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1.发明授权Low temperature polymethylsiloxane containing silicon-bonded hydrogen and curable compositions made therewith 失效含有硅键合氢的低温聚甲基硅氧烷和由其制成的可固化组合物
公开(公告)号：US4613659A
公开(公告)日：1986-09-23
申请号：US809455
申请日：1985-12-16
申请人： Chi-long Lee , Myron T. Maxson
发明人： Chi-long Lee , Myron T. Maxson
CPC分类号： C08G77/12
摘要： Polymethylsiloxanes containing silicon-bonded hydrogen exhibit low temperature properties and can be made into gels with which also exhibit low temperature properties or into elastomeric materials. The polymethylsiloxanes have 84 to 96 mole percent dimethylsiloxane units, 0.5 to 6 mole percent trimethylsiloxy units, 2 to 10 mole percent methylsilsesquioxane units, and 0.25 to 3 mole percent monohydrogendimethylsiloxy units and the total mole percent of the trimethylsiloxy units and the monohydrogendimethylsiloxy units is at least 1.5.
摘要翻译： 含有硅键合氢的聚甲基硅氧烷具有低温性能，并且可以制成也具有低温性能的凝胶或弹性材料。 聚甲基硅氧烷具有84至96摩尔％的二甲基硅氧烷单元，0.5至6摩尔％的三甲基甲硅烷氧基单元，2至10摩尔％的甲基硅倍半氧烷单元和0.25至3摩尔％的单氢化二甲基甲硅烷氧基单元，并且三甲基甲硅烷氧基单元和单氢羟基二甲基甲硅烷氧基单元的总摩尔百分数为 至少1.5。
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公开(公告)号：US4711928A
公开(公告)日：1987-12-08
申请号：US835578
申请日：1986-03-03
申请人： Chi-long Lee , Myron T. Maxson
发明人： Chi-long Lee , Myron T. Maxson
IPC分类号： C08K13/02 , C08G77/50 , C08K3/00 , C08K5/05 , C08K5/54 , C08K5/544 , C08K9/06 , C08L83/04 , C08L83/07 , C08L83/14 , C09K3/10
CPC分类号： C09K3/1018 , C08G77/50 , C08K5/54 , C09K2003/1056 , C09K2200/0208
摘要： A method of producing a one-part silicone elastomeric sealant which has improved shelf life and an economical process of manufacture is disclosed. The method mixes a diorganovinylsiloxy endblocked polydiorganosiloxane, reinforcing filler, and a silazane. This reinforced base is then converted by reacting with a silane of the formulaH[SiR.sub.2 OSiR.sub.2 CH.sub.2 CH.sub.2 ].sub.b SiR.sub.a (OR").sub.3-awhere R is methyl, ethyl, propyl, phenyl or trifluoropropyl, R" is methyl or ethyl, a is 0 or 1, and b is 0 or 1 using a platinum catalyst. The result is a base containing an alkoxy functional polymer. This base is then mixed with alkoxy functional silane crosslinker and titanium catalyst to yield a composition which is stable in the absence of moisture for long periods of time in storage, but cures to an elastomer upon exposure to moisture. The improved shelf life is due to the presence of alkylene radicals between the penultimate silicon atom and the last silicon atom of the polymer.
摘要翻译： 公开了一种制备具有改进的保质期和经济的制造方法的单组分硅酮弹性体密封剂的方法。 该方法混合二有机乙烯基甲硅烷氧基封端的聚二有机硅氧烷，增强填料和硅氮烷。 乙基，丙基，苯基或三氟丙基，R“是甲基或乙基，a是与式H [SiR 2 OSiR 2 CH 2 CH 2] bSiRa（OR”）3-a的硅烷反应， 0或1，b为0或1，使用铂催化剂。 结果是含有烷氧基官能聚合物的碱。 然后将该碱与烷氧基官能的硅烷交联剂和钛催化剂混合，以产生在不存在水分的情况下在长时间储存时稳定的组合物，但在暴露于水分时可固化至弹性体。 改良的保质期是由于在倒数第二硅原子和聚合物的最后硅原子之间存在亚烷基。
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公开(公告)号：US6040353A
公开(公告)日：2000-03-21
申请号：US199623
申请日：1998-11-25
IPC分类号： C08L83/07 , C08F2/46 , C08F2/50 , C08F16/12 , C08F16/32 , C08F290/00 , C08F299/08 , C09D4/00 , C09D183/04 , C09D183/06 , G03F7/039 , C08J3/28 , C08L83/06
CPC分类号： C08F16/32 , C08F16/12 , C09D183/06
摘要： This invention relates to a radiation curable silicone compositions. More particularly this invention relates to radiation curable silicone compositions comprising a vinyl ether functional silicon compound, a cationic photoinitiator, a free radical photoinitiator, and dodecylphenol. The compositions of this invention can further comprise a vinyl ether compound which is free of silicon atoms. The radiation curable silicone compositions of this invention are useful as release coating compositions which are especially suitable for release of pressure sensitive adhesives.
摘要翻译： 本发明涉及可辐射固化的硅氧烷组合物。 更具体地说，本发明涉及包含乙烯基醚官能的硅化合物，阳离子光引发剂，自由基光引发剂和十二烷基苯酚的可辐射固化的硅氧烷组合物。 本发明的组合物还可以包含不含硅原子的乙烯基醚化合物。 本发明的可辐射固化的硅氧烷组合物可用作特别适用于压敏粘合剂释放的脱模涂料组合物。
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公开(公告)号：US5162560A
公开(公告)日：1992-11-10
申请号：US842914
申请日：1992-02-28
申请人： Russell K. King , Chi-long Lee
发明人： Russell K. King , Chi-long Lee
CPC分类号： C07F7/1844 , C07F7/10 , C07F7/12
摘要： Azasilacyclopentanes of the general formula ##STR1## are prepared by reacting a dialkoxyalkyl(3-chloro-2-alkylpropyl)silane with a Grignard reagent of the formula R.sup.1 MgBr in the presence of an ether, to make an alkoxyalkylalkenyl(3-chloro-2-alkylpropyl)silane which is reacted with acetyl chloride and a Lewis acid to make chloroalkylalkenyl(3-chloro-2-alkylpropyl)silane which is then reacted with an amine of the formula R.sup.3 NH.sub.2 to make the azasilacyclopentanes.
摘要翻译： 通式（III-c）所示的亚氮杂环戊烷通过在醚存在下使二烷氧基烷基（3-氯-2-烷基丙基）硅烷与式R 1 MgBr的格氏试剂反应制得烷氧基烷基（3-氯-2- 烷基丙基）硅烷，其与乙酰氯和路易斯酸反应以制备氯烷基烯基（3-氯-2-烷基丙基）硅烷，然后与式R 3 NH 2的胺反应以制备氮杂环丙烷基。
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公开(公告)号：US4923754A
公开(公告)日：1990-05-08
申请号：US187693
申请日：1988-04-29
申请人： Chi-long Lee , Michael A. Lutz
发明人： Chi-long Lee , Michael A. Lutz
CPC分类号： C08K5/00 , C03C25/106 , C08L83/04 , C08G77/20 , C08G77/24 , C08G77/28 , C08G77/70 , Y10T428/31612
摘要： Compositions which cure by UV radiation in less than one second are obtained by mixing an alkenyl containing polydiorganosiloxane, a mercapto functional crosslinker of the mercapto functional polyorganosiloxane or mercapto organic compounds, a photosensitizer, a viscosity stabilizer, and optionally a reinforcing agent. These compositions can be packaged in one container and can be used as the primary coating for optical fibers.
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6.发明授权Storage stable heat curable organosiloxane compositions containing microencapsulated platinum-containing catalysts 失效储存稳定的可固化有机硅氧烷组合物，含有微囊化的含铂催化剂
公开(公告)号：US4766176A
公开(公告)日：1988-08-23
申请号：US75177
申请日：1987-07-20
摘要： Storage stable, one part organosiloxane compositions that cure upon heating by a platinum-catalyzed hydrosilation reaction comprise, in addition to the organosiloxane reactants, a platinum-containing hydrosilation catalyst that is microencapsulated within one or two layers of thermoplastic organic polymers. The microcapsules are formed using known techniques.
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公开(公告)号：US4584337A
公开(公告)日：1986-04-22
申请号：US683303
申请日：1984-12-18
申请人： Chi-long Lee , Wen-Bin Shyu
发明人： Chi-long Lee , Wen-Bin Shyu
IPC分类号： C08F299/00 , B01D53/22 , B01D71/28 , B01D71/40 , B01D71/70 , B01D71/80 , C08F283/12 , C08F290/00 , C08F290/06 , C08F299/08 , C08G18/61 , C08G18/81 , C08L83/00 , C08L83/04 , C08L83/10 , C09D5/14 , C09D155/00 , C09D183/07 , C08L51/08
CPC分类号： C08G18/61 , C08F290/068 , C08G18/8116
摘要： This present invention provides aqueous emulsions which are capable of depositing coatings and membranes of hydrophilic, water-absorbing silicone-organic polymer elastomers. The elastomers are free radical polymerized copolymers of (A) from 50 to 95 parts by weight of block copolymers containing polydiorganosiloxane segments and polyalkyleneoxy segments which block copolymers contain terminal aliphatically unsaturated groups such as those derived from the reaction of isocyanatoethyl methacrylate with terminal free hydroxyl groups present on the polyalkyleneoxy segments and (B) from 5 to 50 parts by weight of at least one substantially water insoluble aliphatically unsaturated organic monomer which is compatible with (A) such as methyl methacrylate. The aqueous emulsions are useful for forming coatings and membranes of the above elastomers and also provide a vehicle for the deposition of coatings of such elastomers which are capable of controllably releasing bioactive agents such as insecticides or herbicides which are dispersed within the elastomer film deposited from the aqueous emulsion.
摘要翻译： 本发明提供了能够沉积亲水性，吸水性有机硅聚合物弹性体的涂层和膜的水性乳液。 弹性体是（A）50至95重量份的含聚二有机硅氧烷链段和聚亚烷基氧基链段的嵌段共聚物的自由基聚合共聚物，所述嵌段共聚物含有末端脂族不饱和基团，例如衍生自甲基丙烯酸异氰酸根合乙酯与末端游离羟基的反应 存在于聚亚烷基氧基部分和（B）5至50重量份的与（A）如甲基丙烯酸甲酯相容的至少一种基本上不溶于水的不饱和有机单体。 水乳液可用于形成上述弹性体的涂层和膜，并且还提供用于沉积这种弹性体的涂层的载体，其能够可控地释放生物活性剂如杀虫剂或除草剂，其分散在由 水乳液。
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公开(公告)号：US5254645A
公开(公告)日：1993-10-19
申请号：US938743
申请日：1992-09-02
申请人： Russell K. King , Chi-long Lee
发明人： Russell K. King , Chi-long Lee
IPC分类号： C08G81/00 , C08G77/50 , C08G77/54 , C08K5/5425 , C08L83/04 , C08L83/05 , C08L83/07 , C08G77/26
摘要： Cluster azasilacycloalkyl functional polysiloxanes are prepared by combining vinyl-containing polysiloxane, polyfunctional hydrogen polysiloxane, and a platinum catalyst; reacting the combination to produce .tbd.Si--CH.sub.2 CH.sub.2 --Si.tbd. linkages and substantial amounts of unreacted Si--H groups remain in the reaction product. The Si--H groups in the reaction product are reacted with aliphatically unsaturated azasilacycloalkane forming the cluster compound. These cluster azasilacycloalkyl functional polysiloxanes cure when exposed to moisture to elastomers, sealants, encapsulants, and resins products.
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公开(公告)号：US5169879A
公开(公告)日：1992-12-08
申请号：US495824
申请日：1990-04-19
申请人： Chi-long Lee , Michael A. Lutz
发明人： Chi-long Lee , Michael A. Lutz
CPC分类号： C08K5/00 , C03C25/106 , C08L83/04 , C08G77/16 , C08G77/20 , C08G77/24 , C08G77/28 , C08G77/70 , Y10S522/901
摘要： Compositions which cure by UV radiation in less than one second are obtained by mixing an alkenyl containing polydiorganosiloxane, a mercapto functional crosslinker of the mercapto functional polyorganosiloxane or mercapto organic compounds, a photosensitizer, a viscosity stabilizer, and optionally a reinforcing agent. These compositions can be packaged in one container and can be used as the primary coating for optical fibers.
摘要翻译： 通过混合含有聚二有机硅氧烷的链烯基，巯基官能聚有机硅氧烷或巯基有机化合物的巯基官能交联剂，光敏剂，粘度稳定剂和任选的增强剂，可得到通过UV辐射固化少于1秒的组合物。 这些组合物可以包装在一个容器中，并且可以用作光纤的主要涂层。
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10.发明授权
公开(公告)号：US5153238A
公开(公告)日：1992-10-06
申请号：US790043
申请日：1991-11-12
CPC分类号： C08J3/124 , C08J2383/04
摘要： Storage stable and gel-free organosiloxane compositions in the form of flowable powders are prepared by blending a high consistency polydiorganosiloxane into a quantity of fluidized reinforcing filler that is heated to a temperature of from 100.degree. to 200.degree. C. prior to or immediately following introduction of the polydiorganosiloxane. When silica is the reinforcing filler, the filler is typically treated with an anti-creping agent either prior to or during this blending process. The resultant mixture is heated while being subjected to shearing forces that reduce its average particle size to achieve a flowable powder.
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