公开(公告)号：US20070287871A1

公开(公告)日：2007-12-13

申请号：US11725103

申请日：2007-03-16

申请人： Eelko Brevoord ,  Stephan Janbroers ,  Mark Harte ,  Pekka Aalto ,  Elina Harlin ,  Heidi Osterholm

发明人： Eelko Brevoord ,  Stephan Janbroers ,  Mark Harte ,  Pekka Aalto ,  Elina Harlin ,  Heidi Osterholm

IPC分类号： C07C5/31 ,  B01J27/182 ,  B01J27/185

CPC分类号： B01J29/85 ,  B01J29/068 ,  B01J35/023 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2775 ,  C07C2529/85 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4018 ,  Y02P30/20 ,  C07C9/22 ,  C07C9/16

摘要： A catalyst system for treating a hydrocarbonaceous feed comprising a matrix selected from the group consisting of alumna, silica alumina, titanium alumina and mixtures thereof; a support medium substantially uniformly distributed through said matrix comprising a SAPO-11 molecular sieve; and 0.1 to 1.0 wt % (based on the total weight of the catalyst system) of a catalytically active metal phase supported on said medium and comprising a metal selected from the group consisting of platinum, palladium, ruthenium, rhodium or mixtures thereof. The catalyst system is characterized in that said SAPO-11 molecular sieve has: a) a silica to alumina molar ratio of 0.08 to 0.24; b) a phosphorous to alumina ratio of 0.75 to 0.83; c) a surface area of at least 150 m2/g; d) a crystallite size in the range 250 to 600 angstroms; and, e) a sodium content of less than 2000 ppm weight.

摘要翻译： 一种用于处理含烃原料的催化剂体系，其包含选自校准物，二氧化硅氧化铝，钛氧化铝及其混合物的基质; 基本上均匀分布在包含SAPO-11分子筛的基质中的载体介质; 和0.1至1.0重量％（基于催化剂体系的总重量）负载在所述介质上的催化活性金属相，并且包含选自铂，钯，钌，铑或其混合物的金属。 催化剂体系的特征在于所述SAPO-11分子筛具有：a）二氧化硅与氧化铝的摩尔比为0.08至0.24; b）磷与氧化铝的比例为0.75至0.83; c）表面积至少为150m 2 / g; d）微晶尺寸在250至600埃的范围内; 和e）小于2000ppm重量的钠含量。

公开(公告)号：US20070244343A1

公开(公告)日：2007-10-18

申请号：US11717845

申请日：2007-03-14

申请人： Eelko Brevoord ,  Stephan Janbroers ,  Francisco Mas Cabre ,  Mark Harte

发明人： Eelko Brevoord ,  Stephan Janbroers ,  Francisco Mas Cabre ,  Mark Harte

IPC分类号： C07C45/47

CPC分类号： C07C45/48 ,  Y02P20/582 ,  C07C49/04

摘要： A process for the production of a ketone having a carbon number between about 20 and about 40 comprising contacting fatty acids containing from about 10 to about 21 carbons atoms with a hydrotalcite catalyst under conditions effective to decarboxylate said acids. More particularly said decarboxylation conditions comprise: a temperature in the range between about 300° C. and about 400° C.; a pressure in the range between about 0.01 and about 5 bar; and a weight hourly space velocity (WHSV) of from about 0.1 to about 10 hr−1.

摘要翻译： 一种制备碳数在约20至约40之间的酮的方法，包括使含有约10至约21个碳原子的脂肪酸与水滑石催化剂在有效使所述酸脱羧的条件下接触。 更具体地说，脱羧条件包括：在约300℃和约400℃之间的范围内的温度; 压力在约0.01至约5巴之间的范围内; 和约0.1至约10小时-1的重时空速（WHSV）。

公开(公告)号：US08795392B2

公开(公告)日：2014-08-05

申请号：US11911168

申请日：2007-06-06

申请人： Eelko Brevoord ,  Robertus Leliveld ,  Stephan Janbroers

发明人： Eelko Brevoord ,  Robertus Leliveld ,  Stephan Janbroers

IPC分类号： C10L1/188

CPC分类号： B01J23/85 ,  B01J23/883 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1011 ,  C10G2300/207 ,  C10G2300/4018 ,  C11C3/123 ,  Y02P30/20

摘要： A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.

摘要翻译： 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。

公开(公告)号：US07781619B2

公开(公告)日：2010-08-24

申请号：US11717845

申请日：2007-03-14

申请人： Eelko Brevoord ,  Stephan Janbroers ,  Francisco René Mas Cabre ,  Mark Hendrikus Harte

发明人： Eelko Brevoord ,  Stephan Janbroers ,  Francisco René Mas Cabre ,  Mark Hendrikus Harte

IPC分类号： C07C45/41 ,  C07C45/65

CPC分类号： C07C45/48 ,  Y02P20/582 ,  C07C49/04

摘要： A process for the production of a ketone having a carbon number between about 20 and about 40 comprising contacting fatty acids containing from about 10 to about 21 carbons atoms with a hydrotalcite catalyst under conditions effective to decarboxylate said acids. More particularly said decarboxylation conditions comprise: a temperature in the range between about 300° C. and about 400° C.; a pressure in the range between about 0.01 and about 5 bar; and a weight hourly space velocity (WHSV) of from about 0.1 to about 10 hr−1.

摘要翻译： 一种制备碳数在约20至约40之间的酮的方法，包括使含有约10至约21个碳原子的脂肪酸与水滑石催化剂在有效使所述酸脱羧的条件下接触。 更具体地说，脱羧条件包括：在约300℃和约400℃之间的范围内的温度; 压力在约0.01至约5巴之间的范围内; 和约0.1至约10小时-1的重时空速（WHSV）。

公开(公告)号：US20100043278A1

公开(公告)日：2010-02-25

申请号：US11911168

申请日：2007-06-09

申请人： Eelko Brevoord ,  Robertus Gerardus Leliveld ,  Stephan Janbroers

发明人： Eelko Brevoord ,  Robertus Gerardus Leliveld ,  Stephan Janbroers

IPC分类号： C10L1/188

CPC分类号： B01J23/85 ,  B01J23/883 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1011 ,  C10G2300/207 ,  C10G2300/4018 ,  C11C3/123 ,  Y02P30/20

摘要： A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.

摘要翻译： 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。

公开(公告)号：US20110319505A1

公开(公告)日：2011-12-29

申请号：US13203845

申请日：2010-03-05

申请人： Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

发明人： Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

IPC分类号： C07C27/00 ,  B01J27/051

CPC分类号： B01J27/0515 ,  B01J23/8872 ,  B01J37/0009 ,  B01J37/20 ,  C07C29/1518 ,  Y02P20/52 ,  C07C31/08 ,  C07C31/04

摘要： A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.

摘要翻译： 硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。 所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量 在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。 还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。

公开(公告)号：US08980782B2

公开(公告)日：2015-03-17

申请号：US13203845

申请日：2010-03-05

申请人： Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

发明人： Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

IPC分类号： B01J27/051 ,  B01J23/887 ,  B01J37/00 ,  B01J37/20 ,  C07C29/151

CPC分类号： B01J27/0515 ,  B01J23/8872 ,  B01J37/0009 ,  B01J37/20 ,  C07C29/1518 ,  Y02P20/52 ,  C07C31/08 ,  C07C31/04

摘要： A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.

摘要翻译： 硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。 所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量 在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。 还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。

公开(公告)号：US06565643B2

公开(公告)日：2003-05-20

申请号：US09747284

申请日：2000-12-21

申请人： Jan Nieman ,  Stephan Janbroers

发明人： Jan Nieman ,  Stephan Janbroers

IPC分类号： C04B1404

CPC分类号： B01J21/16 ,  B01J35/10 ,  C01B33/40

摘要： The invention pertains to a process for preparing a synthetic clay mineral which comprises silicon, aluminum, and at least one octahedron ion, which clay mineral has a total content of sodium and potassium of less than 0.5 wt. %, comprising the steps of a) providing a silica-alumina with a total content of sodium and potassium of less than 2.0 wt. % b) combining the silica-alumina with an octahedron ion source in such a manner that less than 0.1 mole of the total of sodium or potassium is added per mole of octahedron ion, c) if necessary, adjusting the pH to a value of at least 7, with less than 0.1 mole of the total of sodium and potassium being added per mole of octahedron ion during the pH adjustment, d) ageing the precipitate formed in c) at a temperature of 0-350° C. in an aqueous environment; e) optionally isolating the resulting material, optionally followed by washing. The invention makes it possible to prepare a saponite with a low content of sodium and potassium without an ion-exchange on the final material being necessary.

摘要翻译： 本发明涉及制备包含硅，铝和至少一种八面体离子的合成粘土矿物的方法，该粘土矿物的钠和钾的总含量小于0.5wt。 ％，包括以下步骤：a）提供总钠含量低于2.0重量％的二氧化硅 - 氧化铝。 b）将二氧化硅 - 氧化铝与八面体离子源结合，使得每摩尔八面体离子加入小于0.1摩尔的钠或钾的总量，c）如果需要，将pH调节至 至少7，在pH调节期间，每摩尔八面体离子添加少于0.1摩尔的钠和钾，d）在水溶液中在0-350℃的温度下老化c）中形成的沉淀物 ; e）任选地分离所得材料，任选地随后进行洗涤。本发明使得可以在最终材料上制备不含离子交换的钠和钾含量低的皂石。

公开(公告)号：US06537442B1

公开(公告)日：2003-03-25

申请号：US09720852

申请日：2001-02-20

申请人： Jan Nieman ,  Stephan Janbroers

发明人： Jan Nieman ,  Stephan Janbroers

IPC分类号： C10G4702

CPC分类号： B01J37/036

摘要： The invention pertains to a cogel comprising oxidic compounds of one or more trivalent metallic elements selected from the group of aluminum, borium, gallium, chromium, iron, cobalt, manganese, vanadium, molybdenum, tungsten, indium, rhodium, scandium, or mixtures thereof, oxidic compounds of one or more tetravalent metallic elements selected from the group of silicon, titanium, germanium, or mixtures thereof and oxidic compounds of one or more divalent metallic elements with at least one divalent metallic element not selected from Group VIII non-noble metallic elements, wherein a) the cogel is essentially X-ray amorphous apart from saponite, if present; b) the saponite content CA of the cogel is less than 60%; c) the cogel has a surface area of at least 400 m2/g; d) the cogel has a cation-exchange capacity of at least 0.5 wt %; and e) the total of sodium and potassium contained in the cogel amounts to less than 0.5 wt %, based on the total weight of the cogel. The invention further relates to a process for preparing said cogel as well as to catalysts comprising these cogels as cracking component, a process for preparing said catalysts, and the use of these catalysts for hydroprocessing applications.

摘要翻译： 本发明涉及包含选自铝，硼，镓，铬，铁，钴，锰，钒，钼，钨，铟，铑，钪或其混合物中的一种或多种三价金属元素的氧化物的共凝胶 选自硅，钛，锗或其混合物的一种或多种四价金属元素的氧化化合物和一种或多种二价金属元素的氧化化合物与至少一种未选自VIII族非贵金属的二价金属元素 元素，其中a）如果存在，共聚胶基本上是除皂石外的X射线无定形的; b）共聚胶的皂石含量CA小于60％; c）共凝胶的表面积至少为400m 2 / g; d）共聚物具有至少0.5重量％的阳离子交换容量; 基于共聚胶的总重量，共聚胶中所含的钠和钾的总量小于0.5重量％。 本发明还涉及一种制备所述共聚物的方法以及包含这些凝结剂作为裂化组分的催化剂，制备所述催化剂的方法以及这些催化剂用于加氢处理应用的方法。