ELASTIC EXPANDED POLYMER FOAM BASED ON POLYOLEFIN/STYRENE POLYMER MIXTURES
    5.
    发明申请
    ELASTIC EXPANDED POLYMER FOAM BASED ON POLYOLEFIN/STYRENE POLYMER MIXTURES 失效
    基于聚烯烃/苯乙烯聚合物混合物的弹性膨胀聚合物泡沫

    公开(公告)号:US20110316198A1

    公开(公告)日:2011-12-29

    申请号:US13254174

    申请日:2010-03-01

    IPC分类号: C08L25/06

    摘要: The invention relates to elastic expanded polymer foams and also a process for producing expanded polymer foams by sintering a mixture comprising foam particles P1 and P2 composed of different thermoplastic polymers or polymer blends, wherein the foam particles P1 are obtained by prefoaming expandable, thermoplastic polymer particles comprising A) from 45 to 97.9 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin having a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin having a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer, C2) from 0.0 to 10 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent, where the sum of A) to E) is 100% by weight.

    摘要翻译: 本发明涉及弹性膨胀聚合物泡沫,还涉及通过烧结由不同的热塑性聚合物或聚合物共混物组成的泡沫颗粒P1和P2的混合物来生产发泡聚合物泡沫的方法,其中泡沫颗粒P1是通过预发泡的可发泡热塑性聚合物颗粒 包括A)45至97.9重量%的苯乙烯聚合物,B1)1至45重量%的熔点在105-140℃的聚烯烃,B2)0-25重量% 熔点低于105℃的聚烯烃的重量,C1)0.1至25重量%的苯乙烯 - 丁二烯或苯乙烯 - 异戊二烯嵌段共聚物,C2)0.0至10重量%的苯乙烯 - 乙烯 - 丁烯嵌段共聚物,D)1〜15重量%的发泡剂,E)0〜5重量%的成核剂,其中A)与E)之和为100重量%。

    Elastic expanded polymer foam based on polyolefin/styrene polymer mixtures
    6.
    发明授权
    Elastic expanded polymer foam based on polyolefin/styrene polymer mixtures 失效
    基于聚烯烃/苯乙烯聚合物混合物的弹性膨胀聚合物泡沫

    公开(公告)号:US08741973B2

    公开(公告)日:2014-06-03

    申请号:US13254174

    申请日:2010-03-01

    IPC分类号: C08L25/06 C08J9/16

    摘要: The invention relates to elastic expanded polymer foams and also a process for producing expanded polymer foams by sintering a mixture comprising foam particles P1 and P2 composed of different thermoplastic polymers or polymer blends, wherein the foam particles P1 are obtained by prefoaming expandable, thermoplastic polymer particles comprising A) from 45 to 97.9 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin having a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin having a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer, C2) from 0.0 to 10 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent, where the sum of A) to E) is 100% by weight.

    摘要翻译: 本发明涉及弹性膨胀聚合物泡沫,还涉及通过烧结由不同的热塑性聚合物或聚合物共混物构成的泡沫颗粒P1和P2的混合物来生产发泡聚合物泡沫的方法,其中泡沫颗粒P1是通过预发泡的可发泡热塑性聚合物颗粒 包括A)45至97.9重量%的苯乙烯聚合物,B1)1至45重量%的熔点在105-140℃的聚烯烃,B2)0-25重量% 熔点低于105℃的聚烯烃的重量,C1)0.1至25重量%的苯乙烯 - 丁二烯或苯乙烯 - 异戊二烯嵌段共聚物,C2)0.0至10重量%的苯乙烯 - 乙烯 - 丁烯嵌段共聚物,D)1〜15重量%的发泡剂,E)0〜5重量%的成核剂,其中A)与E)之和为100重量%。

    FLAME RETARDANT
    8.
    发明申请
    FLAME RETARDANT 有权
    不易燃的

    公开(公告)号:US20110245360A1

    公开(公告)日:2011-10-06

    申请号:US13075518

    申请日:2011-03-30

    IPC分类号: C08J9/00 C09K21/12 C08K5/5313

    摘要: A flame retardant comprising a) at least one sulfur compound of the formula (I) A1-(Z1)m—(S)n—(Z2)p-A2  (I) where the definitions of the symbols and indices are as follows: A1 and A2 are identical or different, being C6-C12-aryl, cyclohexyl, Si(ORa)3, a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COORb, CONRcRd, C1-C18-alkyl, C1-C18-alkoxy, C1-C18-thioalkyl, C6-C12-aryl, C6-C12-aryloxy, C2-C18-alkenyl, C2-C18-alkenoxy, C2-C18-alkynyl, and C2-C18-alkinoxy; Z1 and Z2 are identical or different, being —CO— or —CS—; Ra is C1-C18-alkyl; Rb, Rc, and Rd are identical or different, being H, C1-C18-alkyl, C6-C12-aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.

    摘要翻译: 一种阻燃剂,其包含a)至少一种式(I)A1-(Z1)m-(S)n-(Z2)p-A2(I)的硫化合物,其中符号和指数的定义如下: A1和A2相同或不同,为具有3至12个环成员且包含一个或多个杂原子的饱和,部分不饱和或芳族单环或双环的C 6 -C 12 - 芳基,环己基,Si(OR a)3 由N,O和S的基团组成,其中体系未被取代或被一个或多个O,OH,S,SH,COORb,CONRcRd,C 1 -C 18烷基,C 1 -C 18 - 烷氧基,C 1 -C 18 - 硫代烷基,C 6 -C 12 - 芳基,C 6 -C 12 - 芳氧基,C 2 -C 18烯基,C 2 -C 18 - 烯氧基,C 2 -C 18炔基和C 2 -C 18 - 烷氧基; Z 1和Z 2相同或不同,为-CO-或-CS-; R a是C 1 -C 18 - 烷基; R b,R c和R d相同或不同,为H,C 1 -C 18 - 烷基,C 6 -C 12 - 芳基或具有3至12个环成员并且包含一个或多个来自 N,O,S组; m和p相同或不同,为0或1,n为2至10的自然数,b)至少一种磷含量为5-80重量%的无卤素有机磷化合物,基于 在磷化合物上,特别适用于保护基于苯乙烯聚合物的泡沫体。

    FLAME RETARDANTS
    9.
    发明申请
    FLAME RETARDANTS 审中-公开
    阻燃剂

    公开(公告)号:US20110196052A1

    公开(公告)日:2011-08-11

    申请号:US13022045

    申请日:2011-02-07

    摘要: Phosphine sulfide derivatives of the formula (I), S═PR1R2R3  (I) are suitable as flame retardants, in particular for polymers, where the definitions of the symbols in the formula (I) are as follows: R1 and R2 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C8-C10-aryl-C1-C4-alkyl; R3 is H, SH, SR4, OH, OR5 or a —(Y1)n—[P(═X1)R6—(Y2)n]m—P(═X2)R7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1 and X2 are identical or different, being O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R6, R7 and R8 are identical or different, being independently from one another C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S, and m is an integer from 0 to 100.

    摘要翻译: 式(I)的硫化膦衍生物,S = PR1R2R3(I)适用作阻燃剂,特别是用于聚合物的阻燃剂,其中式(I)中符号的定义如下:R1和R2相同或不同 可以不具有取代基或可以具有一个或多个C 1 -C 4烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基,C 2 -C 12 - 烯基,C 2 -C 12炔基,C 6 -C 10 - 芳基或C 8 -C 10 - 芳基-C 1 -C 4 - 烷基; R3是H,SH,SR4,OH,OR5或 - (Y1)n- [P(= X1)R6-(Y2)n] m-P(= X2)R7R8组; 或两个基团R 1,R 2,R 3与键合的磷原子一起形成环系; X1和X2相同或不同,为O或S; Y1和Y2相同或不同,为O或S; R 4,R 5,R 6,R 7和R 8相同或不同,彼此独立地为可以不具有取代基或可以具有一个或多个C 1 -C 4 - 烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基 ,C 2 -C 12 - 烯基,C 2 -C 12 - 炔基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基; 如果Y1和Y1分别为0,则n为1,如果Y1分别为Y2,并且分别为1,2,3,4,5,6,7或8,并且m分别为0至100的整数。 。

    Flame retardant
    10.
    发明授权
    Flame retardant 有权
    不易燃的

    公开(公告)号:US09115312B2

    公开(公告)日:2015-08-25

    申请号:US13075518

    申请日:2011-03-30

    摘要: A flame retardant comprising a) at least one sulfur compound of the formula (I) A1-(Z1)m—(S)n—(Z2)p-A2  (I) where the definitions of the symbols and indices are as follows: A1 and A2 are identical or different, being C6-C12-aryl, cyclohexyl, Si(ORa)3, a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COORb, CONRcRd, C1-C18-alkyl, C1-C18-alkoxy, C1-C18-thioalkyl, C6-C12-aryl, C6-C12-aryloxy, C2-C18-alkenyl, C2-C18-alkenoxy, C2-C18-alkynyl, and C2-C18-alkinoxy; Z1 and Z2 are identical or different, being —CO— or —CS—; Ra is C1-C18-alkyl; Rb, Rc, and Rd are identical or different, being H, C1-C18-alkyl, C6-C12-aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.

    摘要翻译: 一种阻燃剂,其包含a)至少一种式(I)A1-(Z1)m-(S)n-(Z2)p-A2(I)的硫化合物,其中符号和指数的定义如下: A1和A2相同或不同,为具有3至12个环成员且包含一个或多个杂原子的饱和,部分不饱和或芳族单环或双环的C 6 -C 12 - 芳基,环己基,Si(OR a)3 由N,O和S的基团组成,其中体系未被取代或被一个或多个O,OH,S,SH,COORb,CONRcRd,C 1 -C 18烷基,C 1 -C 18 - 烷氧基,C 1 -C 18 - 硫代烷基,C 6 -C 12 - 芳基,C 6 -C 12 - 芳氧基,C 2 -C 18烯基,C 2 -C 18 - 烯氧基,C 2 -C 18炔基和C 2 -C 18 - 烷氧基; Z 1和Z 2相同或不同,为-CO-或-CS-; R a是C 1 -C 18 - 烷基; R b,R c和R d相同或不同,为H,C 1 -C 18 - 烷基,C 6 -C 12 - 芳基或具有3至12个环成员并且包含一个或多个来自 N,O,S组; m和p相同或不同,为0或1,n为2至10的自然数,b)至少一种磷含量为5-80重量%的无卤素有机磷化合物,基于 在磷化合物上,特别适用于保护基于苯乙烯聚合物的泡沫体。