OH的比例根据烷基链R中的碳原子数按如下方式变化：R =正丁基，H 2 O / R（CH 3）3 N-OH 35; R =正戊基，H 2 O / R（CH 3）3 N-OH <70; R =正己基，H 2 O / R（CH 3）3 N-OH <102; R =正庚基，H 2 O / R（CH 3）3 N-OH <136; （b）使步骤（a）中获得的凝胶或固体进行干燥和煅烧。
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公开(公告)号：US5789336A
公开(公告)日：1998-08-04
申请号：US371395
申请日：1995-01-11
申请人： Giannino Pazzucconi , Gianluca Bassi , Roberto Millini , Carlo Perego , Giovanni Perego , Giuseppe Bellussi
发明人： Giannino Pazzucconi , Gianluca Bassi , Roberto Millini , Carlo Perego , Giovanni Perego , Giuseppe Bellussi
CPC分类号： B01J37/033 , B01J20/06 , B01J20/28026 , B01J20/28047 , B01J20/28057 , B01J20/28069 , B01J20/28078 , B01J20/2809 , B01J21/08 , B01J35/002 , B01J35/1023 , B01J35/1038 , B01J35/1061
摘要： Micro-mesoporous gel consisting of a silica matrix possibly wherein one or more metal oxides selected from transition metals or metals belonging to groups IIIA, IVA and VA are uniformly dispersed, characterized by a monomodal porosity distribution.
摘要翻译： 由二氧化硅基质组成的微孔介质凝胶，其中一种或多种选自过渡金属或属于IIIA，IVA和VA族的金属的金属氧化物均匀分散，其特征在于单峰孔隙率分布。
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公开(公告)号：US07241931B2
公开(公告)日：2007-07-10
申请号：US11333201
申请日：2006-01-18
CPC分类号： B01J29/7034 , B01J29/90 , B01J38/56 , B01J2229/186 , B01J2229/26 , B01J2229/42 , C07C2/864 , C07C5/2737 , C07C6/126 , C07C15/24 , C07C2529/70 , C07C2602/10 , Y02P20/584
摘要： A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.
摘要翻译： 描述了用于制备2,6-二甲基萘的高选择性方法，其包括将选自萘，甲基萘，二甲基萘，三甲基萘，聚甲基萘和/或其混合物的萘烃与一种或多种选自苯，甲苯，二甲苯， 三甲基苯，四甲基苯，五甲基苯和/或六甲基苯，在至少部分液相条件下和在包含属于MTW结构类型的沸石和选自P，B和Si中的至少一种元素的催化组合物存在下进行。 该方法优选在甲基化剂的存在下进行。
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公开(公告)号：US06696614B2
公开(公告)日：2004-02-24
申请号：US10309145
申请日：2002-12-04
IPC分类号： C07C600
CPC分类号： C10G11/04 , B01J23/002 , B01J23/02 , B01J2523/00 , C01F7/164 , C01P2002/70 , B01J2523/23 , B01J2523/31
摘要： Catalyst for steam cracking reactions consisting of pure mayenite having the general formula: 12CaO.7Al2O3 having an X-ray diffraction spectrum as indicated in Table I, obtained with a preparation process comprising the following steps: dissolution of salts containing calcium and aluminum with water; complexing of the dissolved salts by means of polyfunctional organic hydroxyacids; drying of the solution resulting from the completing in order to obtain a solid precursor product; calcination of the solid precursor product at a temperature ranging from 1300 to 1400° C. for at least two hours.
摘要翻译： 用于蒸汽裂解反应的催化剂，其由具有以下通式的纯钙铝石组成：具有表I所示的X射线衍射光谱，其制备方法包括以下步骤：用水溶解含钙和铝的盐; 通过多官能有机羟基酸溶解的盐;干燥由完成得到的溶液以获得固体前体产物;在1300-1400℃的温度下煅烧固体前体产物至少2小时。
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9.发明授权
公开(公告)号：US5977424A
公开(公告)日：1999-11-02
申请号：US64775
申请日：1998-04-23
申请人： Giovanni Colombo , Stefano Amarilli , Imre Kiricsi , Carlo Perego
发明人： Giovanni Colombo , Stefano Amarilli , Imre Kiricsi , Carlo Perego
CPC分类号： B01J29/049 , C07C2/66 , C07C2529/04 , C07C2529/05
摘要： A catalyst is disclosed which comprises a clay belonging to the family of smectites, containing multi-metal pillars, together with a process which uses such a catalyst for the alkylation of aromatic hydrocarbons by means of long chain linear olefins. The resulting alkyl-aromatic compounds are useful for preparing biodegradable synthetic detergents.
摘要翻译： 公开了一种催化剂，其包含属于蒙皂石族的粘土，其包含多金属柱，以及使用这种催化剂通过长链线性烯烃烷基化芳族烃的方法。 所得的烷基 - 芳族化合物可用于制备可生物降解的合成洗涤剂。
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公开(公告)号：US5942613A
公开(公告)日：1999-08-24
申请号：US890677
申请日：1997-07-09
IPC分类号： B01J21/12 , B01J35/10 , C07B43/06 , C07B61/00 , C07D201/04
CPC分类号： B01J35/10 , B01J21/12 , C07D201/04 , B01J35/1023 , B01J35/1061
摘要： Process for the preparation of amides via the catalytic rearrangement of oximes which comprises putting an oxime in vapor phase in contact with a catalyst selected from a mesoporous silica-alumina having a molar ratio SiO/Al.sub.2 O.sub.2 of between 20 and 1000, an average pore diameter of between 20 and 100 .ANG. and an X-ray diffraction pattern (XRD) from powders which, after calcination, has the deepest reflection at d-spacing of more than 18 .ANG. (2.theta.
摘要翻译： 通过肟催化重排制备酰胺的方法，其包括将肟与气相中的肟与选自摩尔比SiO / Al 2 O 2的介孔二氧化硅 - 氧化铝的催化剂接触20至1000，平均孔径为 在20和100之间的ANGSTROM和来自粉末的X射线衍射图（XRD），其在煅烧之后在d间距处具有超过18个ANGSTROM（2θ<4.9°，CuKα辐射）的最深反射。
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