摘要:
One embodiment of an ammonia gas sensor includes: a reference electrode, an ammonia selective sensing electrode and an electrolyte disposed therebetween. The sensing electrode comprises the reaction product of a main material selected from the group consisting of vanadium, tungsten, molybdenum, vanadium oxides, tungsten oxides, molybdenum oxides, and combinations comprising at least one of the foregoing main materials, and an electrically conducting material selected from the group consisting of electrically conductive metals, electrically conductive metal oxides, and combinations comprising at least one of the foregoing.
摘要:
Disclosed herein are electrochemical cells comprising a first electrode, a second electrode, and a solid oxide electrolyte disposed between and in ionic communication with the first electrode and the second electrode. The solid oxide electrolyte comprises the reaction product of a solid oxide electrolyte material, an aliovalent cation dopant, and a sintering aid selected from the group consisting of Al2O3, Ca2Al2O5, and combinations comprising at least one of the foregoing. The electrochemical cells can be utilized water electrolyzers, hydrogen pumps and for various gas sensing cells, SOFCs, and the like.
摘要翻译:本文公开了包含第一电极,第二电极和设置在第一电极和第二电极之间且与第一电极和第二电极离子连通的固体氧化物电解质的电化学电池。 固体氧化物电解质包括固体氧化物电解质材料,二价阳离子掺杂剂和选自Al 2 O 3 3,Ca 以及包含前述的至少一种的组合。 电化学电池可以使用水电解器,氢泵和各种气体感测单元,SOFC等。
摘要:
A sensor including a species selective electrode and a reference electrode having an electrolyte layer disposed therebetween; a reference gas channel in fluid communication with the reference electrode; a heater and a temperature sensor; wherein the species selective electrode is disposed on a first side of an insulating layer separating the species selective electrode from the electrolyte layer, the insulating layer having a first substantially solid area and a second area having an opening pattern extending through the insulating layer; the species selective electrode comprising a species sensing electrode portion disposed on the opening pattern of the insulating layer so as to contact the electrolyte layer through the opening pattern and a non-active electrode lead portion disposed over the first substantially solid area so that the non-active electrode lead portion is in electrical communication with the species sensing electrode portion and is free from contact with the electrolyte layer.
摘要:
Disclosed herein are NOx sensors and methods of using the same. In one embodiment, a method for sensing NOx comprises: contacting a first NOx electrode with the gas, contacting a second NOx electrode with the gas, determining a NO2 emf between the first NOX electrode and a first reference electrode, determining a NOx emf between the second NOx electrode and a second reference electrode, and determining a NO2 concentration and a NO concentration using the NO2 emf and the NOx emf. The first electrode can be at a first temperature of greater than or equal to about 700 ° C., and the second electrode can be at a second temperature of about 500 ° C. to about 650 ° C.
摘要:
A gas sensor system includes an ammonia-sensing cell for generating a signal upon exposure to an unknown gas comprising ammonia, an A/F cell for generating a signal upon exposure to hydrocarbons in the gas, a heater in thermal communication with the cells and a housing in which the cells and the heater are mounted. The housing permits an unknown gas to flow therethrough for contact with the cells, and there is a sensor control circuit in communication with the cells. The sensor control circuit is configured to utilize the signals from the cells to generate an ammonia concentration signal indicating the concentration of ammonia in the unknown gas. Ammonia may be sensed in an unknown gas by heating such cells to selected working temperatures, exposing them to an unknown gas, obtaining signals from the cells, and using the cell signals to determine the ammonia content.
摘要:
A sensor includes an oxygen pump cell; an oxygen pump chamber; an emf cell; a reference chamber providing a fluid connection to the reference gas; gas channels in fluid communication with the pump and emf electrodes, the reference gas comprising reformate produced by a fuel reformer fueled by an air-fuel gas mixture having an air-fuel ratio; a reformer electronic control module; a sensor electronic control module; a heater; a temperature sensor disposed in communication with the heater and the sensor control module for maintaining the sensor at a desired operating temperature; a closed loop controlled operation amplifier in electrical communication with the sensor, whereby the oxygen pump cell provides sufficient oxygen ions to oxidize an incoming diffusion-limiting fuel flux to the emf cell and maintain a constant emf at the emf cell, and wherein a current value represents an equivalent to the air-fuel ratio of the air-fuel gas mixture.
摘要:
In one embodiment, a gas sensor element comprises: an electrolyte disposed between and in ionic communication with a first electrode and a second electrode; and a protective layer disposed adjacent to the first electrode. The protective layer comprises a catalytic coating comprising a reducible support material, a catalyst, and a water activator material. The catalyst coating is capable of converting an oxygen consuming species in a gas to an oxygen donating species.
摘要:
One embodiment of an ammonia gas sensor includes: a reference electrode, an ammonia selective sensing electrode and an electrolyte disposed therebetween. The sensing electrode comprises the reaction product of a main material selected from the group consisting of vanadium, tungsten, molybdenum, vanadium oxides, tungsten oxides, molybdenum oxides, and combinations comprising at least one of the foregoing main materials, and an electrically conducting material selected from the group consisting of electrically conductive metals, electrically conductive metal oxides, and combinations comprising at least one of the foregoing.
摘要:
Disclosed herein are NOx sensors and methods of using the same. In one embodiment, a method for sensing NOx comprises: contacting a first NOx electrode with the gas, contacting a second NOx electrode with the gas, determining a NO2 emf between the first NOX electrode and a first reference electrode, determining a NOx emf between the second NOx electrode and a second reference electrode, and determining a NO2 concentration and a NO concentration using the NO2 emf and the NOx emf. The first electrode can be at a first temperature of greater than or equal to about 700° C., and the second electrode can be at a second temperature of about 500° C. to about 650° C.
摘要:
A diesel exhaust gas system includes a diesel particulate filter (DPF), a trap for nitrogen oxides (LNT), a hydrocarbon catalytic reformer for generating reformate, and an air supply. A method for controlling the rate of burn of soot in a DPF limits the oxygen percentage in the exhaust to about 6%. The LNT may be located ahead of the DPF in the exhaust line. Reformate is directed with exhaust through the LNT. The second flow of air cools the exhaust gas and thereby prevents overheating of the DPF substrate. The DPF also may be located ahead of the LNT. Reformate is controllably combusted by the second air flow in the DPF, reducing the oxygen percentage to about 6%, thus limiting the rate at which soot in the DPF can burn and thereby preventing overheating of the DPF substrate.