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公开(公告)号：US5637663A
公开(公告)日：1997-06-10
申请号：US596932
申请日：1996-02-05
申请人： Colin Anolick , Viacheslav A. Petrov , Bruce E. Smart , Charles W. Stewart , Robert C. Wheland , William B. Farnham , Andrew E. Feiring , Weiming Qiu
发明人： Colin Anolick , Viacheslav A. Petrov , Bruce E. Smart , Charles W. Stewart , Robert C. Wheland , William B. Farnham , Andrew E. Feiring , Weiming Qiu
IPC分类号： C07C317/04 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , C08L23/02 , C08L27/18 , C09D127/20 , C08F14/18
CPC分类号： C09D127/20 , C07C317/04 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/265 , C08F214/28 , C08L23/02 , C08L23/06 , C08L27/18
摘要： Disclosed herein are novel amorphous tetrafluoroethylene-hexafluoropropylene (TFE-HFP) dipolymers, and other copolymers containing TFE, HFP and a third monomer, many of which are more random than previous amorphous TFE-HFP copolymers, as well as a novel high productivity continuous process for making these polymers. The polymers are particularly useful in the form of coatings, films and encapsulants.
摘要翻译： 本文公开了新型无定形四氟乙烯 - 六氟丙烯（TFE-HFP）二元聚合物，以及含有TFE，HFP和第三单体的其它共聚物，其中许多比以前的无定形TFE-HFP共聚物更随机，以及新颖的高生产率连续方法 用于制备这些聚合物。 聚合物特别可用于涂料，薄膜和密封剂的形式。
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公开(公告)号：US5478905A
公开(公告)日：1995-12-26
申请号：US384068
申请日：1995-02-06
IPC分类号： C07C313/20 , C07C317/04 , C07C317/18 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , C08L23/02 , C08L27/18 , C09D123/02 , C09D127/18 , C09D127/20 , C08F14/18
CPC分类号： C09D127/20 , C07C313/20 , C07C317/04 , C07C317/18 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/265 , C08F214/28 , C08L23/02 , C08L23/06 , C09D123/02 , C09D127/18 , C08L2205/08 , C08L27/18 , C08L51/06 , C08L77/00
摘要： Disclosed herein are novel amorphous tetrafluoroethylene/hexafluoropropylene (TFE/HFP) copolymers, which are more random than previous amorphous TFE/HFP copolymers, as well as a novel high productivity continuous process for making these polymers. The polymers are particularly useful in the form of coatings, films and encapsulants.
摘要翻译： 本文公开了新型无定形四氟乙烯/六氟丙烯（TFE / HFP）共聚物，其比先前的无定形TFE / HFP共聚物更随机，以及用于制备这些聚合物的新型高生产率连续方法。 聚合物特别可用于涂料，薄膜和密封剂的形式。
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公开(公告)号：US5356986A
公开(公告)日：1994-10-18
申请号：US107645
申请日：1993-08-20
申请人： Charles W. Stewart , Peter D. Spohn
发明人： Charles W. Stewart , Peter D. Spohn
IPC分类号： B32B27/30 , C08F16/14 , C08F16/24 , C08K5/00 , C08K5/02 , C08L27/12 , C08L29/10 , C08L57/00 , C09J127/12 , C09J127/18
CPC分类号： C09J127/12 , C08K5/02 , C09J127/18 , Y10T428/31928
摘要： Fluoroelastomers and fluoroplastics are plasticized with high-boiling fluorinated aliphatic cyclic structures to enhance processibility or to improve final properties.
摘要翻译： 氟弹性体和氟塑料用高沸点氟化脂肪族环状结构增塑以提高加工性能或改善最终性能。
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4.发明授权
公开(公告)号：US4912166A
公开(公告)日：1990-03-27
申请号：US261738
申请日：1988-10-26
申请人： Charles W. Stewart
发明人： Charles W. Stewart
CPC分类号： C08L27/18
摘要： A blend of tetrafluoroethylene and a poly(oxy-p-phenyleneisophthaloyl-phenylene/oxy-p-phenyleneterephthaloyl- p-phenylene) (PEKK) results in improved processing of the fluoroelastomer at temperatures below the melting temperature of the PEKK and improves physical properties of cured fluoroelastomer.
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公开(公告)号：US4713418A
公开(公告)日：1987-12-15
申请号：US805543
申请日：1985-12-06
CPC分类号： C08L27/18
摘要： A composition and method for preparing it is disclosed. The composition in a blend of a cured fluoroelastomer which except for the cure sites is a perfluorocarbon and a thermoplastic copolymer of tetrafluoroethylene which is present as generally spherical particles having a particle size of less than 10 microns. The composition is prepared by blending the fluoroelastomer and thermoplastic copolymer at a temperature above the melting point of the thermoplastic copolymer followed by curing the fluoroelastomer.
摘要翻译： 公开了一种制备组合物和方法。 除了固化部位之外的固化的含氟弹性体的共混物中的组合物是全氟化碳和四氟乙烯的热塑性共聚物，其作为通常为粒径小于10微米的球形颗粒存在。 通过在高于热塑性共聚物的熔点的温度下混合含氟弹性体和热塑性共聚物，然后固化含氟弹性体来制备组合物。
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公开(公告)号：US5547761A
公开(公告)日：1996-08-20
申请号：US457080
申请日：1995-06-01
申请人： George R. Chapman, Jr. , Richard A. Morgan , Charles W. Stewart , William H. Tuminello , John G. Van Alsten , Randall A. Vogel , Mark E. Wagman
发明人： George R. Chapman, Jr. , Richard A. Morgan , Charles W. Stewart , William H. Tuminello , John G. Van Alsten , Randall A. Vogel , Mark E. Wagman
IPC分类号： C08F214/26 , C08L23/02 , C09D127/18 , B32B27/00
CPC分类号： C09D127/18 , C08F214/26 , C08L23/02 , Y10T428/31544 , Y10T428/31855
摘要： Copolymers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) having high HFP content and end-of-melting temperature, T.sub.m (end), as low as 200.degree. C. are disclosed. Exceptional performance as a processing aid in polyolefins results from having T.sub.m (end) of the TFE/HFP copolymer close to the processing temperature of the polyolefin. These TFE/HFP copolymers are soluble in fluorinated cyclic solvents. Copolymer/solvent systems copolymer at significant concentrations in selected solvents are fluid and stable at room temperature.
摘要翻译： 公开了具有高HFP含量和末端熔融温度Tm（末端）低至200℃的四氟乙烯（TFE）和六氟丙烯（HFP）的共聚物。 由于TFE / HFP共聚物的Tm（末端）接近聚烯烃的加工温度，所以作为聚烯烃的加工助剂具有卓越的性能。 这些TFE / HFP共聚物可溶于氟化环状溶剂。 在选择的溶剂中显着浓度的共聚物/溶剂体系共聚物在室温下是流动性和稳定性的。
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公开(公告)号：US4904726A
公开(公告)日：1990-02-27
申请号：US280923
申请日：1988-12-09
IPC分类号： C08F214/26 , C08F259/08 , C08L27/18 , C08L51/06
CPC分类号： C08L27/18 , C08F214/26 , C08F259/08 , C08L51/06 , Y10S525/902
摘要： Dispersion-process-produced, non-melt-processible, particulate, core-shell, tetrafluoroethylene copolymer comprising recurring units of tetrafluoroethylene and modifying recurring units of at least one ethylenically unsaturated comonomer that is copolymerizable with the tetrafluoroethylene, the number of recurring units of comonomer in the shell being sufficient to enable the copolymer to compound uniformly with an elastomer or plastic without forming visible agglomerates, and blends thereof with elastomeric and plastic resins.
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公开(公告)号：US4503192A
公开(公告)日：1985-03-05
申请号：US568888
申请日：1984-01-06
IPC分类号： C08K3/22 , C08L1/00 , C08L23/00 , C08L23/06 , C08L23/26 , C08L23/28 , C08L23/34 , C08L27/00 , C08L101/00
CPC分类号： C08L23/286 , C08L23/34 , C08L23/06
摘要： Blends of elastomers of chlorinated or chlorosulfonated polyethylene and ultra high molecular weight, i.e. at least one million, when cured with conventional curing systems for the chlorinated or chlorosulfonated polyethylene have higher tear strengths at temperatures of about 150.degree. C. than do the unblended elastomers. The amount of polyethylene in the blend is 5 to 50 parts by weight per 100 parts by weight of elastomer. The blend, thus produced has a modulus (M.sub.100) of greater than 1000 psi prior to curing.
摘要翻译： 氯化或氯磺化聚乙烯的弹性体和超高分子量的共混物，即至少一百万，当用常规的氯化或氯磺化聚乙烯的固化体系固化时，在比共混弹性体高约150℃的温度下具有较高的撕裂强度。 共混物中的聚乙烯的量为每100重量份弹性体5至50重量份。 如此制备的共混物在固化之前的模量（M100）大于1000psi。
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公开(公告)号：US5013792A
公开(公告)日：1991-05-07
申请号：US572921
申请日：1990-08-29
CPC分类号： C08L23/02 , B29C47/0883 , C08L101/00 , C08L25/06 , C08L67/00 , C08L77/00 , B29C47/0016 , B29C47/0021 , B29C47/0023 , C08L2205/06 , C08L27/12
摘要： Polymer blend composition having improved processibility and comprising:(a) a major portion of a difficultly melt-processible polymer, and(b) a minor portion of:(1) at least an effective amount, to improve processibility, of a fluorocarbon copolymer which at the melt-processing temperature of (a) is either in a melted form if crystalline, or is above its glass transition temperature if amorphous, and(2) at least an effective amount, to improve processibility, of at least one tetrafluoroethylene homopolymer or copolymer of tetrafluoroethylene and at least one monomer copolymerizable therewith, wherein the mole ratio of fluorine to hydrogen is at least 1:1, and which is solid at the melt-processing temperature of (a);masterbatches comprised of the processing aid; and processes utilizing the processing aid.
摘要翻译： 具有改进的加工性的聚合物共混物组合物包括：（a）难熔融聚合物的主要部分，和（b）少量部分：（1）至少有效量的改善氟碳共聚物的加工性 在（a）的熔融加工温度下，如果是结晶态，则其为熔融形式，或者如果是无定形的，则高于其玻璃化转变温度，和（2）至少一种有效量以提高至少一种四氟乙烯均聚物的加工性 四氟乙烯和至少一种可与其共聚的单体的共聚物，其中氟与氢的摩尔比至少为1:1，并且在（a）的熔融加工温度下为固体; 由加工助剂组成的母料; 以及利用加工助剂的方法。
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公开(公告)号：US4963609A
公开(公告)日：1990-10-16
申请号：US430138
申请日：1989-11-01
IPC分类号： C08J3/12 , C08F14/24 , C08F214/24 , C08F214/26 , C08K3/20 , C08K3/22 , C08L27/12 , C08L27/18 , C08L57/00 , H01B3/44
CPC分类号： H01B3/44 , C08K3/22 , C08L27/18 , C08L2205/02 , Y10T428/2938
摘要： A low smoke and flame-resistant fluoropolymer composition, useful as insulation in a plenum cable and comprised of a base polymer of ethylene units, tetrafluoroethylene and/or chlorotrifluoroethylene units, and fluorine-containing, non-telogenic termonomer units; a metal oxide; and a polytetrafluoroethylene drip suppressant.
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