公开(公告)号：US20150167231A1

公开(公告)日：2015-06-18

申请号：US14382325

申请日：2013-03-07

Applicant: DIC Corporation ,  Kyoto University

Inventor： Takeshi Semba ,  Akihiro Ito ,  Takahiro Uesaka ,  Kazuo Kitagawa ,  Hiroyuki Yano ,  Akihiro Sato ,  Tomoaki Yoshimura

IPC: D06M15/356 ,  C08L39/00 ,  C08L77/06

CPC classification number: D06M15/3562 ,  B82Y30/00 ,  C08B15/00 ,  C08B15/06 ,  C08J5/005 ,  C08J2355/02 ,  C08J2377/00 ,  C08L1/02 ,  C08L39/00 ,  C08L55/02 ,  C08L77/02 ,  C08L77/06 ,  C08L2205/16 ,  D10B2201/20

Abstract: The present invention provides a novel cationically modified cellulose nanofiber. More specifically, the present invention provides a cellulose nanofiber that is cationically modified with a cationic polymer compound comprising repeating units derived from diallylamine.

Abstract translation: 本发明提供一种新型的阳离子改性纤维素纳米纤维。 更具体地说，本发明提供一种纤维素纳米纤维，该纤维素纳米纤维用包含衍生自二烯丙基胺的重复单元的阳离子聚合物化合物进行阳离子改性。

公开(公告)号：US09512304B2

公开(公告)日：2016-12-06

申请号：US14383230

申请日：2013-02-26

Applicant: DIC Corporation ,  Seiko PMC Corporation ,  Kyoto University ,  Kyoto Municipal Institute of Industrial Technology and Culture

Inventor： Hiroyuki Yano ,  Akihiro Sato ,  Tomoaki Yoshimura ,  Yuko Igarashi ,  Daisuke Kabusaki ,  Fumiaki Nakatsubo ,  Hiroaki Okumura ,  Takeshi Semba ,  Kazuo Kitagawa ,  Hiromasa Kataoka ,  Kazuhiro Shintani

IPC: C08L1/10 ,  C08B3/12 ,  D06M13/192 ,  C08J3/20 ,  C08J3/205 ,  C08L101/00 ,  C08B3/16 ,  C08J5/00 ,  C08L23/06 ,  C08L23/12 ,  C08L59/02 ,  C08L23/02 ,  C08L23/04 ,  C08L23/10 ,  C08L77/02 ,  C08J3/22 ,  C08L59/00 ,  C08L97/00 ,  D06M101/06

CPC classification number: C08L1/10 ,  C08B3/12 ,  C08B3/16 ,  C08J3/20 ,  C08J3/205 ,  C08J3/226 ,  C08J5/00 ,  C08J2323/06 ,  C08J2423/06 ,  C08K3/26 ,  C08K5/0083 ,  C08K5/5333 ,  C08L23/02 ,  C08L23/04 ,  C08L23/06 ,  C08L23/10 ,  C08L23/12 ,  C08L51/06 ,  C08L59/00 ,  C08L59/02 ,  C08L67/04 ,  C08L75/00 ,  C08L77/02 ,  C08L97/005 ,  C08L101/00 ,  C08L2201/08 ,  C08L2205/16 ,  C08L2207/062 ,  D06M13/192 ,  D06M2101/06 ,  C08L77/06

Abstract: The present invention provides a method for producing a resin composition, which, by means of simple steps, can uniformly disperse microfibrillated plant fiber in a highly hydrophobic resin and can impart enhanced mechanical strength to a molding material obtained by molding the resin composition. The present invention further provides a resin composition having excellent heat resistance and low linear thermal expansion. The present invention relates to a method for producing a resin composition, the method including a step of mixing a thermoplastic resin or thermosetting resin (A), and modified plant fiber (b) or modified microfibrillated plant fiber (B), in the presence of an organic liquid (C), the modified plant fiber (b) or modified microfibrillated plant fiber (B) being obtained by modification with an alkyl or alkenyl succinic anhydride in a liquid capable of swelling microfibrillated plant fiber (B′) or plant fiber (b).

Abstract translation: 本发明提供了一种树脂组合物的制造方法，其通过简单的步骤可以将微纤化植物纤维均匀地分散在高疏水性树脂中，并且能够赋予通过模塑树脂组合物获得的成型材料更高的机械强度。 本发明还提供了具有优异的耐热性和低线性热膨胀性的树脂组合物。 本发明涉及一种树脂组合物的制造方法，其特征在于，包括将热塑性树脂或热固性树脂（A）与改性植物纤维（b）或改性微纤化植物纤维（B）混合的工序， 通过在能够溶胀微纤化植物纤维（B'）或植物纤维（B'）的液体中用烷基或链烯基琥珀酸酐改性而获得的有机液体（C），改性植物纤维（b）或改性微纤化植物纤维（B） b）。

公开(公告)号：US20160002461A1

公开(公告)日：2016-01-07

申请号：US14770556

申请日：2014-02-26

Applicant: DIC CORPORATION ,  KYOTO UNIVERSITY

Inventor： Yoshinobu Tsujii ,  Keita Sakakibara ,  Taiyo Aoyagi ,  Hiroyuki Yano

IPC: C08L53/00 ,  C08L101/00 ,  C08F293/00 ,  C08L1/02

CPC classification number: C08L53/00 ,  C08F293/00 ,  C08F297/04 ,  C08J3/20 ,  C08J2323/04 ,  C08J2323/10 ,  C08J2453/00 ,  C08L1/02 ,  C08L23/10 ,  C08L53/02 ,  C08L101/00 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2205/16 ,  C08L2310/00 ,  C08L97/02

Abstract: The present invention provides a composition comprising cellulose and a dispersant, the composition being capable of improving the dispersibility of cellulose in resin. More specifically, the present invention provides a composition comprising cellulose and a dispersant, the dispersant comprising a resin affinity segment A and a cellulose affinity segment B and having a block copolymer structure or gradient copolymer structure.

Abstract translation: 本发明提供包含纤维素和分散剂的组合物，该组合物能够提高纤维素在树脂中的分散性。 更具体地，本发明提供包含纤维素和分散剂的组合物，所述分散剂包含树脂亲和链段A和纤维素亲和链段B，并具有嵌段共聚物结构或梯度共聚物结构。

公开(公告)号：US20150105499A1

公开(公告)日：2015-04-16

申请号：US14383230

申请日：2013-02-26

Applicant: DIC Corporation Tokyo1748520 ,  Seiko PMC Corporation ,  Kyoto University ,  Kyoto Municipal Institute of Industrial Technology and Culture

Inventor： Hiroyuki Yano ,  Akihiro Sato ,  Tomoaki Yoshimura ,  Yuko Igarashi ,  Daisuke Kabusaki ,  Fumiaki Nakatsubo ,  Hiroaki Okumura ,  Takeshi Semba ,  Kazuo Kitagawa ,  Hiromasa Kataoka ,  Kazuhiro Shintani

IPC: C08L1/10 ,  C08L97/00 ,  C08L59/00 ,  C08L23/12 ,  C08L23/06 ,  C08L77/02

CPC classification number: C08L1/10 ,  C08B3/12 ,  C08B3/16 ,  C08J3/20 ,  C08J3/205 ,  C08J3/226 ,  C08J5/00 ,  C08J2323/06 ,  C08J2423/06 ,  C08K3/26 ,  C08K5/0083 ,  C08K5/5333 ,  C08L23/02 ,  C08L23/04 ,  C08L23/06 ,  C08L23/10 ,  C08L23/12 ,  C08L51/06 ,  C08L59/00 ,  C08L59/02 ,  C08L67/04 ,  C08L75/00 ,  C08L77/02 ,  C08L97/005 ,  C08L101/00 ,  C08L2201/08 ,  C08L2205/16 ,  C08L2207/062 ,  D06M13/192 ,  D06M2101/06 ,  C08L77/06

Abstract: The present invention provides a method for producing a resin composition, which, by means of simple steps, can uniformly disperse microfibrillated plant fiber in a highly hydrophobic resin and can impart enhanced mechanical strength to a molding material obtained by molding the resin composition. The present invention further provides a resin composition having excellent heat resistance and low linear thermal expansion. The present invention relates to a method for producing a resin composition, the method including a step of mixing a thermoplastic resin or thermosetting resin (A), and modified plant fiber (b) or modified microfibrillated plant fiber (B), in the presence of an organic liquid (C), the modified plant fiber (b) or modified microfibrillated plant fiber (B) being obtained by modification with an alkyl or alkenyl succinic anhydride in a liquid capable of swelling microfibrillated plant fiber (B′) or plant fiber (b).

Abstract translation: 本发明提供了一种树脂组合物的制造方法，其通过简单的步骤可以将微纤化植物纤维均匀地分散在高疏水性树脂中，并且能够赋予通过模塑树脂组合物获得的成型材料更高的机械强度。 本发明还提供了具有优异的耐热性和低线性热膨胀性的树脂组合物。 本发明涉及一种树脂组合物的制造方法，其特征在于，包括将热塑性树脂或热固性树脂（A）与改性植物纤维（b）或改性微纤化植物纤维（B）混合的工序， 通过在能够溶胀微纤化植物纤维（B'）或植物纤维（B'）的液体中用烷基或链烯基琥珀酸酐改性而获得的有机液体（C），改性植物纤维（b）或改性微纤化植物纤维（B） b）。

公开(公告)号：US10858485B2

公开(公告)日：2020-12-08

申请号：US16085686

申请日：2017-03-16

Applicant: KYOTO UNIVERSITY ,  NIPPON PAPER INDUSTRIES CO., LTD

Inventor： Hiroyuki Yano ,  Hiroaki Okumura ,  Hiromasa Kataoka ,  Hironari Sano

IPC: C08J3/22 ,  C08L101/00 ,  C08L97/02 ,  C08J3/00 ,  C08J5/04

Abstract: An object of the present invention is to provide a highly versatile master batch for producing a fiber-reinforced resin composition with high strength even when a highly hydrophobic resin is used as a resin for dilution (a resin that constitutes a fiber-reinforced resin composition). The master batch contains AcylMFs (A), a Pm (B), and a Com (C) and is for use in the production of a fiber-reinforced resin composition by mixing with a Pd (D), wherein the AcylMFs (A), Pm (B), Com (C), and Pd (D) satisfy the following conditions: (a) the AcylMFs (A) have an SPacylmf of 10 or more; (b) the Pm (B) has an SPpm of 9 to 15, and the SPpm is equal to or greater than the SPpd of the Pd (D); and (c) the Com (C) has an SPcom equal to or less than the SPacylmf of the AcylMFs (A).

公开(公告)号：US10676615B2

公开(公告)日：2020-06-09

申请号：US15556220

申请日：2016-03-17

Applicant: Kyoto University ,  KYOTO MUNICIPAL INSTITUTE OF INDUSTRIAL TECHNOLOGY AND CULTURE ,  NIPPON PAPER INDUSTRIES CO., LTD.

Inventor： Takeshi Semba ,  Akihiro Ito ,  Takahiro Uesaka ,  Kazuo Kitagawa ,  Fumiaki Nakatsubo ,  Hiroyuki Yano

IPC: C08L77/02 ,  C08L1/08 ,  C08L101/00 ,  C08L23/12 ,  C08L67/04 ,  C08J5/04 ,  C08B3/06 ,  C08B3/20 ,  C08L23/06 ,  C08L25/06 ,  C08L51/06 ,  C08L55/02 ,  C08L59/02 ,  B82Y30/00

Abstract: An object of the present invention is to provide a fiber-reinforced resin composition in which fibers with good dispersibility and a resin in which the fibers are easily dispersed have been suitably composited; and a method for producing the fiber-reinforced resin composition. Specifically, the object is to provide a fiber-reinforced resin composition that comprises chemically modified CNFs and a thermoplastic resin, and that has improved physical properties due to the suitable compositing of the fibers with the resin; and a method for producing the fiber-reinforced resin composition. The fiber-reinforced resin composition comprises chemically modified CNFs (A) and a thermoplastic resin (B), wherein the chemically modified CNFs and the thermoplastic resin satisfy the following conditions: (a) the ratio R of the solubility parameter (SPcnf) of the chemically modified CNFs (A) to the solubility parameter (SPpol) of the thermoplastic resin (B), SPcnf/SPpol, is in the range of 0.87 to 1.88; and (b) the chemically modified CNFs (A) have a degree of crystallinity of 42.7% or higher.

公开(公告)号：US20180037737A1

公开(公告)日：2018-02-08

申请号：US15556220

申请日：2016-03-17

Applicant: Kyoto University ,  KYOTO MUNICIPAL INSTITUTE OF INDUSTRIAL TECHNOLOGY AND CULTURE ,  NIPPON PAPER INDUSTRIES CO., LTD.

Inventor： Takeshi Semba ,  Akihiro Ito ,  Takahiro Uesaka ,  Kazuo Kitagawa ,  Fumiaki Nakatsubo ,  Hiroyuki Yano

IPC: C08L77/02 ,  C08L51/06 ,  C08B3/20 ,  C08L25/06 ,  C08L23/06 ,  C08B3/06 ,  C08L59/02 ,  C08L55/02

Abstract: An object of the present invention is to provide a fiber-reinforced resin composition in which fibers with good dispersibility and a resin in which the fibers are easily dispersed have been suitably composited; and a method for producing the fiber-reinforced resin composition. Specifically, the object is to provide a fiber-reinforced resin composition that comprises chemically modified CNFs and a thermoplastic resin, and that has improved physical properties due to the suitable compositing of the fibers with the resin; and a method for producing the fiber-reinforced resin composition. The fiber-reinforced resin composition comprises chemically modified CNFs (A) and a thermoplastic resin (B), wherein the chemically modified CNFs and the thermoplastic resin satisfy the following conditions: (a) the ratio R of the solubility parameter (SPcnf) of the chemically modified CNFs (A) to the solubility parameter (SPpol) of the thermoplastic resin (B), SPcnf/SPpol, is in the range of 0.87 to 1.88; and (b) the chemically modified CNFs (A) have a degree of crystallinity of 42.7% or higher.