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公开(公告)号：US08377996B2
公开(公告)日：2013-02-19
申请号：US13031341
申请日：2011-02-21
IPC分类号： C07C27/00
CPC分类号： B01J37/16 , B01J29/068 , B01J29/072 , B01J29/44 , B01J29/46 , B01J37/0009 , B01J37/0203 , B01J37/12 , B01J37/14 , B01J37/18 , B01J2229/20 , B01J2229/42 , C10G2/332 , C10G2/334 , C10G2300/703
摘要： A method for forming a catalyst for synthesis gas conversion comprises impregnating a zeolite extrudate using a solution, for example, a substantially non-aqueous solution, comprising a cobalt salt to provide an impregnated zeolite extrudate and activating the impregnated zeolite extrudate by a reduction-oxidation-reduction cycle.
摘要翻译： 形成合成气转化催化剂的方法包括使用包含钴盐的溶液例如基本上非水溶液浸渍沸石挤出物，以提供浸渍的沸石挤出物，并通过还原氧化活化浸渍的沸石挤出物 - 减少周期。
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2.发明授权Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst, hydrocracking and hydroisomerization catalyst 有权使用合成气转化催化剂，加氢裂化和加氢异构化催化剂的交替层合成气转化为液态烃混合物的方法公开(公告)号：US08519011B2
公开(公告)日：2013-08-27
申请号：US13208195
申请日：2011-08-11
IPC分类号： C07C27/00
CPC分类号： B01J37/0244 , B01J23/8913 , B01J29/42 , B01J29/74 , B01J37/024 , B01J37/04 , C10G2/32 , C10G2/333 , C10G2/341 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/14 , C10G65/12 , C10G2300/1022 , C10G2300/304 , C10G2400/02
摘要： Disclosed is a process for converting synthesis gas to liquid hydrocarbon mixtures useful in the production of fuels and petrochemicals. The synthesis gas is contacted with at least two layers of synthesis gas conversion catalyst wherein each synthesis gas conversion catalyst layer is followed by a layer of hydrocracking catalyst and hydroisomerization catalyst or separate layers of hydrocracking and hydroisomerization catalysts. The process can occur within a single reactor, at an essentially common reactor temperature and an essentially common reactor pressure. The process provides a high yield of naphtha range liquid hydrocarbons and a low yield of wax.
摘要翻译： 公开了将合成气转化成用于生产燃料和石化产品的液体烃混合物的方法。 合成气与至少两层合成气转化催化剂接触，其中每个合成气转化催化剂层之后是一层加氢裂化催化剂和加氢异构化催化剂或分开的加氢裂化和加氢异构化催化剂层。 该方法可以在单个反应器中，在基本上公认的反应器温度和基本上共同的反应器压力下进行。 该方法提供了高产量的石脑油范围液体烃和低产率的蜡。
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3.发明授权Ruthenium hybrid fischer-tropsch catalyst, and methods for preparation and use thereof 有权钌混合费 - 托催化剂及其制备和使用方法公开(公告)号：US08445550B2
公开(公告)日：2013-05-21
申请号：US12953024
申请日：2010-11-23
IPC分类号： C07C27/00
CPC分类号： B01J23/462 , B01J21/04 , B01J23/6562 , B01J29/068 , B01J29/076 , B01J29/48 , B01J29/7815 , B01J35/0006 , B01J35/002 , B01J35/006 , B01J35/1019 , B01J35/1038 , B01J35/108 , B01J37/0009 , B01J37/024 , B01J37/035 , C10G2/332 , C10G2/333 , C10G2300/1022 , C10G2300/304
摘要： Disclosed is a method of forming a hybrid Fischer-Tropsch catalyst extrudate for use in synthesis gas conversion reactions. The method includes extruding a mixture of ruthenium loaded metal oxide support particles, particles of an acidic component and a binder sol to form an extrudate. The resulting extrudate contains from about 0.1 to about 15 weight percent ruthenium based on the weight of the extrudate. In a synthesis gas conversion reaction, the extrudate is contacted with a synthesis gas having a H2 to CO molar ratio of 0.5 to 3.0 at a reaction temperature of 160° C. to 300° C., a total pressure of 3 to 35 atmospheres, and an hourly space velocity of 5 to 10,000 v/v/hour, resulting in hydrocarbon products containing 1-15 weight % CH4; 1-15 weight % C2-C4; 70-95 weight % C5+; 0-5 weight % C21+ normal paraffins; and 0-10 weight % aromatic hydrocarbons.
摘要翻译： 公开了形成用于合成气转化反应的混合费 - 托催化剂挤出物的方法。 该方法包括挤出载有钌的金属氧化物载体颗粒，酸性组分的颗粒和粘合剂溶胶的混合物以形成挤出物。 所得挤出物含有基于挤出物重量的约0.1至约15重量％的钌。 在合成气转化反应中，将挤出物与H 2 CO 2摩尔比为0.5-3.0的合成气在160℃至300℃的反应温度，3至35大气压的总压力下接触， 和5至10,000v / v /小时的小时空间速度，得到含有1-15重量％CH 4的烃产物; 1-15重量％C2-C4; 70-95重量％C5 +; 0-5重量％C21 +正链烷烃; 和0-10重量％的芳烃。
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4.发明申请公开(公告)号：US20120108682A1
公开(公告)日：2012-05-03
申请号：US13208195
申请日：2011-08-11
IPC分类号： C07C1/04
CPC分类号： B01J37/0244 , B01J23/8913 , B01J29/42 , B01J29/74 , B01J37/024 , B01J37/04 , C10G2/32 , C10G2/333 , C10G2/341 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/14 , C10G65/12 , C10G2300/1022 , C10G2300/304 , C10G2400/02
摘要： Disclosed is a process for converting synthesis gas to liquid hydrocarbon mixtures useful in the production of fuels and petrochemicals. The synthesis gas is contacted with at least two layers of synthesis gas conversion catalyst wherein each synthesis gas conversion catalyst layer is followed by a layer of hydrocracking catalyst and hydroisomerization catalyst or separate layers of hydrocracking and hydroisomerization catalysts. The process can occur within a single reactor, at an essentially common reactor temperature and an essentially common reactor pressure. The process provides a high yield of naphtha range liquid hydrocarbons and a low yield of wax.
摘要翻译： 公开了将合成气转化成用于生产燃料和石化产品的液体烃混合物的方法。 合成气与至少两层合成气转化催化剂接触，其中每个合成气转化催化剂层之后是一层加氢裂化催化剂和加氢异构化催化剂或分开的加氢裂化和加氢异构化催化剂层。 该方法可以在单个反应器中，在基本上公认的反应器温度和基本上共同的反应器压力下进行。 该方法提供了高产量的石脑油范围液体烃和低产率的蜡。
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5.发明申请PROCESS AND SYSTEM FOR REDUCING THE OLEFIN CONTENT OF A FISCHER-TROPSCH PRODUCT STREAM 有权用于减少FISCHER-TROPSCH产品流的烯烃含量的方法和系统公开(公告)号：US20110306685A1
公开(公告)日：2011-12-15
申请号：US12797773
申请日：2010-06-10
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , B01J23/44 , B01J29/74 , B01J29/7469 , B01J29/7669 , B01J35/0006 , B01J35/006 , B01J35/0066 , B01J35/1019 , B01J37/0009 , B01J37/0203 , B01J37/18 , B01J2229/42 , C10G2/332 , C10G2/333 , C10G2/334 , C10G45/00 , C10G2300/1022 , C10G2300/304
摘要： A method is provided for converting synthesis gas to liquid hydrocarbon mixtures useful as distillate fuel and/or lube base oil containing no greater than about 25 wt % olefins and containing no greater than about 5 wt % C21+ normal paraffins. The synthesis gas is contacted with a synthesis gas conversion catalyst comprising a Fischer-Tropsch synthesis component and an acidic component in an upstream catalyst bed thereby producing a wax-free liquid containing a paraffin component and an olefin component. The olefin component is saturated by contacting the liquid with an olefin saturation catalyst in a downstream catalyst bed.
摘要翻译： 提供了一种用于将合成气转化成液体烃混合物的方法，该液体烃混合物可用作不大于约25重量％的烯烃并且不超过约5重量％的C21 +正构链烷烃的馏出物燃料和/或润滑油基础油。 使合成气与上游催化剂床中的包含费 - 托合成成分和酸性成分的合成气转化催化剂接触，由此生成含有石蜡成分和烯烃成分的无蜡液体。 通过在下游催化剂床中使液体与烯烃饱和催化剂接触来使烯烃组分饱和。
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6.发明授权Process of synthesis gas conversion to liquid fuels using mixture of synthesis gas conversion catalyst and dual functionality catalyst 有权使用合成气转化催化剂和双官能催化剂的混合物将合成气转化为液体燃料的方法公开(公告)号：US07825164B1
公开(公告)日：2010-11-02
申请号：US12621385
申请日：2009-11-18
申请人： Charles L. Kibby , Kandaswamy Jothimurugesan , Tapan K. Das , Robert J. Saxton , Allen W. Burton
发明人： Charles L. Kibby , Kandaswamy Jothimurugesan , Tapan K. Das , Robert J. Saxton , Allen W. Burton
IPC分类号： C07C27/00
CPC分类号： C10G2/333 , B01J23/75 , B01J23/894 , B01J29/068 , B01J29/44 , B01J29/74 , B01J35/0006
摘要： A process is disclosed for converting a feed comprising synthesis gas to liquid hydrocarbons within a single reactor at essentially common reaction conditions. The synthesis gas contacts a catalyst bed comprising a mixture of a synthesis gas conversion catalyst on a support containing an acidic component and a dual functionality catalyst including a hydrogenation component and a solid acid component. The hydrocarbons produced are liquid at about 0° C., contain at least 25% by volume C10+ and are substantially free of solid wax.
摘要翻译： 公开了用于在基本上常见的反应条件下将包含合成气的进料转化为单个反应器内的液体烃的方法。 合成气在包含酸性组分的载体和包含氢化组分和固体酸组分的双官能催化剂的催化剂床上接触合成气转化催化剂的混合物。 生产的烃在约0℃是液体的，含有至少25体积％的C 10+，并且基本上不含固体蜡。
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7.发明申请PROCESSES AND SYSTEMS FOR CONVERTING SYNTHESIS GAS TO LIQUID HYDROCARBON PRODUCT 审中-公开将合成气转化为液体产物的方法和系统公开(公告)号：US20130109768A1
公开(公告)日：2013-05-02
申请号：US13285098
申请日：2011-10-31
申请人： Robert J. Saxton , Gordon R. Deppe , Scott Oliver , David W. Parham , Kandaswamy Jothimurugesan , Charles L. Kibby , Tapan K. Das , Christine M. Philips , Richard Sasson , Anne Helgeson
发明人： Robert J. Saxton , Gordon R. Deppe , Scott Oliver , David W. Parham , Kandaswamy Jothimurugesan , Charles L. Kibby , Tapan K. Das , Christine M. Philips , Richard Sasson , Anne Helgeson
CPC分类号： C10G2/32 , B01J2219/00006 , B01J2219/0004 , C10G33/06 , C10G2300/203 , C10G2300/304 , C10K3/06
摘要： Processes and systems are provided for converting synthesis gas containing a mixture of H2 and CO to liquid hydrocarbon products having a cloud point less than about 15° C. The systems utilize at least one Fischer-Tropsch reactor containing hybrid Fischer-Tropsch catalyst with cooling and separation of reactor effluent following each reactor. The low cloud point indicates that the amount of wax in the hydrocarbon products is minimized relative to conventional Fischer-Tropsch conversion. Accordingly, more economical systems can be built and operated because equipment associated with wax removal or wax treatment can be reduced or eliminated.
摘要翻译： 提供了将含有H 2和CO 2的混合物的合成气转化成具有低于约15℃的浊点的液体烃产物的方法和系统。该系统利用至少一个含有混合费 - 托催化剂的费 - 托反应器，其中冷却和 在每个反应器之后分离反应器流出物。 低浊点表明相对于常规费 - 托转化，烃产物中的蜡的量最小化。 因此，可以建造和操作更经济的系统，因为可以减少或消除与除蜡或蜡处理有关的设备。
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8.发明申请公开(公告)号：US20120129960A1
公开(公告)日：2012-05-24
申请号：US12953042
申请日：2010-11-23
IPC分类号： C07C1/04
CPC分类号： C10G2/332 , B01J21/04 , B01J23/462 , B01J23/6562 , B01J29/068 , B01J29/44 , B01J29/7415 , B01J35/0006 , B01J35/006 , B01J35/0066 , B01J35/1019 , B01J35/1038 , B01J37/04 , C10G2300/1022 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/30
摘要： The disclosure relates to a method of performing a synthesis gas conversion reaction in which synthesis gas contacts a catalyst system including a mixture of ruthenium loaded Fischer-Tropsch catalyst particles and at least one set of catalyst particles including an acidic component promoted with a noble metal, e.g., Pt or Pd. The reaction occurs at conditions resulting in a hydrocarbons product containing 1-15 weight % CH4, 1-15 weight % C2-C4, 70-95 weight % C5+, 0-5 weight % C21+ normal paraffins, and 0-10 weight % aromatic hydrocarbons.
摘要翻译： 本发明涉及一种进行合成气转化反应的方法，其中合成气与包含钌负载的费 - 托催化剂颗粒和至少一组催化剂颗粒的催化剂体系接触，所述催化剂颗粒包括用贵金属促进的酸性组分， 例如Pt或Pd。 反应发生在产生含有1-15重量％CH 4，1-15重量％C 2 -C 4，70-95重量％C 5+，0-5重量％C 21+正构烷烃和0-10重量％芳族烃的烃产物的条件下 碳氢化合物。
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9.发明申请RUTHENIUM HYBRID FISCHER-TROPSCH CATALYST, AND METHODS FOR PREPARATION AND USE THEREOF 有权钌混合物螯合催化剂及其制备和使用方法公开(公告)号：US20120129959A1
公开(公告)日：2012-05-24
申请号：US12953024
申请日：2010-11-23
IPC分类号： B01J23/00 , B01J23/745 , B01J23/28 , B01J23/34 , B01J23/30 , B01J23/42 , B01J23/72 , B01J23/48 , B01J23/06 , B01J23/755 , C07C1/04 , B01J23/10
CPC分类号： B01J23/462 , B01J21/04 , B01J23/6562 , B01J29/068 , B01J29/076 , B01J29/48 , B01J29/7815 , B01J35/0006 , B01J35/002 , B01J35/006 , B01J35/1019 , B01J35/1038 , B01J35/108 , B01J37/0009 , B01J37/024 , B01J37/035 , C10G2/332 , C10G2/333 , C10G2300/1022 , C10G2300/304
摘要： Disclosed is a method of forming a hybrid Fischer-Tropsch catalyst extrudate for use in synthesis gas conversion reactions. The method includes extruding a mixture of ruthenium loaded metal oxide support particles, particles of an acidic component and a binder sol to form an extrudate. The resulting extrudate contains from about 0.1 to about 15 weight percent ruthenium based on the weight of the extrudate. In a synthesis gas conversion reaction, the extrudate is contacted with a synthesis gas having a H2 to CO molar ratio of 0.5 to 3.0 at a reaction temperature of 160° C. to 300° C., a total pressure of 3 to 35 atmospheres, and an hourly space velocity of 5 to 10,000 v/v/hour, resulting in hydrocarbon products containing 1-15 weight % CH4; 1-15 weight % C2-C4; 70-95 weight % C5+; 0-5 weight % C21+ normal paraffins; and 0-10 weight % aromatic hydrocarbons.
摘要翻译： 公开了形成用于合成气转化反应的混合费 - 托催化剂挤出物的方法。 该方法包括挤出载有钌的金属氧化物载体颗粒，酸性组分的颗粒和粘合剂溶胶的混合物以形成挤出物。 所得挤出物含有基于挤出物重量的约0.1至约15重量％的钌。 在合成气转化反应中，将挤出物与H 2 CO 2摩尔比为0.5-3.0的合成气在160℃至300℃的反应温度，3至35大气压的总压力下接触， 和5至10,000v / v /小时的小时空间速度，得到含有1-15重量％CH 4的烃产物; 1-15重量％C2-C4; 70-95重量％C5 +; 0-5重量％C21 +正链烷烃; 和0-10重量％的芳烃。
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10.发明授权Process of synthesis gas conversion to liquid fuels using mixture of synthesis gas conversion catalyst and dual functionality catalyst 有权使用合成气转化催化剂和双官能催化剂的混合物将合成气转化为液体燃料的方法公开(公告)号：US07973087B2
公开(公告)日：2011-07-05
申请号：US12902915
申请日：2010-10-12
申请人： Charles L. Kibby , Kandaswamy Jothimurugesan , Tapan K. Das , Robert J. Saxton , Allen W. Burton, Jr.
发明人： Charles L. Kibby , Kandaswamy Jothimurugesan , Tapan K. Das , Robert J. Saxton , Allen W. Burton, Jr.
IPC分类号： C07C27/00
CPC分类号： C10G2/333 , B01J23/75 , B01J23/894 , B01J29/068 , B01J29/44 , B01J29/74 , B01J35/0006
摘要： A process is disclosed for converting a feed comprising synthesis gas to liquid hydrocarbons within a single reactor at essentially common reaction conditions. The synthesis gas contacts a catalyst bed comprising a mixture of a synthesis gas conversion catalyst on a support containing an acidic component and a dual functionality catalyst including a hydrogenation component and a solid acid component. The hydrocarbons produced are liquid at about 0° C., contain at least 25% by volume C10+ and are substantially free of solid wax.
摘要翻译： 公开了用于在基本上常见的反应条件下将包含合成气的进料转化为单个反应器内的液体烃的方法。 合成气在包含酸性组分的载体和包含氢化组分和固体酸组分的双官能催化剂的催化剂床上接触合成气转化催化剂的混合物。 生产的烃在约0℃是液体的，含有至少25体积％的C 10+，并且基本上不含固体蜡。
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