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公开(公告)号:US20240400808A1
公开(公告)日:2024-12-05
申请号:US18807116
申请日:2024-08-16
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI , Shota YAMAMOTO , Hiroaki NISHIMURA , Azusa YAGI
IPC: C08L23/08 , B32B7/12 , B32B15/082 , B32B15/085 , B32B15/20 , B32B17/10 , B32B27/08 , B32B27/32 , C08F210/02 , C08F212/08 , C08F212/36 , C08K5/14 , C08L25/08
Abstract: A laminate has an olefin-aromatic vinyl compound-aromatic polyene copolymer and a metal foil. The number average molecular copolymer weight is between 5000 and 100000; the aromatic vinyl compound monomer is aromatic vinyl compound having between 8 and 20 carbon atoms, and the aromatic vinyl compound monomer unit content is between 10 and 60 mass %; the aromatic polyene is selected having between 5 and 20 carbon atoms and vinyl and/or vinylene groups in the molecule, the content derived from the aromatic polyene unit is between 1.5 and 20 pieces per number average molecular weight; and the olefin is selected having between 2 and 20 carbon atoms, being ethylene alone, or having a mass ratio of α-olefin monomer components other than ethylene to an ethylene monomer component contained in the olefin, of 1/7 or less, and the total monomer units of the olefin, aromatic vinyl compound, and aromatic polyene is 100 mass %.
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公开(公告)号:US20170037174A1
公开(公告)日:2017-02-09
申请号:US15301247
申请日:2015-04-01
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI , Tometomo UCHIDA , Ayumu TSUKAMOTO
IPC: C08F255/02 , C08L25/06
CPC classification number: C08F255/02 , C08F4/65912 , C08F210/16 , C08F297/02 , C08L25/06 , C08L53/00 , C08L2205/03 , C08L2205/06 , C08L2205/08 , C08F210/02 , C08F212/08 , C08F212/36 , C08F210/14 , C08F4/65927 , C08L23/12
Abstract: The present invention addresses the problem of providing a cross-copolymer having excellent flexibility, heat resistance, cold resistance and mechanical properties. The present invention also addresses the problem of providing a resin composition which is prepared using the cross-copolymer, has excellent compatibility with polyolefin resins and aromatic resins, and has excellent flexibility, heat resistance and cold resistance.The problem can be solved by a cross-copolymer produced by a polymerization process comprising a coordination polymerization step and a crossing step, wherein the coordination polymerization step comprises copolymerizing an ethylene monomer, a specific olefin monomer and an aromatic polyene together using a single site coordination polymerization catalyst to synthesize an ethylene-olefin-aromatic polyene copolymer that meets a specific requirement, and the crossing step comprises carrying out a polymerization in the co-presence of the ethylene-olefin-aromatic polyene copolymer and an aromatic vinyl compound monomer using an anionic polymerization initiator or a radical polymerization initiator.
Abstract translation: 该问题可以通过由包含配位聚合步骤和交联步骤的聚合方法制备的交联共聚物来解决,其中配位聚合步骤包括使用单位点配位使乙烯单体,特定烯烃单体和芳族多烯共聚 聚合催化剂以合成满足特定要求的乙烯 - 烯烃 - 芳族多烯共聚物,交联步骤包括在乙烯 - 烯烃 - 芳族多烯共聚物和芳族乙烯基化合物单体的共存下使用阴离子 聚合引发剂或自由基聚合引发剂。
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公开(公告)号:US20250010581A1
公开(公告)日:2025-01-09
申请号:US18701376
申请日:2022-10-12
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI , Ryosuke KANTO
IPC: B32B15/082 , B32B15/20 , H01P3/08
Abstract: A multilayer structure includes at least one insulating layer(s), at least one resin layer(s), and at least one copper foil(s) each having a smooth surface and a roughened surface, wherein the insulating layer contains an olefin-aromatic vinyl compound-aromatic polyene copolymer and a surface modifier, wherein the resin layer contains one or more selected from the group consisting of polyimide, liquid crystal polymer, polyphenylene ether, polyfunctional aromatic vinyl resin, epoxy resin, and the same composition as in the insulating layer, wherein at least one surface of the respective insulating layer(s) is bonded to a smooth surface of the copper foil, and wherein, for each respective resin layer: at least one surface of the resin layer is bonded to the roughened surface, and the resin layer is not bonded to the smooth surface; or both surfaces of the resin layer are not bonded to the copper foil.
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公开(公告)号:US20230147757A1
公开(公告)日:2023-05-11
申请号:US17920631
申请日:2021-04-22
Applicant: DENKA COMPANY LIMITED
Inventor: Takuto OKABE , Motoharu FUKAZAWA , Toru ARAI
CPC classification number: C01B33/18 , C08K3/36 , C01P2004/32 , C01P2002/74
Abstract: A spherical silica powder which, when heated from 25° C. up to 1000° C. at a rate of 30° C./min, desorbs water molecules in an amount of 0.01 mmol/g or less at 500° C. to 1000° C., and which has a specific surface area of 1 to 30 m2/g.
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公开(公告)号:US20230287222A1
公开(公告)日:2023-09-14
申请号:US18015484
申请日:2021-07-13
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI
IPC: C09D4/06 , C09D123/08 , C08F210/02 , C08F210/14 , C08F212/08 , C08F212/36 , C08F4/6592 , C08F4/642 , C08F222/40 , C08K5/14 , C08L71/12 , H01B3/44
CPC classification number: C09D4/06 , C09D123/0838 , C09D123/0815 , C08F210/02 , C08F210/14 , C08F212/08 , C08F212/36 , C08F4/65927 , C08F4/6428 , C08F222/40 , C08K5/14 , C08L71/12 , H01B3/441 , H01B3/442 , C08L2312/00 , C08L2314/06 , C08L2203/20
Abstract: A varnish having low viscosity and a cured product thereof having a high degree of cross-linking, exhibiting excellent low dielectric properties and mechanical properties at high temperature, and a low coefficient of linear thermal expansion are provided. A varnish comprising an olefin-aromatic vinyl compound-aromatic polyene copolymerized oligomer satisfying specific conditions, one or more selected from the following (a) to (c), and (d) a solvent: (a) a curing agent; (b) one or a plurality of resins selected from a hydrocarbon-based elastomer, a polyphenylene ether-based resin, an olefin-aromatic vinyl compound-aromatic polyene copolymer, and an aromatic polyene-based resin; and (c) a polar monomer; and a cured product of the varnish.
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公开(公告)号:US20240400807A1
公开(公告)日:2024-12-05
申请号:US18799459
申请日:2024-08-09
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI , Shota YAMAMOTO , Hiroaki NISHIMURA , Azusa YAGI
IPC: C08L23/08 , B32B7/12 , B32B15/082 , B32B15/085 , B32B15/20 , B32B17/10 , B32B27/08 , B32B27/32 , C08F210/02 , C08F212/08 , C08F212/36 , C08K5/14 , C08L25/08
Abstract: A curable composition includes an olefin-aromatic vinyl compound-aromatic polyene copolymer satisfying conditions (1) to (4) and an additive resin, which is a polyphenylene ether. (1) The number average molecular weight of the copolymer is 5000 to 100000. (2) The aromatic vinyl compound monomer has 8 to 20 carbon atoms, and the content of the unit of the monomer is 0 to 70 mass %. (3) The aromatic polyene is selected from polyenes having 5 to 20 carbon atoms and a plurality of vinyl and/or vinylene groups in the molecule, and the content of the groups is 1.5 to 20 pieces per number average molecular weight. (4) The olefin is selected from olefins having 2 to 20 carbon atoms, and the total monomer units of the olefin, aromatic vinyl compound, and aromatic polyene is 100 mass %.
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公开(公告)号:US20230193090A1
公开(公告)日:2023-06-22
申请号:US17923377
申请日:2021-05-17
Applicant: DENKA COMPANY LIMITED
Inventor: Tometomo UCHIDA , Toru ARAI , Takashi DOMOTO , Takako TANIGAWA , Jun WATANABE , Megumi SUDO , Jun YOSHIDA
CPC classification number: C09J123/22 , C08K5/0025 , C08F2/44 , C08F2/48 , H01L21/02304 , H01L21/0231 , C08K5/101 , C08F20/20 , C09J11/06
Abstract: A composition for temporary bonding, includes: (A) a (meth)acrylate having the following (A-1) and (A-2): (A-1) a monofunctional (meth)acrylate whose side chain is an alkyl group having 18 or more carbon atoms and homopolymer has a Tg of −100° C. to 60° C., and (A-2) a polyfunctional (meth)acrylate; (B) a polyisobutene homopolymer and/or a polyisobutene copolymer; and (C) a photo radical polymerization initiator.
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公开(公告)号:US20230023889A1
公开(公告)日:2023-01-26
申请号:US17782000
申请日:2020-12-01
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI , Shota YAMAMOTO , Hiroaki NISHIMURA , Azusa YAGI
Abstract: A curable composition includes an olefin-aromatic vinyl compound-aromatic polyene copolymer satisfying conditions (1) to (4) and an additive resin, which is at least one of a hydrocarbon-based elastomer, polyphenylene ether, olefin-aromatic vinyl compound-aromatic polyene copolymerized oligomer, and aromatic polyene-based resin. (1) The number average molecular weight of the copolymer is 5000 to 100000. (2) The aromatic vinyl compound monomer has 8 to 20 carbon atoms, and the content of the unit of the monomer is 0 to 70 mass %. (3) The aromatic polyene is selected from polyenes having 5 to 20 carbon atoms and a plurality of vinyl and/or vinylene groups in the molecule, and the content of the groups is 1.5 to 20 pieces per number average molecular weight. (4) The olefin is selected from olefins having 2 to 20 carbon atoms, and the total monomer units of the olefin, aromatic vinyl compound, and aromatic polyene is 100 mass %.
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公开(公告)号:US20250084195A1
公开(公告)日:2025-03-13
申请号:US18728588
申请日:2023-01-17
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI
IPC: C08F212/08 , C08F257/02 , C08K5/14 , C09D4/06 , C09D7/20 , C09D125/08 , C09D153/02
Abstract: An aromatic vinyl compound-aromatic polyene copolymer satisfies the following conditions: the copolymer has a number average molecular weight of between 500 and 100000; the aromatic vinyl compound monomer has between 8 and 20 carbon atoms, and the content of aromatic vinyl compound monomer units is more than 70 mass %; the aromatic polyene is selected from polyenes having between 5 and 20 carbon atoms and having a plurality of vinyl and/or vinylene groups in the molecule, and the content of the vinyl and/or vinylene groups derived from aromatic polyene units is 2 pieces or more and less than 30 pieces per number average molecular weight; one or more selected from olefin monomer units having between 2 and 20 carbon atoms may be included, wherein a total amount of the aromatic vinyl compound monomer units, the aromatic polyene monomer units, and the olefin monomer units, if present, is 100 mass %.
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公开(公告)号:US20230365797A1
公开(公告)日:2023-11-16
申请号:US18026028
申请日:2021-09-09
Applicant: DENKA COMPANY LIMITED
Inventor: Toru ARAI , Azusa YAGI , Suguru ONUKI , Shota YAMAMOTO
IPC: C08L25/08 , C08F212/08 , C08F210/02 , C08K7/18 , C08L23/08 , C08J5/18 , H01B3/44
CPC classification number: C08L25/08 , C08F212/08 , C08F210/02 , C08K7/18 , C08L23/0838 , C08J5/18 , H01B3/441 , C08F2800/20 , C08K2201/006 , C08L2205/025 , C08L2203/30 , C08J2325/08 , C08J2425/08 , C08J2323/08
Abstract: A composition comprises: a resin component including an olefin-aromatic vinyl compound-aromatic polyene copolymer satisfying all the following conditions (1) to (4): (1) a number average molecular weight of the copolymer is 500 or more and 100000 or less; (2) the aromatic vinyl compound monomer is an aromatic vinyl compound having 8 or more and 20 or less carbon atoms, and a content of a unit of the aromatic vinyl compound monomer is 0 mass % or more and 70 mass % or less; (3) the aromatic polyene is one or more selected from polyenes having 5 or more and 20 or less carbon atoms and having a plurality of vinyl groups and/or vinylene groups in the molecule, and a content of the vinyl groups and/or the vinylene groups derived from the unit of the aromatic polyene is 1.5 pieces or more and less than 20 pieces per number average molecular weight; and (4) the olefin is one or more selected from olefins having 2 or more and 20 or less carbon atoms, and a total of units of the olefin monomer, the aromatic vinyl compound monomer, and the aromatic polyene monomer is 100 mass %; and a surface-treated silica. The volume ratio between the resin component and the silica is in the range of 98 to 15:2 to 85. A cured product of the composition has a value of the dielectric tangent obtained by resonator method at a measurement frequency of 10 GHz and/or a measurement frequency range of 25 GHz to 40 GHz of 1.2×10−3 or less and a storage elastic modulus at 250° C. in the range of 10 MPa or more and 10 GPa or less.
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