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公开(公告)号：US5516959A
公开(公告)日：1996-05-14
申请号：US357841
申请日：1994-12-09
CPC分类号： B01J29/7042 , B01J29/65 , B01J29/7046 , C07C5/2775 , B01J2229/26 , B01J2229/42
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100 to 750.degree. C. The process uses a catalyst composition comprising ZSM-35, e.g., microcrystalline ZSM-35 having a crystal size whose largest dimension is no greater than 0.5 micron and whose ratio of its second largest dimension to said largest dimension ranges from 0.5 to 1. The process exhibits enhanced catalyst cycle life where the ZSM-35 is composited with a silica-containing matrix to provide a catalyst composite having a total pore volume greater than 0.6 cc/g or 300.sup.+ angstroms pore volume of greater than 0.1 cc/g.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触， 可以包括100至750℃的温度。该方法使用包含ZSM-35的催化剂组合物，例如具有最大尺寸不大于0.5微米的晶体尺寸的微晶ZSM-35，其第二大尺寸与所述 最大尺寸范围为0.5至1.该方法表现出增强的催化剂循环寿命，其中ZSM-35与含二氧化硅的基质复合以提供总孔体积大于0.6cc / g或300多埃孔体积的催化剂复合材料 大于0.1cc / g。
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2.发明授权Highly selective n-olefin isomerization process using low zeolite content ZSM-35 catalyst 失效使用低沸石含量的ZSM-35催化剂的高选择性正烯烃异构化方法
公开(公告)号：US5523511A
公开(公告)日：1996-06-04
申请号：US228779
申请日：1994-04-18
CPC分类号： B01J29/65 , B01J29/7042 , B01J29/7046 , C07C5/2775 , B01J2229/26 , B01J2229/42
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100.degree. to 750.degree. C. and linear olefin space velocities of less than 30 WHSV. The process uses a catalyst composition comprising 5 to 40 wt % ZSM-35, and 60 to 95 wt % inorganic oxide matrix, e.g., silica.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触， 可以包括100℃至750℃的温度和低于30WHSV的线性烯烃空速。 该方法使用包含5至40重量％的ZSM-35和60至95重量％的无机氧化物基质如二氧化硅的催化剂组合物。
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公开(公告)号：US5449851A
公开(公告)日：1995-09-12
申请号：US49586
申请日：1993-04-19
CPC分类号： B01J29/65 , C07C5/2775 , B01J2229/26 , B01J2229/42 , B01J29/7042 , B01J29/7046
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High iso-olefin selectivities thus can be obtained, even at relatively low temperatures and high linear olefin partial pressures.
摘要翻译： 公开了一种用于线性烯烃的有机原料的高度选择性骨架异构化的方法，其中线性烯烃例如正丁烯在异构化条件下与包含ZSM-35的催化剂接触以产生相应碳数的异烯烃，例如， 异丁烯 因此，即使在较低的温度和高的线性烯烃分压下，也可以获得高的异烯烃选择性。
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4.发明授权Highly selective N-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性N-烯烃异构化方法
公开(公告)号：US5237121A
公开(公告)日：1993-08-17
申请号：US925442
申请日：1992-08-11
IPC分类号： C07C5/27
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化成异烯烃的方法，其中线性烯烃例如正丁烯与包含ZSM-22的催化剂接触，ZSM-22的晶体尺寸 最大尺寸不大于0.5微米。 该方法在异构化条件下进行以产生相应碳数的异烯烃，例如异丁烯。 即使在相对较低的温度下也能获得高的全部异烯烃收率。
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5.发明授权Highly selective n-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性n-烯烃异构化方法
公开(公告)号：US5157194A
公开(公告)日：1992-10-20
申请号：US811355
申请日：1991-12-20
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
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公开(公告)号：US5453554A
公开(公告)日：1995-09-26
申请号：US249609
申请日：1994-05-26
申请人： Jane C. Cheng , Anthony S. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
发明人： Jane C. Cheng , Anthony S. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
IPC分类号： B01J20/18 , B01J29/03 , B01J29/06 , B01J29/40 , B01J29/70 , C01B33/38 , C01B35/00 , C01B39/00 , C01B39/02 , C01B39/48 , C07C2/66 , C07C15/02 , C10G35/06 , C10G35/095
CPC分类号： B01J29/70 , B01J37/0009 , C01B33/38 , B01J2229/42
摘要： Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under sufficient reaction conditions in the presence of a catalyst comprising zeolite MCM-56. The liquid phase syntheses of ethylbenzene and cumene are particular examples of such MCM-56 catalyzed reactions.
摘要翻译： 通过在含有沸石MCM-56的催化剂的存在下，在足够的反应条件下，用相对短链的烷基化剂烷基化可烷基化芳族化合物来制备相对短链烷基芳族化合物。 乙苯和枯烯的液相合成是这种MCM-56催化反应的具体实例。
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公开(公告)号：US5557024A
公开(公告)日：1996-09-17
申请号：US452919
申请日：1995-05-30
申请人： Jane C. Cheng , Anthony D. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
发明人： Jane C. Cheng , Anthony D. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
IPC分类号： B01J20/18 , B01J29/03 , B01J29/06 , B01J29/40 , B01J29/70 , C01B33/38 , C01B35/00 , C01B39/00 , C01B39/02 , C01B39/48 , C07C2/66 , C07C15/02 , C10G35/06 , C10G35/095
CPC分类号： B01J29/70 , B01J37/0009 , C01B33/38 , B01J2229/42
摘要： Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under sufficient reaction conditions in the presence of a catalyst comprising zeolite MCM-56. The liquid phase syntheses of ethylbenzene and cumene are particular examples of such MCM-56 catalyzed reactions.
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8.发明授权Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49 失效异构烷烃：在合成多孔MCM-49存在下进行烯烃烷基化
公开(公告)号：US5254792A
公开(公告)日：1993-10-19
申请号：US774482
申请日：1991-10-10
CPC分类号： C07C2/58 , C07C2529/70
摘要： The invention provides an isoparaffin: olefin alkylation process comprising contacting isoparaffin and olefin with a synthetic porous crystalline material which is characterized, in its uncalcined form, by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 20, X is a trivalent element and Y is a tetravalent element.
摘要翻译： 本发明提供了异链烷烃：烯烃烷基化方法，其包括使异链烷烃和烯烃与合成的多孔结晶材料接触，所述合成多孔结晶材料的特征在于其未煅烧形式，其X射线衍射图包括基本上如本说明书的表I所述的值，并且具有 包含摩尔关系X 2 O 3：（n）YO 2的组合物，其中n小于约20，X是三价元素，Y是四价元素。
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9.发明授权Low nitrogen iron-containing Fischer-Tropsch catalyst for conversion of synthesis gas and process for preparing the catalyst 失效用于转化合成气的低含氮铁的费 - 托催化剂和用于制备催化剂的方法
公开(公告)号：US4617288A
公开(公告)日：1986-10-14
申请号：US687695
申请日：1984-12-31
IPC分类号： B01J23/745 , B01J23/75 , B01J23/80 , B01J23/881 , B01J23/89 , C07C1/04 , B01J23/72 , B01J23/85
CPC分类号： B01J23/745 , B01J23/75 , B01J23/80 , B01J23/881 , B01J23/8906 , C07C1/0445 , C07C2521/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/28 , C07C2523/44 , C07C2523/72 , C07C2523/745 , C07C2523/75
摘要： Synthesis gas (a mixture of hydrogen gas and carbon monoxide) is converted to hydrocarbons by flowing the gas first over iron-containing Fischer-Tropsch catalyst and then over a zeolite. The Fischer-Tropsch catalyst contains relatively little nitrogen as a result of its preparation by continuous precipitation at a pH ranging from about 6.6 to 6.9 and a temperature ranging from about 80.degree. to about 100.degree. C.
摘要翻译： 将气体首先流过含铁费 - 托催化剂，然后通过沸石，将合成气（氢气和一氧化碳的混合物）转化成烃。 由于其在约6.6至6.9的pH和约80至约100℃的温度下连续沉淀制备，费 - 托催化剂含有相对较少的氮。
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10.发明授权Low nitrogen iron-containing Fischer-Tropsch catalyst and conversion of synthesis gas therewith 失效低含氮铁的费 - 托催化剂和合成气的转化
公开(公告)号：US4686313A
公开(公告)日：1987-08-11
申请号：US869649
申请日：1986-06-02
IPC分类号： B01J23/745 , B01J23/75 , B01J23/80 , B01J23/881 , B01J23/89 , C07C1/04
CPC分类号： B01J23/881 , B01J23/745 , B01J23/75 , B01J23/80 , B01J23/8906 , C07C1/0445 , C07C2521/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/28 , C07C2523/44 , C07C2523/72 , C07C2523/745 , C07C2523/75
摘要： Synthesis gas (a mixture of hydrogen gas and carbon monoxide) is converted to hydrocarbons by flowing the gas first over iron-containing Fischer-Tropsch catalyst and then over a zeolite. The Fischer-Tropsch catalyst contains relatively little nitrogen as a result of its preparation by continuous precipitation at a pH ranging from about 6.6 to 6.9 and a temperature ranging from about 80.degree. to about 100.degree. C.
摘要翻译： 将气体首先流过含铁费 - 托催化剂，然后通过沸石，将合成气（氢气和一氧化碳的混合物）转化成烃。 由于其在约6.6至6.9的pH和约80至约100℃的温度下连续沉淀制备，费 - 托催化剂含有相对较少的氮。
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