公开(公告)号：US11912871B2

公开(公告)日：2024-02-27

申请号：US17251843

申请日：2018-07-12

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Baoqing Zheng ,  Yan Wu ,  Jia Tang ,  James C. Bohling ,  Juan Zhao ,  Yujiang Wang

IPC: C08L83/10 ,  C08F2/26 ,  C08F220/06 ,  C08F220/14 ,  C08F220/18 ,  C08F230/02 ,  C08G77/00 ,  C08G77/16 ,  C08G77/20 ,  C08G77/44 ,  C08K5/37 ,  C08L25/14 ,  C09D5/08

CPC classification number: C08L83/10 ,  C08F2/26 ,  C08F220/06 ,  C08F220/14 ,  C08F220/1804 ,  C08F230/02 ,  C08G77/16 ,  C08G77/20 ,  C08G77/44 ,  C08G77/80 ,  C08K5/37 ,  C08L25/14 ,  C09D5/08 ,  C08L2201/50 ,  C08L2201/52

Abstract: An aqueous dispersion comprising a silicone-acrylic polymer with reduced coagulum, a process of preparing the aqueous dispersion, and an aqueous coating composition comprising the aqueous dispersion and providing coatings with improved corrosion resistance.

公开(公告)号：US11505716B2

公开(公告)日：2022-11-22

申请号：US16628691

申请日：2017-07-11

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Daoshu Lin ,  Jianming Xu ,  Shuyu Duan ,  Jian Zou ,  James C. Bohling

IPC: C09D7/65 ,  C09D7/20 ,  C09D7/63 ,  C09D133/06 ,  C08F220/18 ,  A61L9/04

Abstract: An aqueous dispersion, an aqueous coating composition comprising the aqueous dispersion, and coatings made therefrom capable of slow release of fragrance.

公开(公告)号：US20210253893A1

公开(公告)日：2021-08-19

申请号：US16973604

申请日：2018-07-10

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Yan Li ,  Tao Wang ,  Junyu Chen ,  Tao Wang ,  James C. Bohling ,  Zhi Juan Gong ,  Yuehan Hu

IPC: C09D133/12 ,  C08F220/14

Abstract: An aqueous dispersion of multistage polymer particles comprising a specific oligomer prepared from polymerization of monomers comprising an alkoxylated (meth)acrylate providing aqueous coating compositions with both good flow-and-leveling property and extended open time.

公开(公告)号：US10851186B2

公开(公告)日：2020-12-01

申请号：US16490977

申请日：2017-04-24

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Yan Li ,  Junyu Chen ,  Tao Wang ,  Zhi Juan Gong ,  James C. Bohling ,  Cheng Shen

IPC: C08F2/22 ,  C09D7/40 ,  C08F212/08 ,  C08F220/06 ,  C08F220/14 ,  C08F230/02 ,  C08L71/02 ,  C09D5/02 ,  C08F220/18

Abstract: An aqueous polymer dispersion, a process of preparing the aqueous polymer dispersion, and an aqueous coating composition comprising the aqueous polymer dispersion and providing coatings with improved water repellency and/or improved hydrophobic stain resistance without compromising hydrophilic stain resistance.

公开(公告)号：US20200181442A1

公开(公告)日：2020-06-11

申请号：US16628691

申请日：2017-07-11

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Daoshu Lin ,  Jianming Xu ,  Shuyu Duan ,  Jian Zou ,  James C. Bohling

IPC: C09D133/06 ,  C09D7/20 ,  C09D7/63 ,  C09D7/65 ,  C08F220/18 ,  A61L9/04

Abstract: An aqueous dispersion, an aqueous coating composition comprising the aqueous dispersion, and coatings made therefrom capable of slow release of fragrance.

公开(公告)号：US20190185674A1

公开(公告)日：2019-06-20

申请号：US16225067

申请日：2018-12-19

Applicant: Rohm and Haas Company ,  The Regents of the University of California ,  Dow Global Technologies LLC

Inventor： James C. Bohling ,  Yijun Guo ,  Alexander Katz ,  Manish Mishra ,  Clayton J. Radke ,  John A. Roper, III ,  Antony K. Van Dyk

IPC: C09C1/36 ,  C09C3/12

CPC classification number: C09C1/3684 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/22 ,  C01P2006/90 ,  C08K9/08 ,  C09C3/12 ,  C09D5/028 ,  C09D7/62

Abstract: The present invention is a composition comprising an aqueous dispersion of metal oxide pigment particles coated with a polymer comprising structural units of an alkyltrihydroxysilane or a salt thereof. The composition of the present invention provides hydrophobicity to pigment particles, thereby imparting water resistance, and allows for high loadings of pigment in water without increased viscosity.

公开(公告)号：US20150073134A1

公开(公告)日：2015-03-12

申请号：US14479113

申请日：2014-09-05

Applicant: The Regents of the University of California ,  Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander S. Katz ,  Oz M. Gazit ,  James C. Bohling ,  John A. Roper, III

IPC: C08B37/00

CPC classification number: C08B37/0024 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3274 ,  B01J20/3278 ,  B01J20/3289 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C08B11/20 ,  C09C1/3054 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/309 ,  C09C1/3661 ,  C09C1/3676 ,  C09C1/3684 ,  C09C1/3692 ,  C09C1/407 ,  C09C3/10 ,  C09D101/28 ,  C09D105/00

Abstract: The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

Abstract translation: 本发明是一种多层复合材料，其包含多孔金属氧化物颗粒，其通过无机醚基团与第一多羟基官能化聚合物的一个或多个位点共价键合。 该第一聚合物又通过无机醚基团共价键合到第二多羟基官能化聚合物的一个或多个位点。 多层复合材料可以通过使多孔无机氧化物颗粒与足够量的OH-反应性交联剂接触以形成吸附有交联剂的金属氧化物颗粒，然后使无机氧化物颗粒与多羟基官能化聚合物 在反应条件下。

公开(公告)号：US20230312969A1

公开(公告)日：2023-10-05

申请号：US18016465

申请日：2020-07-31

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Caifeng Wang ,  Jianming Xu ,  Kok Chiew Poh ,  Yuehan Hu ,  Tao Wang ,  Juan F. Callejas ,  Philip R. Harsh ,  James C. Bohling ,  Andrew J. Swartz ,  Partha S. Majumdar ,  Joseph Tanzer

IPC: C09D133/08 ,  C09D7/61 ,  C09D7/65 ,  C09D7/40

CPC classification number: C09D133/08 ,  C09D7/61 ,  C09D7/65 ,  C09D7/67 ,  C09D7/69 ,  C09D7/70 ,  C08K2201/005 ,  C08K2201/011

Abstract: The present invention is a composition comprising an aqueous dispersion of polymer particles, polymeric organic crosslinked microspheres, and colloidal silica particles. The composition is useful in coating compositions for exterior applications to achieve a balance of excellent dirt pickup resistance and durability performance under accelerated testing conditions.

公开(公告)号：US20230058018A1

公开(公告)日：2023-02-23

申请号：US17784345

申请日：2020-11-19

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： James C. Bohling ,  Wei Gao ,  Justin Gimbal ,  Ian D. Robertson

IPC: C08L33/08 ,  C09D133/08

Abstract: The present invention relates to a composition comprising an aqueous dispersion of multiphase polymer particles comprising first polymer particles having a Tg of less than 30° C. and second polymer particles having a Tg in the range of from 100° C. to 110° C., wherein the second polymer particles are phase separated from and occluded within the first polymer particles; wherein the number average molecular weight (Mn) of the multiphase polymer particles is in the range of from 9,000 to 25,000 g/mole; and wherein the second polymer particles comprise at least 95 weight percent methyl methacrylate. The composition of the present invention is useful in a formulation that can be used to prepare a water-resistant blister free LASD coating with little or no surface defects.

公开(公告)号：US20230052817A1

公开(公告)日：2023-02-16

申请号：US17785072

申请日：2020-11-19

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： James C. Bohling ,  Justin Gimbal ,  Ian D. Robertson

IPC: C08F2/30 ,  C08F4/40 ,  C08F20/12 ,  C08F220/14 ,  C08F220/18 ,  C08F230/02

Abstract: The present invention relates to a process for preparing an aqueous dispersion of multiphase occluded polymer particles comprising the steps of a) contacting, under emulsion polymerization conditions, first monomers and a chain transfer agent to form an aqueous dispersion of first polymer particles having a Tg in the range of from −30° C. to 30° C.; then b) contacting the aqueous dispersion of first polymer particles with a second monomer under emulsion polymerization conditions to form an aqueous dispersion of second polymer particles occluded within the first polymer particles, wherein the first monomers a phosphorus acid monomer or a salt thereof; and the second monomer comprises at least 90 weight percent methyl methacrylate. The aqueous dispersion of occluded polymer particles arising from the process of the present invention is useful in a formulation that can be used to prepare a water-resistant blister free LASD coating.