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公开(公告)号：US07781619B2
公开(公告)日：2010-08-24
申请号：US11717845
申请日：2007-03-14
CPC分类号： C07C45/48 , Y02P20/582 , C07C49/04
摘要： A process for the production of a ketone having a carbon number between about 20 and about 40 comprising contacting fatty acids containing from about 10 to about 21 carbons atoms with a hydrotalcite catalyst under conditions effective to decarboxylate said acids. More particularly said decarboxylation conditions comprise: a temperature in the range between about 300° C. and about 400° C.; a pressure in the range between about 0.01 and about 5 bar; and a weight hourly space velocity (WHSV) of from about 0.1 to about 10 hr−1.
摘要翻译： 一种制备碳数在约20至约40之间的酮的方法，包括使含有约10至约21个碳原子的脂肪酸与水滑石催化剂在有效使所述酸脱羧的条件下接触。 更具体地说，脱羧条件包括：在约300℃和约400℃之间的范围内的温度; 压力在约0.01至约5巴之间的范围内; 和约0.1至约10小时-1的重时空速（WHSV）。
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公开(公告)号：US08795392B2
公开(公告)日：2014-08-05
申请号：US11911168
申请日：2007-06-06
IPC分类号： C10L1/188
CPC分类号： B01J23/85 , B01J23/883 , B01J35/0026 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/20 , C10G45/08 , C10G2300/1011 , C10G2300/207 , C10G2300/4018 , C11C3/123 , Y02P30/20
摘要： A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.
摘要翻译： 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。
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公开(公告)号：US20070287871A1
公开(公告)日：2007-12-13
申请号：US11725103
申请日：2007-03-16
申请人： Eelko Brevoord , Stephan Janbroers , Mark Harte , Pekka Aalto , Elina Harlin , Heidi Osterholm
发明人： Eelko Brevoord , Stephan Janbroers , Mark Harte , Pekka Aalto , Elina Harlin , Heidi Osterholm
IPC分类号： C07C5/31 , B01J27/182 , B01J27/185
CPC分类号： B01J29/85 , B01J29/068 , B01J35/023 , B01J2229/20 , B01J2229/42 , C07C5/2775 , C07C2529/85 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , Y02P30/20 , C07C9/22 , C07C9/16
摘要： A catalyst system for treating a hydrocarbonaceous feed comprising a matrix selected from the group consisting of alumna, silica alumina, titanium alumina and mixtures thereof; a support medium substantially uniformly distributed through said matrix comprising a SAPO-11 molecular sieve; and 0.1 to 1.0 wt % (based on the total weight of the catalyst system) of a catalytically active metal phase supported on said medium and comprising a metal selected from the group consisting of platinum, palladium, ruthenium, rhodium or mixtures thereof. The catalyst system is characterized in that said SAPO-11 molecular sieve has: a) a silica to alumina molar ratio of 0.08 to 0.24; b) a phosphorous to alumina ratio of 0.75 to 0.83; c) a surface area of at least 150 m2/g; d) a crystallite size in the range 250 to 600 angstroms; and, e) a sodium content of less than 2000 ppm weight.
摘要翻译： 一种用于处理含烃原料的催化剂体系，其包含选自校准物，二氧化硅氧化铝，钛氧化铝及其混合物的基质; 基本上均匀分布在包含SAPO-11分子筛的基质中的载体介质; 和0.1至1.0重量％（基于催化剂体系的总重量）负载在所述介质上的催化活性金属相，并且包含选自铂，钯，钌，铑或其混合物的金属。 催化剂体系的特征在于所述SAPO-11分子筛具有：a）二氧化硅与氧化铝的摩尔比为0.08至0.24; b）磷与氧化铝的比例为0.75至0.83; c）表面积至少为150m 2 / g; d）微晶尺寸在250至600埃的范围内; 和e）小于2000ppm重量的钠含量。
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公开(公告)号：US20100043278A1
公开(公告)日：2010-02-25
申请号：US11911168
申请日：2007-06-09
IPC分类号： C10L1/188
CPC分类号： B01J23/85 , B01J23/883 , B01J35/0026 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/20 , C10G45/08 , C10G2300/1011 , C10G2300/207 , C10G2300/4018 , C11C3/123 , Y02P30/20
摘要： A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.
摘要翻译： 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。
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公开(公告)号：US20070244343A1
公开(公告)日：2007-10-18
申请号：US11717845
申请日：2007-03-14
IPC分类号： C07C45/47
CPC分类号： C07C45/48 , Y02P20/582 , C07C49/04
摘要： A process for the production of a ketone having a carbon number between about 20 and about 40 comprising contacting fatty acids containing from about 10 to about 21 carbons atoms with a hydrotalcite catalyst under conditions effective to decarboxylate said acids. More particularly said decarboxylation conditions comprise: a temperature in the range between about 300° C. and about 400° C.; a pressure in the range between about 0.01 and about 5 bar; and a weight hourly space velocity (WHSV) of from about 0.1 to about 10 hr−1.
摘要翻译： 一种制备碳数在约20至约40之间的酮的方法，包括使含有约10至约21个碳原子的脂肪酸与水滑石催化剂在有效使所述酸脱羧的条件下接触。 更具体地说，脱羧条件包括：在约300℃和约400℃之间的范围内的温度; 压力在约0.01至约5巴之间的范围内; 和约0.1至约10小时-1的重时空速（WHSV）。
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公开(公告)号：US07445936B2
公开(公告)日：2008-11-04
申请号：US11057507
申请日：2005-02-14
摘要： The present invention pertains to A cyclic process for testing FCC catalysts with resid feedstock on a small scale wherein in a first cycle: a) the feed to be cracked is heated to a temperature between 50 and 500° C., b) the heated feed is injected into a riser reactor containing the FCC catalyst to be tested having a temperature between 500 and 800° C., the injection time being less than 2 seconds, c) an inert gas is injected into the lower end of said reactor riser together in the vicinity of the feed injection in a volume ratio of inert gas to vaporized feed of about 0.03 and 10, the mixing of feed and inert gas occurring in said riser reactor; d) the feed is contacted with the FCC catalyst under fluidized conditions for a contact time of less than 8 seconds; e) the feed is stripped from the FCC catalyst and the properties of the product are analyzed; and in a second cycle a quench liquid is injected into said riser reactor in an amount of up to about 20 wt. % of said feed so as to reduce the temperature in said riser reactor and minimize undesirable secondary reactions. The invention also comprises the apparatus employed to carry out the process. With the process of the invention the mass transfer and diffusion limitations of commercial FCC units are properly simulated.
摘要翻译： 本发明涉及一种用于以小规模检测具有残留原料的FCC催化剂的循环方法，其中在第一循环中：a）待裂化的进料被加热至50-500℃的温度，b）加热的进料 被注入到含有待测试的FCC催化剂的提升管反应器中，温度在500-800℃之间，注入时间小于2秒，c）将惰性气体一起注入所述反应器提升管的下端 惰性气体与蒸发进料的体积比约为0.03和10的进料注入附近，在所述提升管反应器中发生的进料和惰性气体的混合; d）在流化条件下使进料与FCC催化剂接触，接触时间小于8秒; e）从FCC催化剂中剥离进料，分析产物的性质; 并且在第二循环中，骤冷液体以高达约20重量％的量注入所述提升管反应器。 ％的所述进料，以便降低所述提升管反应器中的温度并使不期望的次级反应最小化。 本发明还包括用于执行该过程的装置。 通过本发明的方法，适当地模拟商业FCC装置的传质和扩散限制。
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公开(公告)号：US20050040080A1
公开(公告)日：2005-02-24
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth Riley , Stuart Soled , Sabato Miseo , Frans Plantenga , Marinus Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth Riley , Stuart Soled , Sabato Miseo , Frans Plantenga , Marinus Cerfontain , Sonja Eijsbouts , Eelko Brevoord
IPC分类号： B01J23/00 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/888 , B01J37/03 , B01J37/08 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G47/12 , C10G49/04 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G67/04 , C10G45/00
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。
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公开(公告)号：US07229548B2
公开(公告)日：2007-06-12
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。
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公开(公告)号：US20050145542A1
公开(公告)日：2005-07-07
申请号：US11057507
申请日：2005-02-14
申请人： Paul O'Connor , Edwin Berends , Martinus Baas , Eelko Brevoord
发明人： Paul O'Connor , Edwin Berends , Martinus Baas , Eelko Brevoord
摘要： The present invention pertains to A cyclic process for testing FCC catalysts with resid feedstock on a small scale wherein in a first cycle: a) the feed to be cracked is heated to a temperature between 50 and 500° C., b) the heated feed is injected into a riser reactor containing the FCC catalyst to be tested having a temperature between 500 and 800° C., the injection time being less than 2 seconds, c) an inert gas is injected into the lower end of said reactor riser together in the vicinity of the feed injection in a volume ratio of inert gas to vaporized feed of about 0.03 and 10, the mixing of feed and inert gas occurring in said riser reactor; d) the feed is contacted with the FCC catalyst under fluidized conditions for a contact time of less than 8 seconds; e) the feed is stripped from the FCC catalyst and the properties of the product are analyzed; and in a second cycle a quench liquid is injected into said riser reactor in an amount of up to about 20 wt.% of said feed so as to reduce the temperature in said riser reactor and minimize undesirable secondary reactions. The invention also comprises the apparatus employed to carry out the process. With the process of the invention the mass transfer and diffusion limitations of commercial FCC units are properly simulated.
摘要翻译： 本发明涉及一种用于以小规模检测具有残留原料的FCC催化剂的循环方法，其中在第一循环中：a）待裂化的进料被加热至50-500℃的温度，b）加热的进料 被注入到含有待测试的FCC催化剂的提升管反应器中，温度在500-800℃之间，注入时间小于2秒，c）将惰性气体一起注入所述反应器提升管的下端 惰性气体与蒸发进料的体积比约为0.03和10的进料注入附近，在所述提升管反应器中发生的进料和惰性气体的混合; d）在流化条件下使进料与FCC催化剂接触，接触时间小于8秒; e）从FCC催化剂中剥离进料，分析产物的性质; 并且在第二循环中，将淬灭液体以所述进料的至多约20重量％的量注入所述提升管反应器中，以便降低所述提升管反应器中的温度并使不期望的次要反应最小化。 本发明还包括用于执行该过程的装置。 通过本发明的方法，适当地模拟商业FCC装置的传质和扩散限制。
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