摘要:
Carbon monoxide and carbonyl sulfide emissions are reduced in manufacturing processes, including titanium tetrachloride production processes. Gas is contacted with CO, COS, and an oxygen-containing gas with a suitable catalyst. The catalyst may be a metal oxide catalyst containing bismuth, cobalt and nickel, a xerogel or aerogel catalyst containing Au, Rh, Ru and Co in aluminum oxide/oxyhydroxide matrices, or a supported metal catalyst that contains at least one metal from the group Pd, Rh, Ru and Cu. In the latter case, the catalyst support is contains alumina or carbon. A catalyst composite of Au, Rh, Ru and Cr, and cerium oxide and lanthanum oxide may also be used.
摘要:
An improved process for decomposing alkyl or aromatic hydroperoxides to form a decomposition reaction mixture containing the corresponding alcohol and ketone. The improvement relates to decomposing the hydroperoxide by contacting the hydroperoxide with a catalytic amount of a heterogenous catalyst of Au, Ag, Cu or a sol-gel compound containing particular combinations of Fe, Ni, Cr, Co, Zr, Ta, Si, Mg, Nb, Al and Ti wherein certain of those metals have been combined with an oxide, such as an inorganic matrix of hydroxides or oxides, or combinations thereof. The catalysts may also optionally be supported on a suitable support member and used in the presence of an additional metal.
摘要:
A catalytic process is disclosed for oxidizing cycloalkanes directly to form, in a single step, a mixture containing the corresponding alcohol and ketone. In particular, the invention relates to oxidizing a cycloalkane by contacting it with a source of oxygen and a catalytic amount of a heterogeneous catalyst. The catalysts of the invention include gold (including gold sol-gel compounds) and sol-gel compounds containing particular combinations of Cr, Co, Zr, Ta, Si, Mg, Nb, Al and Ti, wherein certain of those metals have been combined with an oxide, such as an inorganic matrix of hydroxides or oxides, or combinations thereof. The catalysts may also optionally be supported on a suitable support member.
摘要:
This invention concerns a process for the addition of formaldehyde to the &agr; carbon atom of lactones for the production of &agr;-methylenelactones, and specifically &agr;-methylene-&ggr;-butyrolactone.
摘要:
This invention relates to chrysene compounds that are useful in electroluminescent applications. It also relates to electronic devices in which the active layer includes such a chrysene compound.
摘要:
There is provided an organic light-emitting diode luminaire. The luminaire includes a first electrode, a second electrode, and an electroluminescent layer therebetween. The electroluminescent layer includes: a host material capable of electroluminescence having an emission color that is blue; and a dopant having an emission color that is red-orange. The additive mixing of the emitted colors results in an overall emission of white light.
摘要:
There is provided an organic light-emitting diode luminaire. The luminaire includes a first electrode, a second electrode, and an electroluminescent layer therebetween. The electroluminescent layer includes: a first electroluminescent material having an emission color that is blue-green; and a second electroluminescent material having an emission color that is red/red-orange. The additive mixing of the emitted colors results in an overall emission of white light.
摘要:
There is provided an electroactive composition including: a deuterated first host material and an electroluminescent dopant material. The first host is a compound having Formula I: The compound of Formula I is deuterated. In Formula I: Ar1 to Ar4 are the same or different and are aryl; Q is a multivalent aryl group or where T is (CR′)a, SiR2, S, SO2, PR, PO, PO2, BR, or R; R is the same or different at each occurrence and is an alkyl group or an ary group; R′ is the same or different at each occurrence and is selected H, D, or alkyl; a is an integer from 1-6; and m is an integer from 0-6.