Group VI precursor compounds
    3.
    发明授权

    公开(公告)号:US11807653B2

    公开(公告)日:2023-11-07

    申请号:US17736855

    申请日:2022-05-04

    Applicant: ENTEGRIS, INC.

    CPC classification number: C07F11/00 H01L21/02192 H01L21/32051

    Abstract: The invention provides a facile process for preparing various Group VI precursor compounds useful in the vapor deposition of such Group VI metals onto solid substrates, especially microelectronic semiconductor device substrates. The process provides an effective means to obtain such volatile materials, which can then be sources of molybdenum, chromium, or tungsten-containing materials to be deposited on such substrates. Additionally, the invention provides a method for vapor deposition of such compounds onto microelectronic device substrates.

    Group VI precursor compounds
    5.
    发明授权

    公开(公告)号:US11560397B2

    公开(公告)日:2023-01-24

    申请号:US17370722

    申请日:2021-07-08

    Applicant: ENTEGRIS, INC.

    Abstract: The invention provides a facile process for preparing various Group VI precursor compounds, set forth below as Formula (I), useful in the vapor deposition of certain Group VI metals onto solid substrates, especially microelectronic semiconductor device substrates. Also provided is a process for the preparation of such precursor compounds. Additionally, the invention provides a method for vapor deposition of Group VI metals onto microelectronic device substrates utilizing the precursor compounds of the invention.

    Vapor deposition precursor compounds and process of use

    公开(公告)号:US11466038B2

    公开(公告)日:2022-10-11

    申请号:US16899060

    申请日:2020-06-11

    Applicant: ENTEGRIS, INC.

    Abstract: Provided is a plasma enhanced atomic layer deposition (PEALD) process for depositing etch-resistant SiOCN films. These films provide improved growth rate, improved step coverage and excellent etch resistance to wet etchants and post-deposition plasma treatments containing O2 and NH3 co-reactants. This PEALD process relies on one or more precursors reacting in tandem with the plasma exposure to deposit the etch-resistant thin-films of SiOCN. The films display excellent resistance to wet etching with dilute aqueous HF solutions, both after deposition and after post-deposition plasma treatment(s). Accordingly, these films are expected to display excellent stability towards post-deposition fabrication steps utilized during device manufacturing and build.

    Group VI precursor compounds
    7.
    发明授权

    公开(公告)号:US11352383B2

    公开(公告)日:2022-06-07

    申请号:US16803547

    申请日:2020-02-27

    Applicant: ENTEGRIS, INC.

    Abstract: The invention provides a facile process for preparing various Group VI precursor compounds useful in the vapor deposition of such Group VI metals onto solid substrates, especially microelectronic semiconductor device substrates. The process provides an effective means to obtain such volatile materials, which can then be sources of molybdenum, chromium, or tungsten-containing materials to be deposited on such substrates. Additionally, the invention provides a method for vapor deposition of such compounds onto microelectronic device substrates.

    Preparation of triiodosilanes
    8.
    发明授权

    公开(公告)号:US11203604B2

    公开(公告)日:2021-12-21

    申请号:US16706347

    申请日:2019-12-06

    Applicant: ENTEGRIS, INC.

    Abstract: Provided is a process for preparing certain silane precursor compounds, e.g., triiodosilane from trichlorosilane utilizing lithium iodide in powder form and catalyzed by tertiary amines. The process provides triiodosilane in high yields and high purity. Triiodosilane is a precursor compound useful in the atomic layer deposition of silicon onto various microelectronic device structures.

    Alloys of Co to reduce stress
    9.
    发明授权

    公开(公告)号:US10793947B2

    公开(公告)日:2020-10-06

    申请号:US15674156

    申请日:2017-08-10

    Applicant: Entegris, Inc.

    Abstract: A deposited cobalt composition is described, including cobalt and one or more alloy component that is effective in combination with cobalt to enhance adhesion to a substrate when exposed on the substrate to variable temperature and/or delaminative force conditions, as compared to corresponding elemental cobalt, wherein the one or more alloy component is selected from the group consisting of boron, phosphorous, tin, antimony, indium, and gold. Such deposited cobalt composition may be employed for metallization in semiconductor devices and device precursor structures, flat-panel displays, and solar panels, and provides highly adherent metallization when the metallized substrate is subjected to thermal cycling and/or chemical mechanical planarization operations in the manufacturing of the semiconductor, flat-panel display, or solar panel product.

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