摘要:
A process for disproportionation of olefins is disclosed employing a novel catalyst comprising a silica support treated with an oxide or oxide precursor of tungsten and a Group I oxide or compound convertible to the oxide in admixture with a double bond isomerization catalyst.
摘要:
A process for the disproportionation of olefins is disclosed employing a novel catalyst comprising an inorganic oxide support contacted with at least one of tungsten or molybdenum oxide or oxide precursor and at least one acid. Method for preparation of catalyst is also provided.
摘要:
A hydrocarbon conversion process comprising contacting a hydrocarbon stream such as, for example, gasoline, with a catalyst composition to effect the conversion of the hydrocarbon to olefins and C6 to C8 aromatic hydrocarbons such as toluene and xylenes. The catalyst composition comprises a zeolite, a promoter and optionally a binder.
摘要:
A catalyst composition and a process for converting a hydrocarbon stream such as, for example, gasoline to C6 to C8 aromatic hydrocarbons such as toluene and xylenes are disclosed. The catalyst composition includes an alumina, a silica, and a metal wherein the weight ratio of aluminum to silicon is in the range of from about 0.002:1 to about 0.6:1. The process includes contacting a hydrocarbon stream with the catalyst composition under a condition sufficient to effect the conversion of a hydrocarbon to a C6 to C8 aromatic hydrocarbon. Also disclosed is a process for producing the catalyst composition which includes: (1) contacting a zeolite with an effective amount of an acid under a condition sufficient to effect a reduction in aluminum content of the zeolite to produce an acid-leached zeolite; and (2) impregnating the acid-leached zeolite with an effective amount of a metal compound under a condition sufficient to effect the production of a metal-promoted zeolite.
摘要:
A catalyst composition, a process for producing the catalyst composition, and a hydroconversion process for converting a fluid stream comprising at least one saturated hydrocarbon to C6 to C8 aromatic hydrocarbons such as benzene, toluene, and xylenes are disclosed. The catalyst composition comprises a zeolite and a promoter. The process for producing the composition comprises the steps of: (1) combining a zeolite with a complexing ligand and a promoter compound under a condition sufficient to produce a modified zeolite; and (2) heating the modified zeolite to produce a promoted zeolite. The hydroconversion process comprises contacting a fluid stream with the catalyst composition under a condition sufficient to effect the conversion of a saturated hydrocarbon to a C6 to C8 aromatic hydrocarbon.
摘要:
A method of increasing total diluent conversion in a process for the conversion of cracked gasoline and a first diluent comprising iso-pentane to aromatics and light olefins by contacting the cracked gasoline, the first diluent and a second diluent comprising either propane or 1-hexene with a zeolite catalyst containing phosphorus. The zeolite catalyst comprises a calcined, acid-leached zeolite and phosphorus. Also described is a method of making such catalyst.
摘要:
A catalyst composition and process for preparing such catalyst composition which can be useful in contacting a hydrocarbon-containing fluid which contains a highly unsaturated hydrocarbon such as 1,3-butadiene, in the presence of hydrogen, with such catalyst composition in a hydrogenation zone under a hydrogenation condition effective to hydrogenate such highly unsaturated hydrocarbon to a less unsaturated hydrocarbon such as n-butene is disclosed. Such process for preparing a catalyst composition includes (1) combining a zeolite, a Group VIB metal, and an inorganic support to form a modified zeolite; (2) calcining such modified zeolite under a calcining condition to produce a calcined, modified zeolite; and (3) contacting such calcined, modified zeolite with a carburizing agent under a carburizing condition to provide such catalyst composition.
摘要:
A catalyst composition, a process for producing the catalyst composition, and a hydroconversion process for converting a fluid stream comprising at least one saturated hydrocarbon to C.sub.6 to C.sub.8 aromatic hydrocarbons such as benzene, toluene, and xylenes are disclosed. The catalyst composition comprises a zeolite and a promoter. The process for producing the composition comprises the steps of: (1) combining a zeolite with a complexing ligand and a promoter compound under a condition sufficient to produce a modified zeolite; and (2) heating the modified zeolite to produce a promoted zeolite. The hydroconversion process comprises contacting a fluid stream with the catalyst composition under a condition sufficient to effect the conversion of a saturated hydrocarbon to a C.sub.6 to C.sub.8 aromatic hydrocarbon.
摘要:
An improved zeolite catalyst containing a zeolite and a zinc component manufactured by a novel method having certain process steps necessary for providing the improved zeolite catalyst. The process steps include incorporation of a zinc component with such zeolite followed by a steam treatment. An acid treatment can be conducted after the steam treatment. Processes are also disclosed for using the improved zeolite catalyst in the conversion of hydrocarbons, preferably non-aromatic hydrocarbons, to lower olefins (such as ethylene, propylene, and butene) and aromatic hydrocarbons (such as benzene, toluene, and xylene).
摘要:
A process to produce a composition is provided. Said process comprises: contacting a zeolite component, a silicon component, a Group 14 metal component, and a phosphorus component together to form a first mixture; treating said first mixture to form a second mixture; contacting said second mixture with a binder component to form a third mixture; agglomerating said third mixture to form a fourth mixture; and treating said fourth mixture to form said composition.