公开(公告)号：US07795740B2

公开(公告)日：2010-09-14

申请号：US12245133

申请日：2008-10-03

申请人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

发明人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

IPC分类号： H01L21/4763 ,  H01L23/48

CPC分类号： H01L23/53295 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76831 ,  H01L21/76843 ,  H01L21/76844 ,  H01L23/53238 ,  H01L23/5329 ,  H01L2924/0002 ,  H01L2924/00

摘要： An interconnect structure and method of fabricating the same in which the adhesion between a chemically etched dielectric material and a noble metal liner is improved are provided. In accordance with the present invention, a chemically etching dielectric material is subjected to a treatment step which modified the chemical nature of the dielectric material such that the treated surfaces become hydrophobic. The treatment step is performed prior to deposition of the noble metal liner and aides in improving the adhesion between the chemically etched dielectric material and the noble metal liner.

摘要翻译： 提供了一种互连结构及其制造方法，其中改善了化学蚀刻的电介质材料和贵金属衬垫之间的粘合性。 根据本发明，对化学蚀刻电介质材料进行改性电介质材料的化学性质使处理后的表面变得疏水的处理步骤。 在沉积贵金属衬垫和助剂以改善化学蚀刻的电介质材料和贵金属衬垫之间的粘附性之前进行处理步骤。

公开(公告)号：US20070273044A1

公开(公告)日：2007-11-29

申请号：US11440984

申请日：2006-05-25

申请人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

发明人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

IPC分类号： H01L23/52

CPC分类号： H01L23/53295 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76831 ,  H01L21/76843 ,  H01L21/76844 ,  H01L23/53238 ,  H01L23/5329 ,  H01L2924/0002 ,  H01L2924/00

摘要： An interconnect structure and method of fabricating the same in which the adhesion between a chemically etched dielectric material and a noble metal liner is improved are provided. In accordance with the present invention, a chemically etching dielectric material is subjected to a treatment step which modified the chemical nature of the dielectric material such that the treated surfaces become hydrophobic. The treatment step is performed prior to deposition of the noble metal liner and aides in improving the adhesion between the chemically etched dielectric material and the noble metal liner.

摘要翻译： 提供了一种互连结构及其制造方法，其中改善了化学蚀刻的电介质材料和贵金属衬垫之间的粘合性。 根据本发明，对化学蚀刻电介质材料进行改性电介质材料的化学性质使处理后的表面变得疏水的处理步骤。 在沉积贵金属衬垫和助剂以改善化学蚀刻的电介质材料和贵金属衬垫之间的粘附性之前进行处理步骤。

公开(公告)号：US20090026625A1

公开(公告)日：2009-01-29

申请号：US12245133

申请日：2008-10-03

申请人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

发明人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

IPC分类号： H01L23/52

CPC分类号： H01L23/53295 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76831 ,  H01L21/76843 ,  H01L21/76844 ,  H01L23/53238 ,  H01L23/5329 ,  H01L2924/0002 ,  H01L2924/00

摘要： An interconnect structure and method of fabricating the same in which the adhesion between a chemically etched dielectric material and a noble metal liner is improved are provided. In accordance with the present invention, a chemically etching dielectric material is subjected to a treatment step which modified the chemical nature of the dielectric material such that the treated surfaces become hydrophobic. The treatment step is performed prior to deposition of the noble metal liner and aides in improving the adhesion between the chemically etched dielectric material and the noble metal liner.

摘要翻译： 提供了一种互连结构及其制造方法，其中改善了化学蚀刻的电介质材料和贵金属衬垫之间的粘合性。 根据本发明，对化学蚀刻电介质材料进行改性电介质材料的化学性质使得被处理的表面变得疏水的处理步骤。 在沉积贵金属衬垫和助剂以改善化学蚀刻的电介质材料和贵金属衬垫之间的粘附性之前进行处理步骤。

公开(公告)号：US07446058B2

公开(公告)日：2008-11-04

申请号：US11440984

申请日：2006-05-25

申请人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

发明人： Chih-Chao Yang ,  Griselda Bonilla ,  Qinghuang Lin ,  Terry A. Spooner

IPC分类号： H01L21/31 ,  H01L21/469

CPC分类号： H01L23/53295 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76831 ,  H01L21/76843 ,  H01L21/76844 ,  H01L23/53238 ,  H01L23/5329 ,  H01L2924/0002 ,  H01L2924/00

摘要： An interconnect structure and method of fabricating the same in which the adhesion between a chemically etched dielectric material and a noble metal liner is improved are provided. In accordance with the present invention, a chemically etching dielectric material is subjected to a treatment step which modified the chemical nature of the dielectric material such that the treated surfaces become hydrophobic. The treatment step is performed prior to deposition of the noble metal liner and aides in improving the adhesion between the chemically etched dielectric material and the noble metal liner.

摘要翻译： 提供了一种互连结构及其制造方法，其中改善了化学蚀刻的电介质材料和贵金属衬垫之间的粘合性。 根据本发明，对化学蚀刻电介质材料进行改性电介质材料的化学性质使处理后的表面变得疏水的处理步骤。 在沉积贵金属衬垫和助剂以改善化学蚀刻的电介质材料和贵金属衬垫之间的粘附性之前进行处理步骤。

公开(公告)号：US07816253B2

公开(公告)日：2010-10-19

申请号：US11308422

申请日：2006-03-23

申请人： Shyng-Tsong Chen ,  Qinghuang Lin ,  Kelly Malone ,  Sanjay Mehta ,  Terry A. Spooner ,  Chih-Chao Yang

发明人： Shyng-Tsong Chen ,  Qinghuang Lin ,  Kelly Malone ,  Sanjay Mehta ,  Terry A. Spooner ,  Chih-Chao Yang

IPC分类号： H01L21/76 ,  H01L21/425 ,  H01L21/4763

CPC分类号： H01L21/76825 ,  H01L21/3105 ,  H01L21/31058 ,  H01L21/76808 ,  H01L21/76814 ,  H01L21/76831

摘要： When an interconnect structure is built on porous ultra low k (ULK) material, the bottom of the trench and/or via is usually damaged by a following metallization process which may be suitable for dense higher dielectric materials. Embodiment of the present invention may provide a method of forming an interconnect structure on an inter-layer dielectric (ILD) material. The method includes steps of treating an exposed area of said ILD material to create a densified area, and metallizing said densified area.

摘要翻译： 当在多孔超低k（ULK）材料上构建互连结构时，沟槽和/或通孔的底部通常被以下金属化工艺损坏，这可能适合于较高的介电材料。 本发明的实施例可以提供在层间电介质（ILD）材料上形成互连结构的方法。 该方法包括处理所述ILD材料的暴露区域以产生致密化区域以及金属化所述致密化区域的步骤。

公开(公告)号：US20120329269A1

公开(公告)日：2012-12-27

申请号：US13602119

申请日：2012-09-01

申请人： John C. Arnold ,  Griselda Bonilla ,  William J. Cote ,  Geraud Dubois ,  Daniel C. Edelstein ,  Alfred Grill ,  Elbert Huang ,  Robert D. Miller ,  Satya V. Nitta ,  Sampath Purushothaman ,  E. Todd Ryan ,  Muthumanickam Sankarapandian ,  Terry A. Spooner ,  Willi Volksen

发明人： John C. Arnold ,  Griselda Bonilla ,  William J. Cote ,  Geraud Dubois ,  Daniel C. Edelstein ,  Alfred Grill ,  Elbert Huang ,  Robert D. Miller ,  Satya V. Nitta ,  Sampath Purushothaman ,  E. Todd Ryan ,  Muthumanickam Sankarapandian ,  Terry A. Spooner ,  Willi Volksen

IPC分类号： H01L21/768

CPC分类号： H01L21/76808 ,  H01L21/02063 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02274 ,  H01L21/02304 ,  H01L21/02348 ,  H01L21/02362 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/31633 ,  H01L21/76814 ,  H01L21/76826 ,  H01L21/76831

摘要： Methods of minimizing or eliminating plasma damage to low k and ultra low k organosilicate intermetal dielectric layers are provided. The reduction of the plasma damage is effected by interrupting the etch and strip process flow at a suitable point to add an inventive treatment which protects the intermetal dielectric layer from plasma damage during the plasma strip process. Reduction or elimination of a plasma damaged region in this manner also enables reduction of the line bias between a line pattern in a photoresist and a metal line formed therefrom, and changes in the line width of the line trench due to a wet clean after the reactive ion etch employed for formation of the line trench and a via cavity. The reduced line bias has a beneficial effect on electrical yields of a metal interconnect structure.

摘要翻译： 提供了最小化或消除对低k和超低k有机硅酸盐金属间电介质层的等离子体损伤的方法。 等离子体损伤的降低通过在合适的点处中断蚀刻和剥离工艺流程来实现，以增加本发明的处理，其保护金属间电介质层免受等离子体条带处理期间的等离子体损伤。 以这种方式减少或消除等离子体损伤区域还能够减少光致抗蚀剂中的线图案和由其形成的金属线之间的线偏压，并且由于在反应性之后的湿清洁而改变线沟槽的线宽 用于形成线沟槽和通孔腔的离子蚀刻。 减少的线偏压对金属互连结构的电产量具有有益的影响。

公开(公告)号：US07749892B2

公开(公告)日：2010-07-06

申请号：US11564358

申请日：2006-11-29

申请人： Griselda Bonilla ,  Christos D. Dimitrakopoulos ,  Son V. Nguyen ,  Alfred Grill ,  Satyanarayana V. Nitta ,  Darryl D. Restaino ,  Terry A. Spooner

发明人： Griselda Bonilla ,  Christos D. Dimitrakopoulos ,  Son V. Nguyen ,  Alfred Grill ,  Satyanarayana V. Nitta ,  Darryl D. Restaino ,  Terry A. Spooner

IPC分类号： H01L21/4763

CPC分类号： H01L21/76834 ,  H01L21/76825 ,  H01L21/76832 ,  H01L21/76844 ,  H01L23/53295 ,  H01L2924/0002 ,  H01L2924/00

摘要： An interconnect in provided which comprises a copper conductor having both a top surface and a lower surface, with caps formed on the top surface of the metallic conductor. The cap is formed of dual laminations or multiple laminations of films with the laminated films including an Ultra-Violet (UV) blocking film and a diffusion barrier film. The diffusion barrier film and the UV blocking film may be separated by an intermediate film.

摘要翻译： 提供的互连，其包括具有顶表面和下表面的铜导体，其中帽形成在金属导体的顶表面上。 盖由双层叠或多层薄膜形成，层压膜包括超紫（UV）阻挡膜和扩散阻挡膜。 扩散阻挡膜和UV阻挡膜可以通过中间膜分离。

公开(公告)号：US20090075472A1

公开(公告)日：2009-03-19

申请号：US11857760

申请日：2007-09-19

申请人： John C. Arnold ,  Griselda Bonilla ,  William J. Cote ,  Geraud Dubois ,  Daniel C. Edelstein ,  Alfred Grill ,  Elbert Huang ,  Robert D. Miller ,  Satya V. Nitta ,  Sampath Purushothaman ,  E. Todd Ryan ,  Muthumanickam Sankarapandian ,  Terry A. Spooner ,  Willi Volksen

发明人： John C. Arnold ,  Griselda Bonilla ,  William J. Cote ,  Geraud Dubois ,  Daniel C. Edelstein ,  Alfred Grill ,  Elbert Huang ,  Robert D. Miller ,  Satya V. Nitta ,  Sampath Purushothaman ,  E. Todd Ryan ,  Muthumanickam Sankarapandian ,  Terry A. Spooner ,  Willi Volksen

IPC分类号： H01L21/4763

CPC分类号： H01L21/76808 ,  H01L21/02063 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02274 ,  H01L21/02304 ,  H01L21/02348 ,  H01L21/02362 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/31633 ,  H01L21/76814 ,  H01L21/76826 ,  H01L21/76831

摘要： Methods of minimizing or eliminating plasma damage to low k and ultra low k organosilicate intermetal dielectric layers are provided. The reduction of the plasma damage is effected by interrupting the etch and strip process flow at a suitable point to add an inventive treatment which protects the intermetal dielectric layer from plasma damage during the plasma strip process. Reduction or elimination of a plasma damaged region in this manner also enables reduction of the line bias between a line pattern in a photoresist and a metal line formed therefrom, and changes in the line width of the line trench due to a wet clean after the reactive ion etch employed for formation of the line trench and a via cavity. The reduced line bias has a beneficial effect on electrical yields of a metal interconnect structure.

摘要翻译： 提供了最小化或消除对低k和超低k有机硅酸盐金属间电介质层的等离子体损伤的方法。 等离子体损伤的降低通过在合适的点处中断蚀刻和剥离工艺流程来实现，以增加本发明的处理，其保护金属间电介质层免受等离子体条带处理期间的等离子体损伤。 以这种方式减少或消除等离子体损伤区域还能够减少光致抗蚀剂中的线图案和由其形成的金属线之间的线偏压，并且由于在反应性之后的湿清洁而改变线沟槽的线宽 用于形成线沟槽和通孔腔的离子蚀刻。 减少的线偏压对金属互连结构的电产量具有有益的影响。

公开(公告)号：US20080122103A1

公开(公告)日：2008-05-29

申请号：US11564358

申请日：2006-11-29

申请人： Griselda Bonilla ,  Christos D. Dimitrakopoulos ,  Son V. Nguyen ,  Alfred Grill ,  Satyanarayana V. Nitta ,  Darryl D. Restaino ,  Terry A. Spooner

发明人： Griselda Bonilla ,  Christos D. Dimitrakopoulos ,  Son V. Nguyen ,  Alfred Grill ,  Satyanarayana V. Nitta ,  Darryl D. Restaino ,  Terry A. Spooner

IPC分类号： H01L23/532 ,  H01L21/768

CPC分类号： H01L21/76834 ,  H01L21/76825 ,  H01L21/76832 ,  H01L21/76844 ,  H01L23/53295 ,  H01L2924/0002 ,  H01L2924/00

摘要： An interconnect in provided which comprises a copper conductor having both a top surface and a lower surface, with caps formed on the top surface of the metallic conductor. The cap is formed of dual laminations or multiple laminations of films with the laminated films including an Ultra-Violet (UV) blocking film and a diffusion barrier film. The diffusion barrier film and the UV blocking film may be separated by an intermediate film.

摘要翻译： 提供的互连，其包括具有顶表面和下表面的铜导体，其中帽形成在金属导体的顶表面上。 盖由双层叠或多层薄膜形成，层压膜包括超紫（UV）阻挡膜和扩散阻挡膜。 扩散阻挡膜和UV阻挡膜可以通过中间膜分离。

公开(公告)号：US08470706B2

公开(公告)日：2013-06-25

申请号：US13602119

申请日：2012-09-01

申请人： John C. Arnold ,  Griselda Bonilla ,  William J. Cote ,  Geraud Dubois ,  Daniel C. Edelstein ,  Alfred Grill ,  Elbert Huang ,  Robert D. Miller ,  Satya V. Nitta ,  Sampath Purushothaman ,  E. Todd Ryan ,  Muthumanickam Sankarapandian ,  Terry A. Spooner ,  Willi Volksen

发明人： John C. Arnold ,  Griselda Bonilla ,  William J. Cote ,  Geraud Dubois ,  Daniel C. Edelstein ,  Alfred Grill ,  Elbert Huang ,  Robert D. Miller ,  Satya V. Nitta ,  Sampath Purushothaman ,  E. Todd Ryan ,  Muthumanickam Sankarapandian ,  Terry A. Spooner ,  Willi Volksen

IPC分类号： H01L21/4763

CPC分类号： H01L21/76808 ,  H01L21/02063 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02274 ,  H01L21/02304 ,  H01L21/02348 ,  H01L21/02362 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/31633 ,  H01L21/76814 ,  H01L21/76826 ,  H01L21/76831

摘要： Methods of minimizing or eliminating plasma damage to low k and ultra low k organosilicate intermetal dielectric layers are provided. The reduction of the plasma damage is effected by interrupting the etch and strip process flow at a suitable point to add an inventive treatment which protects the intermetal dielectric layer from plasma damage during the plasma strip process. Reduction or elimination of a plasma damaged region in this manner also enables reduction of the line bias between a line pattern in a photoresist and a metal line formed therefrom, and changes in the line width of the line trench due to a wet clean after the reactive ion etch employed for formation of the line trench and a via cavity. The reduced line bias has a beneficial effect on electrical yields of a metal interconnect structure.

摘要翻译： 提供了最小化或消除对低k和超低k有机硅酸盐金属间电介质层的等离子体损伤的方法。 等离子体损伤的降低通过在合适的点处中断蚀刻和剥离工艺流程来实现，以增加本发明的处理，其保护金属间电介质层免受等离子体条带处理期间的等离子体损伤。 以这种方式减少或消除等离子体损伤区域还能够减少光致抗蚀剂中的线图案和由其形成的金属线之间的线偏压，并且由于在反应性之后的湿清洁而改变线沟槽的线宽 用于形成线沟槽和通孔腔的离子蚀刻。 减少的线偏压对金属互连结构的电产量具有有益的影响。